Propylene polymer-based hot melt adhesive composition exhibiting fast set time and articles including the same
View Patent ↗A hot melt adhesive composition that includes at least 35% polymer, from about 15% by weight, to no greater than 75% by weight propylene polymer derived from at least 50% by weight propylene and from 0 mole % to about 37.5% by weight of an alpha-olefin comonomer other than propylene, the propylene polymer exhibiting a heat of fusion of from about 5 Joules per gram (J/g) to 60 J/g, from 5% by weight to about 50% by weight ethylene alpha-olefin copolymer derived from at least 50% by weight ethylene and at least one alpha-olefin comonomer having at least three carbon atoms, the ethylene alpha-olefin copolymer having a density of no greater than 0.90 g/cm 3 , and from 18% by weight to about 37% by weight of a wax component that exhibits a melting point greater than 80° C. and a heat of fusion of at least 200 J/g.
1. A hot melt adhesive composition comprising:
from about 15% by weight to no greater than 75% by weight propylene polymer derived from at least 50% by weight propylene, based on the weight of the propylene polymer, and optionally an alpha-olefin comonomer other than propylene, the propylene polymer exhibiting a heat of fusion of from about 5 Joules per gram (J/g) to 60 J/g;
from 5% by weight to about 50% by weight ethylene alpha-olefin copolymer derived from at least 50% by weight ethylene, based on the weight of the ethylene alpha-olefin polymer, and at least one alpha-olefin comonomer having at least three carbon atoms, the ethylene alpha-olefin copolymer having a density of no greater than 0.90 g/cm 3 ;
at least 35% by weight of a polymer selected from the group consisting of the propylene polymer, the ethylene alpha-olefin copolymer, and combinations thereof, and
from 18% by weight to about 37% by weight of a wax component exhibiting a melting point greater than 80° C. and a heat of fusion of at least 200 J/g,
the composition exhibiting a set time of no greater than 1.5 seconds at an application temperature of at least 149° C.
2. The hot melt adhesive composition of claim 1 , wherein the propylene polymer exhibits a melt temperature of no greater than 126° C.
3. The hot melt adhesive composition of claim 1 , wherein the propylene polymer exhibits a melt temperature of no greater than 120° C.
4. The hot melt adhesive composition of claim 1 , wherein the propylene polymer exhibits a melt temperature of no greater than 110° C.
5. The hot melt adhesive composition of claim 1 , wherein the wax is selected from the group consisting of Fischer Tropsch wax, polyethylene wax, and combinations thereof.
6. The hot melt adhesive composition of claim 1 , wherein the wax component comprises at least 15% by weight, based on the weight of the adhesive composition, of a wax that exhibits a melting point greater than 80° C. and a heat of fusion of at least 200 J/g and is selected from the group consisting of Fischer Tropsch wax, polyethylene wax, and combinations thereof.
7. The hot melt adhesive composition of claim 1 comprising from about 10% by weight to about 35% by weight of the ethylene alpha-olefin copolymer.
8. The hot melt adhesive composition of claim 1 , wherein the hot melt adhesive composition comprises
from about 15% by weight to about 55% by weight of the propylene polymer,
from about 10% by weight to about 32% by weight of the ethylene alpha-olefin copolymer, and
from about 19% by weight to about 35% by weight of the wax component, and
further comprises from about 10% by weight to about 35% by weight tackifying agent.
9. The hot melt adhesive composition of claim 1 , wherein the hot melt adhesive composition comprises
from about 15% by weight to about 50% by weight of the propylene polymer,
from about 10% by weight to about 30% by weight of the ethylene alpha-olefin copolymer, and
from 25% by weight to about 35% by weight of the wax component, and
further comprises from about 15% by weight to about 35% by weight tackifying agent.
10. The hot melt adhesive composition of claim 9 , wherein the tackifying agent has a Ring and Ball softening point of at least 120° C.
11. The hot melt adhesive composition of claim 1 , wherein the hot melt adhesive composition exhibits a specific gravity of no greater than 0.93.
12. The hot melt adhesive composition of claim 3 , wherein the hot melt adhesive composition comprises
from about 15% by weight to about 70% by weight of the propylene polymer,
from about 10% by weight to about 35% by weight of the ethylene alpha-olefin copolymer, and
from about 19% by weight to about 35% by weight of the wax component.
13. The hot melt adhesive composition of claim 1 , wherein the hot melt adhesive exhibits a set time of no greater than 1.0 second at an application temperature of at least 135° C.
14. The hot melt adhesive composition of claim 1 , wherein the hot melt adhesive exhibits a set time of no greater than 0.8 seconds at an application temperature of at least 135° C.
15. The hot melt adhesive composition of claim 1 , wherein the hot melt adhesive exhibits a set time of no greater than 0.7 seconds at an application temperature of at least 135° C.
16. The hot melt adhesive composition of claim 1 , wherein the hot melt adhesive exhibits a peel adhesion failure temperature of at least 50° C.
17. The hot melt adhesive composition of claim 1 , wherein the propylene polymer exhibits a Tg no greater than 0° C.
18. The hot melt adhesive composition of claim 1 , wherein the hot melt adhesive composition exhibits at least 50% fiber tear at −43° C. and at least 50% fiber tear at 55° C.
19. The hot melt adhesive composition of claim 1 , comprising from 10% by weight to 20% by weight of the ethylene alpha-olefin copolymer.
20. The hot melt adhesive composition of claim 1 , wherein the propylene polymer comprises a propylene-alpha olefin polymer derived from at least 50% by weight propylene, based on the weight of the propylene polymer, and from about 1 mole % to about 37.5 mole % of an alpha-olefin comonomer, based on the molar mass of the propylene polymer.
21. An article comprising:
a first substrate;
the hot melt adhesive composition of claim 1 ; and
a second substrate bonded to the first substrate through the adhesive composition.
22. A hot melt adhesive composition comprising:
from about 15% by weight to no greater than 75% by weight propylene polymer derived from at least 50% by weight propylene, based on the weight of the propylene polymer, and optionally an alpha-olefin comonomer other than propylene, the propylene polymer exhibiting a heat of fusion of from about 5 J/g to 60 J/g and a melt temperature of no greater than 120° C.;
from 5% by weight to about 50% by weight ethylene alpha-olefin copolymer derived from at least 50% by weight ethylene, based on the weight of the ethylene alpha-olefin polymer, and at least one alpha-olefin comonomer having at least three carbon atoms, the ethylene alpha-olefin copolymer having a density of no greater than 0.90 g/cm 3 ;
at least 35% by weight of a polymer selected from the group consisting of the propylene polymer, the ethylene alpha-olefin copolymer, and combinations thereof, and
from at least 15% by weight to about 37% by weight of at least one wax that exhibits a melting point greater than 80° C. and a heat of fusion of at least 200 J/g, the at least one wax being selected from the group consisting of Fischer Tropsch wax, polyethylene wax, and combinations thereof,
the composition exhibiting a set time of no greater than 1.5 seconds at an application temperature of at least 149° C.
23. The hot melt adhesive composition of claim 22 , wherein the propylene polymer comprises a propylene-alpha olefin polymer derived from at least 50% by weight propylene, based on the weight of the propylene polymer, and from about 1 mole % to about 37.5 mole % of an alpha-olefin comonomer, based on the molar mass of the propylene polymer.