Positive electrode for lithium secondary battery and method for preparing the same
Disclosed is a positive electrode for a lithium secondary battery which uses a positive electrode active material containing secondary particles with a relatively weak particle strength to improve the adhesion between a positive electrode mixture layer and a current collector, and the positive electrode includes a positive electrode current collector; a primer coating layer including a first polymer binder and a first conductive material, having surface roughness (R a ) of 85 nm to 300 nm and formed on at least one surface of the positive electrode current collector; and a positive electrode mixture layer formed on an upper surface of the primer coating layer and including a positive electrode active material containing secondary particles with a compressive breaking strength of 1 to 15 MPa, a second polymer binder and a second conductive material.
1. A positive electrode for a lithium secondary battery, comprising:
a positive electrode current collector comprising aluminum;
a primer coating layer consisting essentially of a first polymer binder and a first conductive material, having surface roughness (R a ) of 90 nm to 200 nm and formed on at least one surface of the positive electrode current collector; and
a positive electrode mixture layer formed on a surface of the primer coating layer opposite from the current collector and including a positive electrode active material containing secondary particles with a compressive breaking strength of 1 to 15 MPa, a second polymer binder and a second conductive material.
2. The positive electrode for a lithium secondary battery according to claim 1 ,
wherein the secondary particles have a compressive breaking strength of 4 to 11 MPa.
3. The positive electrode for a lithium secondary battery according to claim 1 ,
wherein the secondary particles are aggregates of primary particles, the primary particles have an average particle diameter of 0.2 to 1.0 μm, and the secondary particles have an average particle diameter of 3.1 to 22.4 μm.
4. The positive electrode for a lithium secondary battery according to claim 1 ,
wherein the primer coating layer has a thickness of 0.3 μm to 1 μm.
5. The positive electrode for a lithium secondary battery according to claim 1 ,
wherein the first conductive material and the first polymer binder are included at a weight ratio of 0.8:1 to 2:1.
6. The positive electrode for a lithium secondary battery according to claim 1 ,
wherein the first polymer binder is an acrylate-based polymer.
7. The positive electrode for a lithium secondary battery according to claim 1 ,
wherein the second polymer binder is at least one selected from the group consisting of polyvinylidene fluoride-hexafluoropropylene, polyvinylidene fluoride, polyacrylonitrile, polymethyl methacrylate, styrene-butadiene rubber and carboxymethyl cellulose.
8. The positive electrode for a lithium secondary battery according to claim 1 ,
wherein the first conductive material is a carbon-based material.
9. The positive electrode for a lithium secondary battery according to claim 1 ,
wherein the positive electrode mixture layer has a compressive density of 1.8 g/cm 3 to 4.4 g/cm 3 .
10. A method for preparing a positive electrode for a lithium secondary battery, comprising:
preparing slurry for forming a primer coating layer, which includes a first polymer binder, a first conductive material and a first solvent;
preparing a positive electrode active material slurry including a second polymer binder, a positive electrode active material containing secondary particles with a compressive breaking strength of 1 to 15 MPa, a second conductive material, and a second solvent;
forming a primer coating layer having a surface roughness (R a ) of 90 nm to 200 nm consisting essentially of the first polymer binder and the first conductive material by coating and drying the slurry for forming a primer coating layer on at least one surface of the positive electrode current collector comprising aluminum; and
forming a positive electrode active material layer by coating and drying the positive electrode active material slurry on a surface of the primer coating layer opposite from the current collector where the slurry for forming a primer coating layer is coated,
wherein the first solvent is an organic solvent and the second solvent is a water-based solvent, or the first solvent is a water-based solvent and the second solvent is an organic solvent.
11. The method for preparing a positive electrode for a lithium secondary battery according to claim 10 ,
wherein the organic solvent is at least one selected from the group consisting of propylene carbonate (PC), ethylene carbonate (EC), diethyl carbonate (DEC), dimethyl carbonate (DMC), dipropyl carbonate (DPC), dimethyl sulfoxide, acetonitrile, dimethoxyethane, diethoxyethane, tetrahydrofuran, N-methyl-2-pyrrolidone (NMP), ethyl methyl carbonate (EMC), gamma butyrolactone (GBL), fluoroethylene carbonate (FEC), methyl formate, ethyl formate, propyl formate, methyl acetate, ethyl acetate, propyl acetate, pentyl acetate, methyl propionate, ethyl propionate, propyl propionate and butyl propionate, and the water-based solvent is at least one selected from the group consisting of water, methanol, ethanol, ethylene glycol, diethylene glycol and glycerol.