Crosslinked coating compositions for packaging articles such as food and beverage containers
View Patent ↗A method of forming a coating on a food or beverage container, which includes spraying a coating composition onto an interior surface of the food or beverage container, where the coating composition includes a latex copolymer and a metal drier or crosslinking agent. The latex copolymer is a reaction product of monomers that include (a) one or more styrene-offset monomers containing one or more cyclic groups and one or more ethylenically-unsaturated pendant groups, at least a portion of such styrene-offset monomers being polycyclic monomers containing ring unsaturation, and (b) one or more other ethylenically-unsaturated monomers. Preferably, the coating composition is substantially free of BPA, PVC, and styrene. The method may also include curing the sprayed coating composition, thereby providing the coating on the interior surface of the food or beverage container.
1. A method of forming a coating on a food or beverage container, the method comprising:
receiving a coating composition having an emulsion-polymerized latex copolymer dispersed in an aqueous carrier and mixed with one or both of a metal drier or crosslinking agent, wherein the emulsion-polymerized latex polymer is a reaction product of monomers comprising:
one or more styrene-offset monomers containing one or more cyclic groups and one or more ethylenically-unsaturated pendant groups, at least a portion of such styrene-offset monomers comprising norbornene (meth)acrylate, tricyclodecenyl (meth)acrylate, octahydronaphthalene (meth)acrylate, norbornene (meth)acrylamide, tricyclodecenyl (meth)acrylamide, octahydronaphthalene (meth)acrylamide, tricyclodecenyl vinyl acetate, norbornene vinyl acetate, octahydronaphthalene vinyl acetate, or a combination thereof, and
one or more other ethylenically-unsaturated monomers; and
applying the coating composition to a substrate prior to or after forming the substrate into a food or beverage container, or a portion thereof.
2. The method of claim 1 , wherein applying the coating composition to the substrate comprises:
spraying the coating composition onto an interior surface of the food or beverage container; and
curing the sprayed coating composition to substantially remove the aqueous carrier, and provide the coating on the interior surface of the food or beverage container.
3. The method of claim 2 , wherein the average viscosity of the coating composition ranges from about 15 seconds to about 25 seconds, pursuant to the Viscosity Test.
4. The method of claim 2 , wherein the coating composition is spray applied onto an interior surface of an aluminum beverage can including a body portion and a bottom end portion, and where the cured coating has a coating thickness ranging of from about 0.7 milligrams/square-inch (mg/inch) to about 2.5 mg/inch 2 .
5. The method of claim 1 , wherein the monomers used to produce the emulsion-polymerized latex copolymer are substantially free of BPA, PVC and halogenated monomers.
6. The method of claim 1 , wherein the monomers used to produce the emulsion-polymerized latex copolymer are substantially free of styrene.
7. The method of claim 1 , wherein the polycyclic monomers containing ring unsaturation constitute at least 10% by weight of the monomers used to produce the emulsion-polymerized latex copolymer.
8. The method of claim 1 , wherein the polycyclic monomers containing ring unsaturation constitute less than 50% by weight of the monomers used to produce the emulsion-polymerized latex copolymer.
9. The method of claim 1 , wherein the one or more other ethylenically-unsaturated monomers are each substantially free of cyclic groups.
10. The method of claim 1 , wherein the one or more other ethylenically-unsaturated monomers comprise:
one or more ethylenically-unsaturated, acid-functional monomers;
one or more non-cyclic (meth)acrylates; or
combinations thereof.
11. The method of claim 10 , wherein the one or more ethylenically-unsaturated, acid-functional monomers constitute at least 3% by weight of the emulsion-polymerized latex copolymer, based on the total weight of the monomers used to produce the emulsion-polymerized latex copolymer.
12. The method of claim 10 , wherein the one or more non-cyclic (meth)acrylates have a concentration ranging from 10% by weight to 70% by weight, based on the total weight of the monomers used to produce the emulsion-polymerized latex copolymer.
13. The method of claim 1 , wherein the one or more other ethylenically-unsaturated monomers further comprise one or more multi-functional monomers having two or more ethylenically-unsaturated groups.
