Ethylene acid copolymers, their ionomers, and their use in packaging films and injection molded articles
View Patent ↗Provided are novel ethylene acid copolymers, their ionomers and their use in various articles, including packaging films and injection molded articles. The ethylene acid copolymers comprise copolymerized units of ethylene, about 10 to about 30 wt % of copolymerized units of a first α,β-unsaturated carboxylic acid having 3 to 10 carbon atoms; and about 5 to about 15 wt % of copolymerized units of a derivative of a second α,β-unsaturated carboxylic acid having 3 to 10 carbon atoms. Preferred derivatives include esters, and in particular alkyl esters. These ethylene acid copolymers and ionomers have improved optical properties when compared to conventional ethylene acrylic or methacrylic acid copolymers and their ionomers.
1. A polymer composition comprising:
an ethylene acid copolymer,
a hydroxyl-containing crosslinking agent, and
a silane adjuvant;
said ethylene acid copolymer comprising copolymerized units of ethylene, about 10 wt % to about 30 wt % of copolymerized units of a first α,β-unsaturated carboxylic acid having 3 to 10 carbon atoms and about 5 wt % to about 15 wt % of copolymerized units of a derivative of a second α,β-unsaturated carboxylic acid having 3 to 10 carbon atoms;
wherein the weight percentages of the copolymerized units are based on the total weight of the ethylene copolymer and the sum of the weight percentages of the copolymerized units is 100 wt %;
wherein the hydroxyl-containing crosslinking agent is a diol selected from 1,4-butanediol, 1,3-propanediol, 1,6-hexanediol, or combinations thereof; and
wherein at least a portion of the carboxylic acid groups of the first α,β-unsaturated carboxylic acid are neutralized to form an ionomer comprising carboxylate groups having counterions.
2. The polymer composition of claim 1 , wherein about 5% to about 90% of the carboxylic acid groups present in the ethylene copolymer have been neutralized.
3. The polymer composition of claim 1 , wherein the ethylene copolymer comprises about 20 wt % to about 24 wt % of copolymerized units of the first α,β-ethylenically unsaturated carboxylic acid.
4. The polymer composition of claim 1 , wherein the ethylene copolymer comprises about 8 wt % to about 12 wt % of copolymerized units of the derivative of the second α,β-ethylenically unsaturated carboxylic acid.
5. The polymer composition of claim 1 , wherein the sum of the weight percentages of the copolymerized acid and of the copolymerized acid derivative is about 20 to about 45 wt %.
6. The polymer composition of claim 1 , wherein the α,β-ethylenically unsaturated carboxylic acid is acrylic acid, methacrylic acid, or a combination of acrylic acid and methacrylic acid.
7. The polymer composition of claim 1 , wherein the diol is 1,4-butanediol.
8. The polymer composition of claim 1 , wherein the amount of the diol is less than about 5 wt %, based on the total weight of the polymer composition.
9. The polymer composition of claim 1 , wherein the silane adjuvant comprises both N-(2 aminoethyl-3-aminopropyl) trimethoxysilane and 3-glycidoxypropyl trimethoxysilane; and wherein the amount of the silane adjuvant is between about 0.025 wt % and 2.0 wt %, based on the total weight of the polymer composition.
10. A product of cross-linking the polymer composition of claim 1 .
11. A sheet or film comprising the polymer composition of claim 1 or a product of cross-linking the polymer composition.
12. The film of claim 11 that is a blown film.
13. An injection molded article comprising the polymer composition of claim 1 or a product of cross-linking the polymer composition.
14. A golf ball comprising the polymer composition of claim 1 or a product of cross-linking the polymer composition.
15. A package comprising the sheet or film of claim 11 .
16. A sheet or film comprising the polymer composition of claim 9 or a product of cross-linking the polymer composition.
17. The film of claim 16 that is a blown film.
18. An injection molded article comprising the polymer composition of claim 9 or a product of cross-linking the polymer composition.
19. A golf ball comprising the polymer composition of claim 9 or a product of cross-linking the polymer composition.
20. A package comprising the sheet or film of claim 16 .