IP Library Granted Patent US 10,427,003
Granted Patent B2
US 10,427,003 · App. 15/635,405 · Granted Oct 1, 2019

Golf ball having at least one layer consisting of a mixture of a thermoset or thermoplastic composition and a plurality of alkoxylated siloxane-surface treated particles and/or polyether-modified siloxane-surface treated particles

Inventors: Michael J. Sullivan (Old Lyme, CT); Brian Comeau (Berkley, MA); Michael Michalewich (Norton, MA)
Assignee: Acushnet Company
A63B37/0022A63B37/0024A63B37/0027A63B37/0031A63B37/0033A63B37/0062A63B37/0064A63B37/0065A63B37/0078A63B37/0082A63B37/0091A63B37/0093B32B5/18B32B27/40C08G18/10C08G18/4854C08K3/22C08K3/30C08K9/06C08K9/08C09D175/02C09D175/04C09D201/00A63B2037/0079B32B2266/0278C08K2003/2241C08K2003/2296C08K2003/3036C08K2003/3045
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Quick Facts
Patent No.
US 10,427,003
App. No.
15/635,405
Granted
Oct 1, 2019
Kind
B2
Abstract

Golf ball having CoR of at least 0.700 and Atti compression of at least about 50 and comprising layer consisting of mixture of thermoset or thermoplastic composition and plurality of particulates, at least a portion surface-treated with alkoxylated siloxanes and/or polyether-modified siloxanes, and may be selected from titanium dioxide particles, barium sulfate particles, zinc sulfide particles, and/or zinc oxide particulates. At least some particulates are contacted with compound having the formula: Compound (I) may be included in amount of 0.01 to 2% by weight based on total weight of portion of plurality being contacted. The plurality may be included in mixture in amount such that layer has specific gravity of from 0.5 to about 10.0, tensile strength of from about 300 psi to about 50,000 psi, and elongation at break of from about 20% to about 1000%, each being greater than that of the thermoset or thermoplastic composition portion of the mixture.

Claims (17)

1. A golf ball having a CoR of at least 0.700 and an Atti compression of at least about 50 and comprising at least one layer comprising a mixture of a polyurethane composition and a plurality of titanium dioxide particulates, wherein at least a portion of the plurality is surface-treated with alkoxylated siloxanes, polyether-modified siloxanes, or combinations thereof;

wherein the plurality of titanium dioxide particulates is included in the mixture in an amount such that the cover layer has a specific gravity of from 0.5 to about 5.0 and greater than a specific gravity of the polyurethane composition; and

wherein the plurality of titanium dioxide particulates creates a specific gravity gradient within the cover layer.

2. The golf ball of claim 1 , wherein at least a portion of the plurality of particulates are contacted with at least one compound having the formula

wherein: R identically or differently is R 1 , methyl or hydroxyl; R 1 is identically or differently a polyether moiety of formula —Z—(O—C m H 2m -(n−1)) o -[O-(AO)—R 3 ] n ;

wherein: Z is a branched alkylene moiety or an unbranched alkylene moiety having from 2 to 4 carbon atoms; m is from 2 to 4; n is from 1 to 3; o is 0 or 1; AO identically or differently is an oxyalkylene moiety comprising an oxyethylene moiety, an oxypropylene moiety, and/or an oxybutylene moiety moieties; R 3 identically or differently is hydrogen or an alkyl moiety having from 1 to 4 carbon atoms; and in R 1 a total number of carbon atoms and oxygen atoms is at least 70; a is from 20 to 200; and b is from 1 to 50; and wherein if none of moieties R is R 1 , then b is at least 3; and

wherein the compound of the formula (I) is included in an amount of 0.01 to 2% by weight based on the total weight of the portion of particles contacted with the compound.

3. The golf ball of claim 2 , wherein 100 wt % of the plurality of titanium dioxide particulates is contacted with the compound.

4. The golf ball of claim 2 , wherein 50 wt % or greater of the plurality of titanium dioxide particulates is contacted with the compound.

5. The golf ball of claim 2 , wherein less than 50 wt % of the plurality of titanium dioxide particulates is contacted with the compound.

6. The golf ball of claim 1 , wherein the plurality of titanium dioxide particulates is included in the mixture in an amount of up to about 25 wt % of the total weight of the mixture.

7. The golf ball of claim 1 , wherein the plurality of titanium dioxide particulates is included in the mixture in an amount of greater than 10 wt % of the total weight of the mixture.

8. The golf ball of claim 1 , wherein the mixture has a tensile strength of from about 300 psi to about 50,000 psi and greater than a tensile strength of the polyurethane composition.

9. The golf ball of claim 8 , wherein the mixture has an elongation at break of from about 20% to about 1000% and greater than an elongation at break of the polyurethane composition.

10. The golf ball of claim 1 , wherein the at least one layer has an MVTR that is less than an MVTR of an adjacent inner layer consisting of the polyurethane composition.

11. The golf ball of claim 1 , wherein the golf ball has a moment of inertia of from about 70 g·cm 2 to about 95 g·cm 2 .

12. The golf ball of claim 1 , wherein the polyurethane composition comprises a polyurethane foam.

Assignments (4)
ASSIGNMENT OF SECURITY INTEREST IN PATENTS (ASSIGNS 051618-0777) Recorded Aug 3, 2022
From: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS RESIGNING ADMINISTRATIVE AGENT
To: JPMORGAN CHASE BANK, N.A., AS SUCCESSOR ADMINISTRATIVE AGENT
Reel/Frame 061069/0731 →
SECURITY INTEREST Recorded Aug 3, 2022
From: ACUSHNET COMPANY
To: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 061099/0236 →
SECURITY INTEREST Recorded Jan 15, 2020
From: ACUSHNET COMPANY
To: WELLS FARGO BANK, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 051618/0777 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 28, 2017
From: SULLIVAN, MICHAEL J.; COMEAU, BRIAN; MICHALEWICH, MICHAEL
To: ACUSHNET COMPANY
Reel/Frame 042838/0104 →
Continuity (1)
Related Publication 20190001191A1 · Jan 3, 2019