Processes and systems for producing nanocellulose from old corrugated containers
View Patent ↗In some variations, OCC is screened, cleaned, deinked, and mechanically refined to generate cellulose nanofibrils. The OCC may be subjected to further chemical, physical, or thermal processing, prior to mechanical refining. For example, the OCC may be subjected to hot-water extraction, or fractionation with an acid catalyst, a solvent for lignin, and water. In certain embodiments to produce cellulose nanocrystals, OCC is exposed to AVAP® digestor conditions. The resulting pulp is optionally bleached and is mechanically refined to generate cellulose nanocrystals. In certain embodiments to produce cellulose nanofibrils, OCC is exposed to GreenBox+® digestor conditions. The resulting pulp is mechanically refined to generate cellulose nanofibrils. The site of a system to convert OCC to nanocellulose may be co-located with an existing OCC processing site. The nanocellulose line may be a bolt-on retrofit system to existing infrastructure. In other embodiments, a dedicated plant for converting OCC to nanocellulose is used.
1. A process for producing cellulose nanofibrils and/or cellulose nanocrystals from old corrugated containers, said process comprising:
(a) providing a feedstock comprising old corrugated containers;
(b) screening and cleaning said feedstock to remove one or more non-cellulosic components contained in said feedstock, to generate a cleaned feedstock;
(c) digesting said cleaned feedstock with an acid catalyst, a solvent for lignin, and water, to generate a treated feedstock;
(d) optionally bleaching said treated feedstock;
(e) mechanically refining said treated feedstock to generate cellulose nanofibrils and/or cellulose nanocrystals; and
(f) optionally bleaching said cellulose nanofibrils and/or cellulose nanocrystals.
2. The process of claim 1 , wherein said one or more non-cellulosic components removed in step (b) include components selected from the groups consisting of solvents, resins, lubricants, solubilizers, surfactants, particulate matter, pigments, dyes, fluorescents, and combinations thereof.
3. The process of claim 1 , wherein said acid catalyst is a sulfur-containing acid, and wherein said sulfur-containing acid is optionally sulfur dioxide.
4. The process of claim 1 , wherein step (d) is carried out.
5. The process of claim 1 , wherein step (f) is carried out.
6. The process of claim 1 , wherein cellulase enzymes are introduced to said process.
7. The process of claim 6 , wherein said cellulase enzymes are introduced during step (b).
8. The process of claim 6 , wherein said cellulase enzymes are introduced between step (c) and step (e).
9. The process of claim 6 , wherein said cellulase enzymes are introduced during step (e), and wherein step (e) optionally includes multiple stages of mechanical refining.
10. The process of claim 1 , said process further comprising introducing said cellulose nanofibrils and/or cellulose nanocrystals to a material comprising corrugating medium pulp.