Water quality measurement apparatus and method
View Patent ↗A water quality measurement apparatus is provided. The apparatus comprises an electrochemical cell, a pH sensor, a temperature sensor, a control circuit, a power source, a database, and a warning device. The electrochemical cell comprises a working electrode, a reference electrode, and a counter electrode. The control circuit provides predetermined adjustable potentials between the reference electrode and the working electrode and measures electrochemical currents between the working electrode and the counter electrode, to form a current diagram based on the predetermined adjustable potentials and the electrochemical currents. The database stores predetermined reference diagrams based on various pH values and temperatures, and is in communication with the control circuit. The warning device is configured to output warnings, wherein the control circuit triggers the warning device in the condition that the current diagram exceeds the predetermined reference diagram based on the same range of the pH values and the temperatures.
1. A water quality measurement apparatus, comprising:
an electrochemical cell, comprising a working electrode, a reference electrode, and a counter electrode, wherein the working electrode, the reference electrode, and the counter electrode are configured to be inserted into water to be detected,
a pH sensor, configured to detect pH values of the water and to provide a pH signal reflecting the pH values of the detected water to a control circuit,
a temperature sensor, configured to detect temperatures of the water, and to provide a temperature signal reflecting the temperatures of the detected water to the control circuit,
the control circuit, electrically connected to the electrochemical cell, the pH sensor, and the temperature sensor, wherein the control circuit is configured to provide predetermined adjustable potentials between the reference electrode and the working electrode and to measure electrochemical currents between the working electrode and the counter electrode, to periodically form a current diagram based on the predetermined adjustable potentials and the electrochemical currents,
a power source, providing power to the control circuit,
a database, storing predetermined reference diagrams based on various pH values and temperatures, and being in communication with the control circuit, and
a warning device, being in communication with the control circuit and configured to output warnings, wherein the control circuit triggers the warning device in the condition that the current diagram exceeds the predetermined reference diagram based on the same range of the pH values and the temperature values,
wherein the predetermined adjustable potentials are underpotentials.
2. The water quality measurement apparatus of claim 1 further comprising a flow sensor, electrically connected to the control circuit, and configured to detect flow rates of the water and to provide a flow rate signal reflecting the flow rates of the detected water to the control circuit, wherein the control circuit calibrates the current diagram based on the flow rates.
3. The water quality measurement apparatus of claim 2 , wherein the control circuit is at its standby mode when the flow rate is lower than a predetermined threshold; the control circuit is at its detecting mode when the flow rate is higher than the predetermined threshold.
4. The water quality measurement apparatus of claim 1 , wherein the control circuit provides a first predetermined adjustable potential for a first time period and a second predetermined adjustable potential for a second time period, wherein the current diagram is a time-current diagram formed during the second time period.
5. The water quality measurement apparatus of claim 4 , wherein the first predetermined adjustable potential is opposite to the second predetermined adjustable potential.
6. The water quality measurement apparatus of claim 1 , wherein the predetermined adjustable potentials are cyclic voltammetry potentials.
7. The water quality measurement apparatus of claim 1 , wherein the current diagram is a cyclic voltammetry diagram.