Toner formulation using crystalline polyester encapsulated with a styrene acrylate latex and method of preparing the same
The present disclosure relates to a chemically prepared toner composition including a toner particle having a core including a first polymer binder, an styrene acrylate encapsulated crystalline polyester latex, a pigment, and a shell formed around the core including a second polymer binder and method to make the same. The disclosed method of preparing the toner results in a change in the distribution of the components of the toner particle wherein the lower molecular weight resins, the pigment and the wax are located away from the surface of the toner particle and the pigment is clinging to the edge of the wax domain.
1. A chemically prepared toner comprising:
a core including a first polyester resin polymer binder, a crystalline polyester encapsulated by a polymer latex that is polymerized by a monomer solution including a hydrophilic monomer having one of a carboxyl (—COOH) functional group and a hydroxyl (—OH) functional group and hydrophobic styrene and acrylate monomers, a pigment, and a wax; and
a shell formed around the core including a second polyester resin polymer binder, wherein the pigment and wax are located away from the surface of the toner particle and the hydrophilic monomer having the carboxyl (—COOH) functional group is beta-carboxyethyl acrylate and the hydrophilic monomer having the hydroxy (—OH) functional group is hydroxyethyl methacrylate.
2. The chemically prepared toner of claim 1 , wherein the hydrophobic acrylate monomer is an alkyl acrylate.
3. The chemically prepared toner of claim 2 , wherein the alkyl acrylate monomer is butyl acrylate.
4. The chemically prepared toner of claim 2 , wherein the alkyl acrylate monomer is lauryl acrylate.
5. The chemically prepared toner of claim 1 , wherein a glass transition temperature (Tg) of the polymer latex is between 20° C. and 60° C.
6. The chemically prepared toner of claim 1 , further comprising a borax coupling agent between the outer surface of the core and the shell.