Fuel cell with segregated electrolyte distribution and method for making the same

1. A method of making a fuel cell electrode, comprising:

mixing water, n-propanol, and an ionomer dispersion to form an initial dispersion, wherein:

the initial dispersion includes an ionomer;

the ionomer is included in the ionomer dispersion; and

mixing the water, the n-propanol, and the ionomer dispersion includes stirring the water, the n-propanol, and the ionomer dispersion;

mixing carbon nanotubes (CNT) with the initial dispersion, wherein:

mixing the carbon nanotubes with the initial dispersion includes adding the carbon nanotubes to the initial dispersion while stirring the initial dispersion; and

the carbon nanotubes are graphitized carbon nanotubes;

heating and stirring the initial dispersion to form a CNT-ionomer composite suspension;

after forming the CNT-ionomer composite suspension, mixing the CNT-ionomer composite suspension with an electrode catalyst solution to form an electrode ink, wherein the electrode catalyst solution includes a carbon black powder and a catalyst supported by the carbon black powder; and

coating a proton exchange membrane with the electrode ink to form the fuel cell electrode.

2. The method of claim 1 , wherein the initial dispersion includes 80 grams of the water, 8 grams of the n-propanol, and 1.8 grams of the graphitized carbon nanotubes.

3. The method of claim 2 , wherein the carbon nanotubes are multi-wall carbon nanotubes having a diameter ranging between 10 nanometers and 20 nanometers.

4. The method of claim 3 , wherein heating and stirring the initial dispersion includes stirring the initial dispersion with a magnetic stirrer rotating at 350 revolutions per minute.

5. The method of claim 4 , wherein heating and stirring the initial dispersion includes heating the initial dispersion to a temperature ranging between 50 degrees Celsius and 100 degrees Celsius.

6. The method of claim 5 , wherein heating and stirring the initial dispersion includes simultaneously heating and stirring the initial dispersion for 2.5 hours.

7. The method of claim 6 , further comprising, after simultaneously heating and stirring the initial dispersion for 2.5 hours, continuing stirring the initial dispersion for 16 hours without heating the initial dispersion.

8. The method of claim 7 , further comprising allowing the initial dispersion to cool through natural convection.

9. The method of claim 8 , wherein allowing the initial dispersion to cool through natural convection and continuing stirring the initial dispersion for 16 hours without heating the initial dispersion occur simultaneously.

10. The method of claim 9 , wherein the catalyst includes a plurality of platinum nanoparticles, and the plurality of platinum nanoparticles are deposited on the carbon black powder to form a catalyst-loaded carbon black powder.

11. The method of claim 10 , wherein mixing the CNT-ionomer composite suspension with the electrode catalyst solution includes mixing the catalyst-loaded carbon black powder with water, n-propanol, and the CNT-ionomer composite suspension to form a segregated ionomer electrode coating.

12. The method of claim 11 , wherein the segregated ionomer electrode coating includes 3.81 grams of the catalyst-loaded carbon black powder, 8.3 grams of n-propanol, 32.73 grams of water, and 56 grams of the CNT-ionomer composite suspension.

13. The method of claim 12 , further comprising mixing the segregated ionomer electrode coating in a polymeric bottle containing ZrO 2 beads to form the electrode ink, wherein mixing the segregated ionomer electrode coating includes rolling the polymeric bottle, and the each of the ZrO 2 beads has a diameter of 5 millimeters.

14. The method of claim 13 , wherein the coating the proton exchange membrane with the electrode ink while the electrode ink is still wet, and letting the electrode ink dry to form the fuel cell electrode.