Method to improve the morphology of core/shell quantum dots for highly luminescent nanostructures
View Patent ↗Highly luminescent nanostructures, particularly highly luminescent quantum dots, comprising a nanocrystal core are provided. Also provided are methods of increasing the sphericity of nanostructures comprising subjecting nanocrystal cores to an acid etch step, an annealing step, or a combination of an acid etch step and an annealing step.
1. A population of nanostructures comprising a core comprising InP and at least one shell wherein the population of nanostructures deviate from a perfect sphere shape by between about 1% and about 8% and have a full width at half-maximum (FWHM) of between 10 nm and 60 nm.
2. The population of nanostructures of claim 1 , wherein the population of nanostructures displays a photoluminescence quantum yield between 70% and 99%.
3. The population of nanostructures of claim 1 , wherein the at least one shell comprises at least one of zinc, sulfur, selenium, or tellurium.
4. The population of nanostructures of claim 1 , wherein the population of nanostructures has a FWHM of between 10 nm and 50 nm.
5. The population of nanostructures of claim 1 , wherein the population of nanostructures deviate from a perfect sphere shape by between about 1% and about 4%.
6. The population of nanostructures of claim 1 , wherein the population of nanostructures displays a photoluminescence quantum yield between 75% and 99%.
7. The population of nanostructures of claim 1 , wherein the at least one shell comprises zinc and selenium or zinc and sulfur.
8. The population of nanostructures of claim 1 , wherein the population of nanostructures comprises two shells, wherein a first shell comprises zinc and selenium and a second shell comprises zinc and sulfur.
9. A method of producing the population of nanostructures of claim 1 comprising:
(a) contacting a nanocrystal core comprising InP with an organic acid, wherein the molar ratio of the nanocrystal core to the organic acid is between about 1:1 and about 1:1000; and
(b) heating (a) at a temperature between about 50° C. and about 250° C. to provide a nanostructure.
10. The method of claim 9 , wherein the organic acid is a carboxylic acid, a phosphonic acid, or a sulfonic acid.
11. The method of claim 9 , wherein the organic acid is selected from the group consisting of lauric acid, hexanoic acid, oleic acid, trifluoromethanesulfonic acid, octyl phosphonic acid, 2-ethylhexanoic acid, myristic acid, decanoic acid, palmitic acid, stearic acid, linoleic acid, and mixtures thereof.
12. The method of claim 9 , wherein the nanostructure produced is substantially spherical.
13. The method of claim 9 , wherein the nanostructure produced in (b) shows an increase in sphericity compared to the starting nanocrystal core in (a) of between about 1% and about 10%.
14. The method of claim 9 , further comprising:
(c) heating the nanostructure of (b) at a temperature between about 200° C. and 350° C. for between about 1 minute and 2 hours.
15. The method of claim 14 , further comprising:
(d) contacting the nanostructure of (c) with a shell material; and
(e) heating (d) at a temperature between about 200° C. and about 310° C.;
to provide a nanostructure with at least one shell.
16. The method of claim 9 , further comprising:
(d) contacting the nanostructure of (b) with a shell material; and
(e) heating (d) at a temperature between about 200° C. and about 310° C.;
to provide a nanostructure with at least one shell.
17. The method of claim 15 , wherein the shell material comprises at least two of a zinc source, a sulfur source, a selenium source, and a tellurium source.
18. The method of claim 9 , wherein the organic acid is lauric acid, the heating in (b) is conducted for between about 10 minutes and 50 minutes, and the heating in (b) is at a temperature between about 50° C. and about 100° C.
19. A method of producing the population of nanostructures of claim 1 comprising:
(a) heating a nanocrystal core comprising InP at a temperature between about 150° C. and 350° C. for between about 1 minute and 2 hours to provide a nanostructure;
(b) contacting the nanostructure of (a) with a shell material; and
(c) heating (b) at a temperature between about 200° C. and about 310° C.;
to provide a nanostructure with at least one shell.
20. The method of claim 19 , wherein the nanostructure produced in (c) is substantially spherical.
21. The method of claim 19 , wherein the nanostructure produced in (c) shows an increase in sphericity compared to the starting nanocrystal core in (a) of between about 1% and about 10%.
22. The method of claim 19 , wherein the shell material of (b) comprises at least two of a zinc source, a sulfur source, a selenium source, and a tellurium source.