Saponified ethylene-vinyl ester copolymer composition pellet, and production method therefor
View Patent ↗An EVOH resin composition excellent in inorganic compound dispersibility and a method of producing an EVOH resin composition excellent in productivity and inorganic compound dispersibility are provided. The EVOH resin composition contains an EVOH resin (A) and an inorganic compound (B), and has a crystallinity of not lower than 36%. The EVOH resin composition is produced by: feeding an EVOH resin (A), an inorganic compound (B) and water (C) into a kneading apparatus including a screw-type side feeder ( 3 ); melt-kneading the resulting EVOH resin mixture while driving the screw-type side feeder ( 3 ); and expelling water vapor from the screw-type side feeder ( 3 ) to reduce the water content of the EVOH resin mixture to lower than 5 weight % while suppressing leakage of the EVOH resin kneaded body from the screw-type side feeder ( 3 ).
1. A saponified ethylene-vinyl ester copolymer composition pellet comprising:
(A) a saponified ethylene-vinyl ester copolymer; and
(B) an inorganic compound;
wherein the saponified ethylene-vinyl ester copolymer composition pellet has a water content of lower than 5 weight % and a crystallinity of not lower than 36%.
2. The saponified ethylene-vinyl ester copolymer composition pellet according to claim 1 , wherein the inorganic compound (B) is present in a proportion of 0.1 to 100 parts by weight based on 100 parts by weight of the saponified ethylene-vinyl ester copolymer (A).
3. The saponified ethylene-vinyl ester copolymer composition pellet according to claim 1 , wherein the inorganic compound (B) is a layered inorganic compound.
4. A saponified ethylene-vinyl ester copolymer composition pellet production method comprising the steps of:
feeding a saponified ethylene-vinyl ester copolymer (A), an inorganic compound (B) and water (C) into a kneading apparatus including a screw side feeder; and
driving the screw side feeder and melt-kneading the resulting saponified ethylene-vinyl ester copolymer mixture to expel water vapor from the screw side feeder to reduce the water content of the saponified ethylene-vinyl ester copolymer mixture to lower than 5 weight % while suppressing leakage of the saponified ethylene-vinyl ester copolymer kneaded body from the screw side feeder,
whereby the saponified ethylene-vinyl ester copolymer composition pellet according to claim 1 having a crystallinity of not lower than 36% is prepared.
5. The saponified ethylene-vinyl ester copolymer composition pellet production method according to claim 4 , wherein the inorganic compound (B) is a layered inorganic compound.
6. The saponified ethylene-vinyl ester copolymer composition pellet production method according to claim 4 , wherein the screw side feeder is positioned downstream of a kneading portion of the kneading apparatus with respect to a material transport direction.
7. The saponified ethylene-vinyl ester copolymer composition pellet production method according to claim 6 , wherein the kneading apparatus further includes water expeller provided downstream of the screw side feeder to expel water from the saponified ethylene-vinyl ester copolymer kneaded body.
8. The saponified ethylene-vinyl ester copolymer composition pellet production method according to claim 4 , wherein the kneading apparatus further includes water expeller provided downstream of the screw side feeder to expel water from the saponified ethylene-vinyl ester copolymer kneaded body.