IP Library Granted Patent US 10,418,638
Granted Patent B2
US 10,418,638 · App. 15/649,818 · Granted Sep 17, 2019

Electrode with perforated current collector and lithium secondary battery including the same

Inventor: Kyung Hwa Woo (Daejeon, KR)
Assignee: LG CHEM, LTD.
H01M4/742H01M4/366H01M4/622H01M4/661H01M4/667H01M4/668H01M4/808H01M10/0413H01M10/0525
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Quick Facts
Patent No.
US 10,418,638
App. No.
15/649,818
Granted
Sep 17, 2019
Kind
B2
Abstract

Disclosed are an electrode including a perforated current collector, and a lithium secondary battery including the same, and according to the present disclosure, precipitation and elimination reactions of lithium metal are induced inside a perforation of a negative electrode current collector, and therefore, volume expansion of a cell is suppressed and battery performance is enhanced therefrom.

Claims (22)

1. An electrode for a lithium secondary battery comprising:

a pair of negative electrode current collectors having a plurality of perforations; and

a lithium metal layer disposed between the pair of negative electrode current collectors,

wherein the lithium metal layer comprises a first surface and a second surface opposite the first surface, the first surface directly contacting a surface of a first negative electrode current collector of the pair of negative electrode current collectors and the second surface directly contacting a surface of a second negative current collector of the pair of negative current collectors.

2. The electrode for a lithium secondary battery of claim 1 , further comprising an insulation layer disposed on the negative electrode current collector and having a plurality of perforations funneled to the perforations.

3. The electrode for a lithium secondary battery of claim 1 , wherein the perforation has a circular, oval or polygonal shape.

4. The electrode for a lithium secondary battery of claim 1 , wherein an aperture ratio caused by the perforations of the negative electrode current collector is from 20% to 80%.

5. The electrode for a lithium secondary battery of claim 1 , wherein the perforation of the negative electrode current collector is a circle having a diameter from 0.1 mm to 1.0 mm.

6. The electrode for a lithium secondary battery of claim 1 , wherein the perforation of the negative electrode current collector is a polygon having a longest distance of an inner side surface from 0.1 mm to 1.0 mm.

7. The electrode for a lithium secondary battery of claim 1 , wherein space between the perforations of the negative electrode current collector is from 0.1 mm to 1.0 mm.

8. The electrode for a lithium secondary battery of claim 1 , wherein the negative electrode current collector is selected from the group consisting of copper, aluminum, stainless steel, zinc, titanium, silver, palladium, nickel, iron, chromium, an alloy thereof and a combination thereof.

9. The electrode for a lithium secondary battery of claim 1 , wherein a thickness of the negative electrode current collector is from 3 μm to 500 μm.

10. The electrode for a lithium secondary battery of claim 2 , wherein the insulation layer is one or more types selected from among styrene-butadiene series rubber, carboxymethylcellulose, polytetrafluoroethylene, polyethylene, polypropylene, an ethylene propylene copolymer, polybutadiene, butyl rubber, fluoro rubber, polyethylene oxide, polyvinyl pyrrolidone, polyepichlorohydrin, polyphosphazene, polyacrylonitrile, polystyrene, an ethylene propylene diene copolymer, polyvinyl pyridine, chlorosulfonated polyethylene, latex, a polyester resin, an acrylic resin, a phenol resin, an epoxy resin, polyvinyl alcohol, hydroxypropylcellulose and a combination thereof.

11. The electrode for a lithium secondary battery of claim 2 , wherein a thickness of the insulation layer is from 0.01 μm to 50 μm.

12. A lithium secondary battery comprising:

a negative electrode;

a positive electrode;

a separator provided therebetween; and

an electrolyte,

wherein the negative electrode is the electrode of claim 1 .

13. The electrode for a lithium secondary battery of claim 1 , wherein the lithium metal layer includes Li; and a lithium-containing metal compound selected from the group consisting of S, P, O, Cl, Se, F, Br, I and a combination thereof.

14. The electrode for a lithium secondary battery of claim 13 , wherein the lithium metal layer further includes an element selected from the group consisting of Ni, Co, Cu, Zn, Ga, Ge, Si, Al, Fe, V, Mn, Ti, Mo, Cr, Nb, Pt and a combination thereof.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 4, 2021
From: LG CHEM, LTD.
To: LG ENERGY SOLUTION, LTD.
Reel/Frame 058295/0068 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 24, 2017
From: WOO, KYUNG HWA
To: LG CHEM, LTD.
Reel/Frame 043080/0915 →
Priority Claims (1)
KR 10-2016-0090626 · Jul 18, 2016 · national
Continuity (1)
Related Publication 20180019477A1 · Jan 18, 2018