Steel for carburizing, carburized steel component, and method of producing the same
View Patent ↗A steel for a carburizing and a carburized steel component having a steel portion and a carburized layer with a thickness of more than 0.4 mm to less than 2 mm which is formed on an outside of the steel portion. A chemical composition of the steel for the carburizing and the steel portion of the carburized steel component satisfies simultaneously equations of a hardness parameter, a hardenability parameter, and a TiC precipitation parameter.
1. A steel for a carburizing comprising as a chemical composition, by mass %,
C: 0.07% to 0.13%,
Si: 0.0001% to 0.50%,
Mn: 0.0001% to 0.80%,
S: 0.0001% to 0.100%,
Cr: more than 1.30% to 5.00%,
B: 0.0005% to 0.0100%,
Al: 0.105% to 0.200%,
N: 0.0030% to 0.0100%,
Ti: limited to 0.020% or less,
P: limited to 0.050% or less,
O: limited to 0.0030% or less, and
a balance consisting of iron and unavoidable impurities, wherein:
amounts expressed in mass % of each element in the chemical composition satisfy simultaneously a following Equation 1 as a hardness parameter, a following Equation 2 as a hardenability parameter, and a following Equation 3 as an AlN precipitation parameter;
a shape is a bar or a wire rod in which a cross section perpendicular to a longitudinal direction is round; and
when a distance from a periphery to a center of the cross section is defined as r in unit of mm, in a metallographic structure of a surface layer which is a portion from the periphery to r×0.01, a ferrite and a pearlite are limited before spheroidizing annealing, by area %, to 10% or less in total, and a balance includes at least one of martensite, bainite, tempered martensite, tempered bainite, and cementites,
0.10<C+0.194×Si+0.065×Mn+0.012×Cr+0.078×Al<0.235 (Equation 1)
7.5<(0.7×Si+1)×(5.1×Mn+1)×(2.16×Cr+1)<44 (Equation 2)
0.0003<Al×(N−Ti×(14/48))<0.0011 (Equation 3),
and
the hardness at a position at a depth which is ¼ of a diameter of the cross section from the periphery of the steel for carburizing measured before spheroidizing annealing is HV 125 or less.
2. The steel for the carburizing according to claim 1 , further comprising as the chemical composition, by mass %, at least one of
Nb: 0.002% to 0.100%,
V: 0.002% to 0.20%,
Mo: 0.005% to 0.50%,
Ni: 0.005% to 1.00%,
Cu: 0.005% to 0.50%,
Ca: 0.0002% to 0.0030%,
Mg: 0.0002% to 0.0030%,
Te: 0.0002% to 0.0030%,
Zr: 0.0002% to 0.0050%,
Rare Earth Metal: 0.0002% to 0.0050%, and
Sb: 0.002% to 0.050%,
wherein the hardness parameter is defined as a following Equation 4 on behalf of the Equation 1 and the hardenability parameter is defined as a following Equation 5 on behalf of the Equation 2,
0.10<C+0.194×Si+0.065×Mn+0.012×Cr+0.033×Mo+0.067×Ni +0.097×Cu+0.078×Al<0.235 (Equation 4),
7.5<( 0 . 7 ×Si+1)×(5.1×Mn+1)×(2.16×Cr+1)×(3×Mo+1)×(0.3633×Ni+1)<44 (Equation 5).
