Lithium battery electrode and method of manufacturing the same
View Patent ↗A lithium battery according to the inventive concept may comprise a cathode, an anode separated from the cathode, a first separator disposed between the cathode and the anode, the first separator having first pores, a second separator disposed on the first separator, the second separator having second pores, and an electrolyte filling a gap between the cathode and the anode. Diameters of the second pores may be smaller than those of the first pores. A standard deviation of the diameters of the second pores is smaller than that of the first pores.
1. A lithium battery comprising:
a cathode;
an anode separated from the cathode;
a first separator disposed between the cathode and the anode, the first separator having first pores;
a second separator disposed on the first separator, the second separator having second pores; and
an electrolyte filling a gap between the cathode and the anode,
wherein diameters of the second pores are smaller than those of the first pores, and
a standard deviation of the diameters of the second pores is smaller than that of the first pores.
2. The lithium battery of claim 1 , wherein a distance between the second pores is smaller than a distance between the first pores.
3. The lithium battery of claim 1 , wherein at least some of the second pores are connected to the first pores; and
the second separator is in direct physical contact with the first separator.
4. The lithium battery of claim 1 , wherein the second separator faces the anode.
5. The lithium battery of claim 1 , further comprising a third separator that is disposed on the second separator and has third pores,
wherein diameters of the third pores are smaller than those of the first pores, and
a standard deviation of the diameters of the third pores is smaller than that of the first pores.
6. The lithium battery of claim 1 , wherein the second separator comprises a plurality of second separators, and
the plurality of second separators are disposed on the first separator.
7. A method of manufacturing a lithium battery, comprising:
preparing a first separator having first pores;
forming a second separator having second pores, on a temporary substrate; and
transferring the second separator onto the first separator,
wherein diameters of the second pores are smaller than those of the first pores, and
a standard deviation of the diameters of the second pores is smaller than that of the first pores.
8. The method of claim 7 , wherein a distance between the second pores is smaller than a distance between the first pores.
9. The method of claim 7 , wherein at least some of the second pores are connected to the first pores.
10. The method of claim 7 , further comprising:
preparing an anode;
preparing a cathode;
placing the first and second separators between the anode and the cathode; and
forming an electrolyte to fill a gap between the anode and the cathode.
11. The method of claim 10 , wherein the second separator faces the anode.
12. The method of claim 7 , further comprising forming a third separator that is disposed on the second separator and has third pores.
13. The method of claim 12 , wherein diameters of the third pores are smaller than those of the first pores, and
a standard deviation of the diameters of the third pores is smaller than that of the first pores.
14. The method of claim 12 , wherein diameters of the third pores are smaller than those of the second pores, and
a standard deviation of the diameters of the third pores is smaller than that of the second pores.
15. The method of claim 7 , wherein the second separator comprises a plurality of second separators, each of which is independently transferred onto the first separator.
16. The method of claim 7 , wherein the forming of the second separator comprises:
coating a block copolymer onto the temporary substrate to form a block copolymer film;
applying heat or light to the block copolymer film to form a first block portion and a second block portion; and
removing the second block portion to form the second pores exposing the temporary substrate.
17. The method of claim 7 , wherein the forming of the second separator comprises:
forming a carbon structure having oxygen-containing functional groups;
thermally treating the carbon structure to form pores;
adding the carbon structure into a solvent to form a precursor solution; and
coating the temporary substrate with the precursor solution.
18. The method of claim 7 , wherein the forming of the second separator comprises:
preparing a mold having a protruding portion;
forming a preliminary separator on the protruding portion of the mold; and
transferring the preliminary separator onto the temporary substrate.