Golf ball
An object of the present invention is to provide a golf ball having excellent resilience performance. The present invention provides a golf ball having a spherical core and at least one cover layer, wherein the spherical core is formed from a rubber composition containing (a) a base rubber, (b) an α,β-unsaturated carboxylic acid having 3 to 8 carbon atoms and/or a metal salt thereof as a co-crosslinking agent, and (c) a crosslinking initiator, provided that the rubber composition further contains (d) a metal compound in the case of containing only (b) the α,β-unsaturated carboxylic acid having 3 to 8 carbon atoms as the co-crosslinking agent, wherein (c) the crosslinking initiator includes a peroxy ketal represented by the formula (1), and substituents represented by R 1 and R 2 have a bond dissociation energy of 435 KJ/mol or more.
1. A golf ball having a spherical core and at least one cover layer covering the spherical core,
wherein the spherical core is formed from a rubber composition containing:
(a) a base rubber,
(b) an α,β-unsaturated carboxylic acid having 3 to 8 carbon atoms and/or a metal salt thereof as a co-crosslinking agent, and
(c) a crosslinking initiator,
provided that the rubber composition further contains (d) a metal compound if only (b) the α,β-unsaturated carboxylic acid having 3 to 8 carbon atoms is present as the co-crosslinking agent,
wherein (c) the crosslinking initiator includes a peroxy ketal represented by formula (1):
wherein in formula (1), R 1 and R 2 independently represent an aryl group, an aralkyl group, an alkylaryl group, an alkoxy group, an amino group or a hydroxyl group, R 3 to R 12 independently represent a hydrogen atom, an alkyl group having 4 to 6 carbon atoms, an aryl group, an aralkyl group or an alkylaryl group, and the substituents represented by R 1 and R 2 have a bond dissociation energy of 435 KJ/mol or more.
2. The golf ball according to claim 1 , wherein the substituents represented by R 1 and R 2 have a bond dissociation energy of 450 KJ/mol or more.
3. The golf ball according to claim 1 , wherein the substituents represented by R 1 and R 2 include a phenyl group or a naphthyl group.
4. The golf ball according to claim 1 , wherein the spherical core has a hardness difference (Hs−Ho) of 0 or more in Shore C hardness between a surface hardness (Hs) thereof and a center hardness (Ho) thereof.
5. The golf ball according to claim 1 , wherein the rubber composition contains the metal salt of the α,β-unsaturated carboxylic acid having 3 to 8 carbon atoms as (b) the co-crosslinking agent.
6. The golf ball according to claim 1 , wherein the rubber composition further contains (e) an organic sulfur compound.
7. The golf ball according to claim 6 , wherein (e) the organic sulfur compound is at least one compound selected from the group consisting of thiophenols, diphenyl disulfides, thionaphthols, thiuram disulfides, and metal salts thereof.
8. The golf ball according to claim 6 , wherein the rubber composition contains (e) the organic sulfur compound in an amount ranging from 0.05 part by mass to 5.0 parts by mass with respect to 100 parts by mass of (a) the base rubber.
9. The golf ball according to claim 1 , wherein the rubber composition contains (b) the α,β-unsaturated carboxylic acid having 3 to 8 carbon atoms and/or the metal salt thereof in an amount ranging from 15 parts by mass to 50 parts by mass with respect to 100 parts by mass of (a) the base rubber.
10. The golf ball according to claim 1 , wherein the substituents represented by R 1 and R 2 have a bond dissociation energy of 1000 KJ/mol or less.
11. The golf ball according to claim 1 , wherein the peroxy ketal represented by the formula (1) is at least one selected from compounds represented by the formulae (2) to (6):
12. The golf ball according to claim 1 , wherein an amount of the peroxy ketal represented by the formula (1) in an amount of (c) the crosslinking initiator is 50 mass % or more.
13. The golf ball according to claim 1 , wherein (c) the crosslinking initiator consists of the peroxy ketal represented by the formula (1).
14. The golf ball according to claim 1 , wherein the rubber composition further contains (f) a carboxylic acid and/or a salt thereof.
15. The golf ball according to claim 14 , wherein (f) the carboxylic acid and/or the salt thereof is at least one selected from the group consisting of an aliphatic carboxylic acid, a salt of an aliphatic carboxylic acid, an aromatic carboxylic acid, and a salt of an aromatic carboxylic acid.
16. The golf ball according to claim 14 , wherein the rubber composition contains (f) the carboxylic acid and/or the salt thereof in an amount ranging from 0.5 part by mass to 40 parts by mass with respect to 100 parts by mass of (a) the base rubber.
17. The golf ball according to claim 1 , wherein the spherical core has a center hardness Ho ranging from 30 to 70 in Shore C hardness.
18. The golf ball according to claim 1 , wherein the spherical core has a surface hardness Hs ranging from 65 to 100 in Shore C hardness.
19. The golf ball according to claim 1 , wherein
the substituents represented by R 1 and R 2 have a bond dissociation energy of 450 KJ/mol or more,
the substituents represented by R 1 and R 2 include a phenyl group or a naphthyl group, and
the spherical core has a hardness difference (Hs−Ho) of 0 or more in Shore C hardness between a surface hardness (Hs) thereof and a center hardness (Ho) thereof.
20. The golf ball according to claim 1 , wherein the rubber composition contains the metal salt of the α,β-unsaturated carboxylic acid having 3 to 8 carbon atoms as (b) the co-crosslinking agent in an amount ranging from 15 parts by mass to 50 parts by mass with respect to 100 parts by mass of (a) the base rubber, and
the rubber composition further contains (e) an organic sulfur compound in an amount ranging from 0.05 part by mass to 5.0 parts by mass with respect to 100 parts by mass of (a) the base rubber, and (e) the organic sulfur compound is at least one compound selected from the group consisting of thiophenols, diphenyl disulfides, thionaphthols, thiuram disulfides, and metal salts thereof.
21. A golf ball having a spherical core and at least one cover layer covering the spherical core,
wherein the spherical core is formed from a rubber composition containing:
(a) a base rubber,
(b) an α,β-unsaturated carboxylic acid having 3 to 8 carbon atoms and/or a metal salt thereof as a co-crosslinking agent, and
(c) a crosslinking initiator,
provided that the rubber composition further contains (d) a metal compound if only (b) the α,β-unsaturated carboxylic acid having 3 to 8 carbon atoms is present as the co-crosslinking agent,
wherein (c) the crosslinking initiator includes a peroxy ketal represented by formula (1):
wherein in formula (1), R 1 and R 2 independently represent a naphthyl group, an anthryl group, a biphenyl group, a phenanthryl group, a fluorenyl group, an aralkyl group, a xylyl group, a mesityl group, an alkoxy group, an amino group or a hydroxyl group, R 3 to R 12 independently represent a hydrogen atom, an alkyl group, an aryl group, an aralkyl group or an alkylaryl group, and the substituents represented by R 1 and R 2 have a bond dissociation energy of 435 KJ/mol or more.