3. A steel for a carburizing comprising as a chemical composition, by mass %,
C: 0.07% to 0.13%,
Si: 0.0001% to 0.50%,
Mn: 0.0001% to 0.80%,
S: 0.0001% to 0.100%,
Cr: more than 1.30% to 5.00%,
B: 0.0005% to 0.0100%,
Al: 0.105% to 0.200%,
N: 0.0030% to 0.0100%,
Ti: limited to 0.020% or less,
P: limited to 0.050% or less,
O: limited to 0.0030% or less, and
a balance consisting of iron and unavoidable impurities, wherein:
amounts expressed in mass % of each element in the chemical composition satisfy simultaneously a following Equation 1 as a hardness parameter, a following Equation 2 as a hardenability parameter, and a following Equation 3 as an AlN precipitation parameter;
a shape is a bar or a wire rod in which a cross section perpendicular to a longitudinal direction is round; and
0.10<C+0.194×Si+ 0 . 065 ×Mn+0.012×Cr+0.078×Al<0.235 (Equation 1)
7.5<(0.7×Si+1)×(5.1×Mn+1)×(2.16×Cr+1)<44 (Equation 2)
0.0003<Al×(N−Ti×(14/48))<0.0011 (Equation 3),
and
when a distance from a periphery to a center of the cross section is defined as r in units of mm, in cementites included in a metallographic structure of a surface layer which is a portion from the periphery to r×0.01, the cementites of 90% to 100% are cementites whose aspect ratio is 3 or less, and the hardness at a position at a depth which is ¼ of a diameter of the cross section from the periphery of the steel for carburizing measured after spheroidizing annealing is HV 110 or less.
4. A method of producing the steel for the carburizing according to claim 1 , the method comprising,
a casting process to obtain a bloom,
a hot working process of hot-working the bloom to obtain a hot worked steel material, and
a slow cooling process of slow-cooling by a cooling rate of more than 0° C./s to 1° C./s in a temperature range where a surface temperature of the hot worked steel material is 800° C. to 500° C. after the hot working process.
5. The method of producing the steel for the carburizing according to claim 4 , the method further comprising,
a spheroidizing annealing process of spheroidizing-annealing the hot-worked steel material after the slow cooling process.
6. A method of producing the steel for the carburizing according to claim 1 , the method comprising,
a casting process to obtain a bloom,
a hot controlled rolling process of hot-rolling the bloom by controlling conditions so that a surface temperature at an exit side of a final finish rolling becomes 700° C. to 1000° C. to obtain a hot-controlled-rolled steel material,
a rapid cooling process of rapid-cooling so that the surface temperature of the hot-controlled-rolled steel material is more than 0° C. to 500° C. after the hot controlled rolling process, and
a heating process of heating the hot-controlled-rolled steel material after the rapid cooling process at least one time or more.
7. The method of producing the steel for the carburizing according to claim 6 , the method further comprising,
a spheroidizing annealing process of spheroidizing-annealing the hot-controlled-rolled steel material after the heating process.
8. A method of producing the steel for the carburizing according to claim 2 , the method comprising,
a casting process to obtain a bloom,
a hot working process of hot-working the bloom to obtain a hot worked steel material, and
a slow cooling process of slow-cooling by a cooling rate of more than 0° C./s to 1° C./s in a temperature range where a surface temperature of the hot worked steel material is 800° C. to 500° C. after the hot working process.
9. The method of producing the steel for the carburizing according to claim 8 , the method further comprising,
a spheroidizing annealing process of spheroidizing-annealing the hot-worked steel material after the slow cooling process.
10. A method of producing the steel for the carburizing according to claim 2 , the method comprising,
a casting process to obtain a bloom,
a hot controlled rolling process of hot-rolling the bloom by controlling conditions so that a surface temperature at an exit side of a final finish rolling becomes 700° C. to 1000° C. to obtain a hot-controlled-rolled steel material,
a rapid cooling process of rapid-cooling so that the surface temperature of the hot-controlled-rolled steel material is more than 0° C. to 500° C. after the hot controlled rolling process, and
a heating process of heating the hot-controlled-rolled steel material after the rapid cooling process at least one time or more.
11. The method of producing the steel for the carburizing according to claim 10 , the method further comprising,
a spheroidizing annealing process of spheroidizing-annealing the hot-controlled-rolled steel material after the heating process.
