Conductive composition and solid electrolytic capacitor obtained using aforementioned composition
Provided are: a conductive composition containing a conductive polymer (A) satisfying the below-mentioned condition (i) and a compound (B) having at least 3 hydroxyl groups, and having a pH at 25° C. of a 1 mol/L aqueous solution of no greater than 9.0; a conductive composition that further contains a water-soluble polymer (C) having a hydroxyl group; and a solid electrolytic capacitor having a solid electrolytic layer containing the composition. Condition (i): the volume-average particle size of the smallest particle distribution containing the smallest peak exhibited by the particle size among at least one peak obtained by measuring the particle distribution by means of a dynamic light scattering method using a conductive polymer solution containing 1% by mass of the conductive polymer being less than 26 nm.
1. A conductive composition comprising:
a conductive polymer (A) that satisfies the following condition (i); and
a water-soluble compound (B) having three or more hydroxyl groups that satisfies the following condition (ii),
Condition (i): when a particle distribution for a conductive polymer solution including 1% by mass of the conductive polymer with respect to the total mass of the conductive polymer solution is measured by a dynamic light scattering method, and then, a minimum particle distribution including the peak exhibiting a minimum particle diameter among one or more peaks that can be obtained by the above measurement is obtained, a volume average particle diameter of the minimum particle distribution is less than 5 nm; and
Condition (ii): pH of a 1 mol/L aqueous solution is 9.0 or less.
2. The conductive composition according to claim 1 , wherein the volume average particle diameter of the conductive polymer (A) for the condition is 0.1 to less than 5 nm.
3. The conductive composition according to claim 1 , wherein at least some repeating units constituting the conductive polymer (A) have an acidic group.
4. The conductive composition according to claim 3 , wherein the acidic group of the conductive polymer (A) is a sulfonic acid group or a carboxylic acid group.
5. The conductive composition according to claim 1 , wherein the conductive polymer (A) has a repeating unit represented by Formula (1):
where in Formula (1) R 1 to R 4 each independently represent —H, a linear or branched alkyl group of 1 to 24 carbon atoms, a linear or branched alkoxy group having 1 to 24 carbon atoms, an acidic group or a salt thereof, a hydroxyl group, a nitro group, —F, —Cl, —Br, or —I, and among R 1 to R 4 , at least one represents an acidic group or a salt thereof where the acidic group is a sulfonic acid or a carboxyl group.
6. The conductive composition according to claim 1 , wherein the pH of 1 mol/L aqueous solution of the water-soluble compound (B) is 7 or less.
7. The conductive composition according to claim 1 , wherein the water-soluble compound (B) is a water-soluble low molecular weight compound or a water-soluble high molecular weight compound, and the water-soluble low molecular weight compound is at least one compound selected from glycerin, trimethylolethane, pentaerythritol, and mannitol and the water-soluble high molecular weight compound is at least one selected from polyvinyl alcohol, methylcellulose, and pullulan.
8. The conductive composition according to claim 5 , wherein the water-soluble compound (B) is a water-soluble low molecular weight compound or a water-soluble high molecular weight compound, and the water-soluble low molecular weight compound is at least one compound selected from glycerin, trimethylolethane, pentaerythritol, and mannitol and the water-soluble high molecular weight compound is at least one selected from polyvinyl alcohol, methylcellulose, and pullulan.
9. A solid electrolytic capacitor comprising the conductive composition according to claim 1 as a solid electrolyte.
10. A solid electrolytic capacitor comprising an anode body formed with a conductive material as a constituent material, a dielectric thin film formed on the surface of the anode body, and a solid electrolytic layer formed on the dielectric thin film,
wherein the solid electrolytic layer includes a first conductive polymer layer formed from the conductive composition according to claim 1 and a second conductive polymer layer formed on the first conductive polymer layer.