Nanoparticles for photovoltaic and LED devices and methods of making the same
The present disclosure relates to a composition that includes a particle and a surface species, where the particle has a characteristic length between greater than zero nm and 100 nm inclusively, and the surface species is associated with a surface of the particle such that the particle maintains a crystalline form when the composition is at a temperature between −180° C. and 150° C.
1. A composition comprising:
a plurality of perovskite particles having a cubic crystalline structure, wherein:
each perovskite particle is electronically coupled to its neighboring perovskite particles,
each particle has a characteristic length between greater than zero nanometers (nm) and 100 nm inclusively, and
the perovskite particles remain electronically coupled and maintain the cubic crystalline structure when exposed to a temperature between −180° C. and 150° C.
2. The composition of claim 1 , wherein the perovskite particles comprise at least one of a metal chalcogenide, a Group III-V material, or metal oxide.
3. The composition of claim 1 , wherein the perovskite particles comprise at least one of CsPbI 3 , CsPbBr 3 , CsPbCl 3 , RbPbI 3 , RbPbBr 3 , or RbPbCl 3 .
4. The composition of claim 1 , further comprising an organic cation (A) associated with a surface of at least one of the perovskite particles.
5. The composition of claim 4 , wherein A comprises at least one of methylammonium or formamidinium.
6. The composition of claim 1 , further comprising a surface species associated with a surface of at least one of the perovskite particles.
7. The composition of claim 6 , wherein the surface species is associated with the surface of the at least on perovskite particle by at least one of a covalent bond, an ionic bond, van der Waals interactions, dipole-dipole interactions, Debye interactions, or hydrogen-bonding.
8. The composition of claim 7 , wherein the surface species is associated with the surface of the at least one perovskite particle by an ionic bond.
9. The composition of claim 6 , wherein the surface species comprises at least one of a saturated hydrocarbon, an unsaturated hydrocarbon, a thiol-containing molecule, an acid, or a metal halide.
10. The composition of claim 9 , wherein the surface species comprises at least one of oleate or oleylammonium.
11. The composition of claim 9 , wherein a metal of the metal halide comprises at least one of lead, germanium, or tin.
12. The composition of claim 11 , wherein the metal halide comprises at least one of PbI 2 , PbBr 2 , PbCl 2 , GeI 2 , GeBr 2 , GeCl 2 , SnI 2 , SnBr 2 , or SnCl 2 .
13. A device comprising:
layer comprising:
a plurality of perovskite particles having a cubic crystalline structure,
wherein:
each perovskite particle is electronically coupled to its neighboring perovskite particles,
each particle has a characteristic length between greater than zero nanometers (nm) and 100 nm inclusively, and
the plurality of particles remains electronically coupled and maintain the cubic crystalline structure when the device is exposed to a temperature between −180° C. and 150° C.
14. The device of claim 13 , wherein the perovskite particles comprise at least one of CsPbI 3 , CsPbBr 3 , CsPbCl 3 , RbPbI 3 , RbPbBr 3 , or RbPbCl 3 .
15. A method comprising:
dispersing a first surface species and a particle in a mixture comprising an alkyl acetate, wherein:
the first surface species is associated with a surface of the particle,
the particle has characteristic length between greater than 0 nm and100 nm,
the dispersing removes a first portion of the first surface species from the surface,
the particle has a first crystalline form before the dispersing and a second crystalline form after the dispersing, and
the second crystalline form is maintained, after the dispersing, when the particle is at a temperature between −180° C. and 150° C.
16. The method of claim 15 , wherein the particle comprises at least one of a metal chalcogenide, a Group III-V material, a metal oxide, or a perovskite.
17. The method of claim 16 , wherein:
the particle comprises a perovskite comprising at least one of CsPbX 3 , RbPbX 3 , CsGeX 3 , RbGeX 3 , CsSnX 3 , or RbSnX 3 , and
X is a halogen.
18. The method of claim 17 , wherein:
the mixture further comprises a first salt comprising at least one of an acetate, a nitrate, a carbonate, a thiocyanate, or a phosphate and a metal comprising at least one of lead, germanium or tin,
the dispersing results in the first salt forming a second surface modifier comprising the metal and the halogen,
the first portion is 100% of the first surface modifier,
at least a fraction of the second modifier associates with the surface of the particle, and
the second crystalline form is maintained when the particle is at a temperature between −180° C. and 150° C.
19. The method of claim 18 , wherein the second modifier comprises a metal halide.
20. The method of claim 15 , wherein the second crystalline form is cubic.
21. The method of claim 15 , wherein the first surface species comprises at least one of a saturated hydrocarbon, an unsaturated hydrocarbon, a thiol-containing molecule, an acid, or a metal halide.
22. The method of claim 15 , wherein the first portion is less than 100% of the first surface species and a remainder of the first surface species remains associated with the surface of the particle, after the dispersing.
23. The method of claim 15 , wherein the alkyl acetate comprises at least one of ethyl acetate, methyl acetate, propyl acetate, or butyl acetate.
24. The method of claim 15 , wherein the mixture further comprises at least one of acetate ester, acetone, acetonitrile, diethyl ether, or propylene carbonate.
25. The method of claim 15 , further comprising, after the dispersing, contacting the particle with a solution comprising an aprotic solvent and a second salt, resulting in the forming of a third surface species that associates with the surface of the particle.