12. The steel for the carburizing according to claim 3 , further comprising as the chemical composition, by mass %, at least one of
Nb: 0.002% to 0.100%,
V: 0.002% to 0.20%,
Mo: 0.005% to 0.50%,
Ni: 0.005% to 1.00%,
Cu: 0.005% to 0.50%,
Ca: 0.0002% to 0.0030%,
Mg: 0.0002% to 0.0030%,
Te: 0.0002% to 0.0030%,
Zr: 0.0002% to 0.0050%,
Rare Earth Metal: 0.0002% to 0.0050%, and
Sb: 0.002% to 0.050%,
wherein the hardness parameter is defined as a following Equation 4 on behalf of the Equation 1 and the hardenability parameter is defined as a following Equation 5 on behalf of the Equation 2,
0.10<C+0.194×Si+0.065×Mn+0.012×Cr+0.033×Mo+0.067×Ni+0.097×Cu+0.078×Al<0.235 (Equation 4),
7.5<(0.7×Si+1)×(5.1×Mn+1)×(2.16×Cr+1)×(3×Mo+1)×(0.3633×Ni+1)<44 (Equation 5).
13. A steel for a carburizing comprising as a chemical composition, by mass %,
C: 0.07% to 0.13%,
Si: 0.0001% to 0.50%,
Mn: 0.0001% to 0.80%,
S: 0.0001% to 0.100%,
Cr: more than 1.30% to 5.00%,
B: 0.0005% to 0.0100%,
Al: 0.105% to 0.200%,
N: 0.0030% to 0.0100%,
Ti: limited to 0.020% or less,
P: limited to 0.050% or less,
O: limited to 0.0030% or less, and
a balance comprising iron and unavoidable impurities, wherein:
amounts expressed in mass % of each element in the chemical composition satisfy simultaneously a following Equation 1 as a hardness parameter, a following Equation 2 as a hardenability parameter, and a following Equation 3 as an MN precipitation parameter;
a shape is a bar or a wire rod in which a cross section perpendicular to a longitudinal direction is round; and
when a distance from a periphery to a center of the cross section is defined as r in unit of mm, in a metallographic structure of a surface layer which is a portion from the periphery to r×0.01, a ferrite and a pearlite are limited before spheroidizing annealing, by area %, to 10% or less in total, and a balance includes at least one of martensite, bainite, tempered martensite, tempered bainite, and cementites,
0.10<C+0.194×Si+0.065×Mn+0.012×Cr+0.078×Al<0.235 (Equation 1)
7.5<(0.7×Si+1)×(5.1×Mn+1)×(2.16×Cr+1)<44 (Equation 2)
0.0003<Al×(N−Ti×(14/48))<0.0011 (Equation 3),
and
the hardness at a position at a depth which is ¼ of a diameter of the cross section from the periphery of the steel for carburizing measured before spheroidizing annealing is HV 125 or less.
14. A steel for a carburizing comprising as a chemical composition, by mass %,
C: 0.07% to 0.13%,
Si: 0.0001% to 0.50%,
Mn: 0.0001% to 0.80%,
S: 0.0001% to 0.100%,
Cr: more than 1.30% to 5.00%,
B: 0.0005% to 0.0100%,
Al: 0.105% to 0.200%,
N: 0.0030% to 0.0100%,
Ti: limited to 0.020% or less,
P: limited to 0.050% or less,
O: limited to 0.0030% or less, and
a balance comprising iron and unavoidable impurities, wherein:
amounts expressed in mass % of each element in the chemical composition satisfy simultaneously a following Equation 1 as a hardness parameter, a following Equation 2 as a hardenability parameter, and a following Equation 3 as an AlN precipitation parameter;
a shape is a bar or a wire rod in which a cross section perpendicular to a longitudinal direction is round; and
0.10<C+0.194×Si+0.065×Mn+0.012×Cr+0.078×Al<0.235 (Equation 1)
7.5<(0.7×Si+1)×(5.1×Mn+1)×(2.16×Cr+1)<44 (Equation 2)
0.0003<Al×(N−Ti×(14/48))<0.0011 (Equation 3),
and
when a distance from a periphery to a center of the cross section is defined as r in units of mm, in cementites included in a metallographic structure of a surface layer which is a portion from the periphery to r×0.01, the cementites of 90% to 100% are cementites whose aspect ratio is 3 or less, and the hardness at a position at a depth which is ¼ of a diameter of the cross section from the periphery of the steel for carburizing measured after spheroidizing annealing is HV 110 or less.