Electrolyte and lithium-ion battery containing the same
The present application relates to the technical field of lithium-ion batteries and, specifically, relates to an electrolyte and a lithium-ion battery containing the electrolyte. The electrolyte of the present application comprises an organic solvent, a lithium salt and an additive, wherein the additive contains a cyanosulfone compound and a lithium fluorophosphate compound. When the electrolyte contains both the cyanosulfone compound and the lithium fluorophosphate at the same time, the cyanosulfone compound will form a passive film on the surface of the electrode of a high-voltage battery, so as to effectively suppress reaction between the electrolyte and the electrode, further, the lithium fluorophosphate can effectively suppress the decomposition of the lithium salt and improve the film resistance of the electrode. Under the synergistic effect of the two, the cycle performance of the lithium-ion battery is greatly improved, and the storage performance of the electrolyte is also significantly improved.
1. An electrolyte, comprising an organic solvent, a lithium salt and an additive, wherein the additive comprises additive A and additive B, the additive A is at least one cyanosulfone compound, and the additive B is at least one lithium fluorophosphate compound: wherein a structural formula of the cyanosulfone compound is shown as Formula I:
wherein R 1 is selected from a group consisting of halogen, C 1˜20 alkyl, C 2˜20 alkynel, C 6˜26 aryl, C 5˜26 heteroaryl, C 1˜20 alkoxy, C 6˜26 aryloxy, C 1˜20 alkylsulfonyl, C 2˜20 alkynelsulfonyl, C 6˜26 arylsulfonyl, C 1˜20 alkylsulfonyloxy and C 6˜26 arylsulfonyloxy;
each of the C 1˜20 alkyl, the C 2˜20 alkynel, the C 6˜26 aryl, the C 5˜26 heteroaryl, the C 1˜20 alkoxy, the C 6˜26 aryloxy, the C 1˜20 alkylsulfonyl, the C 2˜20 alkynelsulfonyl, the C 6˜26 arylsulfonyl, the C 1˜20 alkylsulfonyloxy and the C 6˜26 arylsulfonyloxy is substituted or unsubstituted by a substituting group; and
the substituting group is selected from a group consisting of halogen.
2. The electrolyte according to claim 1 , wherein R 1 in Formula I is selected from a group consisting of halogen, C 1˜6 alkyl, C 6˜12 aryl and C 5˜11 heteroaryl, and each of the C 1˜6 alkyl, the C 6˜12 aryl and the C 5˜11 heteroaryl is substituted or unsubstituted by a substituting group selected from a group consisting of halogen.
3. The electrolyte according to claim 1 , wherein the cyanosulfone compound is selected from a group consisting of compounds shown as following structural formulas and combinations thereof;
4. The electrolyte according to claim 1 , wherein the lithium fluorophosphate compound is selected from a group consisting of lithium monofluorophosphate, lithium bifluorophosphate and combinations thereof.
5. The electrolyte according to claim 1 , wherein a content of the cyanosulfone compound is 0.05%˜3% by weight of the electrolyte.
6. The electrolyte according to claim 1 , wherein a content of the lithium fluorophosphate compound is 0.001%˜2% by weight of the electrolyte.
7. The electrolyte according to claim 1 , wherein the organic solvent is selected from a group consisting of ethylene carbonate, propylene carbonate 2,3-butylene carbonate, fluoroethylene carbonate, ethylmethyl carbonate, dimethyl carbonate, diethyl carbonate, dipropyl carbonate, methyl propyl carbonate, ethyl propyl carbonate, γ-butyrolactone, methyl propionate, methyl butyrate, ethyl acetate, ethyl propionate, propyl propionate, ethyl butyrate and combinations thereof.
8. The electrolyte according to claim 1 , wherein the lithium salt is selected from a group consisting of lithium hexafluorophosphate, lithium tetrafluoroborate, lithium perchlorate, lithium hexafluoroarsenate, lithium oxalyltetrafluoro phosphate (LiTFOP), LiN(SO 2 R F ) 2 , LiN(SO 2 F)SO 2 R F ), lithium bis(trifluoromethanesulphonyl)imide, lithium bis(fluorosulfonyl)imide, lithium bis(oxalate)borate, lithium oxalyldifluoroborate and combinations thereof; wherein R F ═—C n F 2n+1 , n is an integer within 1˜10.
9. A lithium-ion battery, comprising a positive electrode plate, a negative electrode plate, a separator and the electrolyte according to claim 1 , wherein the positive electrode plate comprises a positive electrode active material, and the negative electrode plate comprises a negative electrode active material.
10. The electrolyte according to claim 1 , wherein a content of the cyanosulfone compound is 0.1%˜2% by weight of the electrolyte.
11. The electrolyte according to claim 1 , wherein a content of the lithium fluorophosphate compound is 0.01%˜1% by weight of the electrolyte.
12. The electrolyte according to claim 1 , wherein the lithium salt is selected from a group consisting of LiPF 6 , LiN(SO 2 R F ) 2 and combinations thereof, wherein R F ═—C n F 2n+1 , n is an integer within 1˜10.
13. The electrolyte according to claim 1 , wherein a concentration of the lithium salt in the electrolyte is 0.5 mol·L −1 ˜2 mol·L −1 .