14. The method of claim 1 , wherein the one or more other ethylenically-unsaturated monomers further comprise one or more polymerizable surfactants.
15. The method of claim 1 , wherein the latex copolymer becomes crosslinked by reacting with itself in the presence of the metal drier.
16. The method of claim 1 , wherein the latex copolymer becomes crosslinked by reacting with the crosslinking agent.
17. The method of claim 1 , wherein the coating has a glass transition temperature greater than 50° C.
18. The method of claim 1 , wherein the glass transition temperature of the coating ranges from about 60° C. to about 120° C.
19. A method of forming a coating on a food or beverage container, the method comprising:
receiving a coating composition having an emulsion-polymerized latex copolymer dispersed in an aqueous carrier and mixed with one or both of a metal drier or crosslinking agent, wherein the emulsion-polymerized latex polymer is a reaction product of monomers comprising:
one or more monomers containing one or more cyclic groups and one or more ethylenically-unsaturated pendant groups, at least a portion of such monomers being polycyclic monomers comprising octahydronaphthalene (meth)acrylate, norbornene (meth)acrylamide, tricyclodecenyl (meth)acrylamide, octahydronaphthalene (meth)acrylamide, tricyclodecenyl vinyl acetate, norbornene vinyl acetate, octahydronaphthalene vinyl acetate, or a mixture thereof, and
one or more other ethylenically-unsaturated monomers; and
applying the coating composition to a substrate prior to or after forming the substrate into a food or beverage container, or a portion thereof.
20. The method of claim 19 , wherein applying the coating composition to the substrate comprises:
spraying the coating composition onto an interior surface of the food or beverage container; and
curing the sprayed coating composition to substantially remove the aqueous carrier, and provide the coating on the interior surface of the food or beverage container.
21. The method of claim 20 , wherein the average viscosity of the coating composition ranges from about 15 seconds to about 25 seconds, pursuant to the Viscosity Test.
22. The method of claim 20 , wherein the coating composition is spray applied onto an interior surface of an aluminum beverage can including a body portion and a bottom end portion, and where the cured coating has a coating thickness ranging of from about 0.7 milligrams/square-inch (mg/inch) to about 2.5 mg/inch.
23. The method of claim 19 , wherein the monomers used to produce the emulsion-polymerized latex copolymer are substantially free of BPA, PVC, styrene, and halogenated monomers.
24. The method of claim 19 , wherein the polycyclic monomers containing ring unsaturation constitute at least 10% and less than 50% by weight of the monomers used to produce the emulsion-polymerized latex copolymer.
25. The method of claim 24 , wherein the one or more other ethylenically-unsaturated monomers comprise:
at least 3% of one or more ethylenically-unsaturated, acid-functional monomers based on the total weight of the monomers used to produce the emulsion-polymerized latex copolymer;
from 10% by weight to 70% by weight of one or more non-cyclic (meth)acrylates based on the total weight of the monomers used to produce the emulsion-polymerized latex copolymer; or
combinations thereof.
26. The method of claim 24 , wherein the coating has a glass transition temperature ranging from about 60° C. to about 120° C.
27. The method of claim 19 , wherein the one or more other ethylenically-unsaturated monomers further comprise:
one or more multi-functional monomers having two or more ethylenically-unsaturated groups;
one or more polymerizable surfactants; or
a combination thereof.
28. The method of claim 19 , wherein the latex copolymer becomes crosslinked by reacting with the crosslinking agent.
29. A method of forming a coating on a food or beverage container, the method comprising:
receiving a coating composition having an emulsion-polymerized latex copolymer dispersed in an aqueous carrier and mixed with one or both of a metal drier or crosslinking agent, wherein the emulsion-polymerized latex polymer is a reaction product of monomers comprising:
one or more monomers containing one or more cyclic groups and one or more ethylenically-unsaturated pendant groups, at least a portion of such monomers being polycyclic monomers comprising norbornene (meth)acrylate or tricyclodecenyl (meth)acrylate, and
one or more other ethylenically-unsaturated monomers; and
applying the coating composition to a substrate prior to or after forming the substrate into a food or beverage container, or a portion thereof.