IP Library Granted Patent US 10,273,183
Granted Patent B2
US 10,273,183 · App. 15/650,441 · Granted Apr 30, 2019

Soda-lime-silica glass-ceramic

Inventors: Scott P Cooper (Maumee, OH); Samuel Schuver (Painesville, OH); Carol A Click (Corning, NY)
Assignee: Owens-Brockway Glass Container Inc.
C03C10/0009B65D1/0207C03C3/078C03C4/20
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Quick Facts
Patent No.
US 10,273,183
App. No.
15/650,441
Granted
Apr 30, 2019
Kind
B2
Abstract

A soda-lime-silica glass-ceramic article having an amorphous matrix phase and a crystalline phase is disclosed along with a method of manufacturing a soda-lime-silica glass-ceramic article from a parent glass composition comprising 47-63 mol % SiO 2 , 15-22 mol % Na 2 O, and 18-36 mol % CaO. The crystalline phase of the glass-ceramic article has a higher concentration of sodium (Na) than that of the amorphous matrix phase.

Claims (22)

1. A method of manufacturing a soda-lime-silica glass-ceramic container comprising:

forming a glass body from a parent glass composition comprising 47-63 mol % SiO 2 , 15-22 mol % Na 2 O, and 18-36 mol % CaO, the glass body being in the shape of a container; and

subjecting the glass body to a thermal treatment schedule to promote bulk in situ crystallization of the glass body such that the glass body is transformed into a glass-ceramic body having an amorphous matrix phase and a crystalline phase homogeneously dispersed throughout the amorphous matrix phase, the crystalline phase comprising combeite crystalline particles.

2. The method set forth in claim 1 , wherein the thermal treatment schedule comprises:

a nucleation stage wherein the glass body is brought to a temperature in a range of 525° C.-625° C. and maintained within the range of 525° C.-625° C. for 10 minutes to 180 minutes such that a plurality of nuclei spontaneously form within the glass body; and

a crystal growth stage wherein the glass body is brought to a temperature in a range of 600° C.-750° C. and maintained within the range of 600° C.-750° C. for 10 minutes to 120 minutes such that a plurality of crystalline particles form on the pre-existing nuclei.

3. The method set forth in claim 1 , wherein, during the crystal growth stage, the glass body is maintained at a temperature in a range of 600° C.-750° C. for an amount of time to transform the glass body into a glass-ceramic body having a crystalline volume fraction in the range of 0.10 to 0.70.

4. A method of manufacturing a soda-lime-silica glass-ceramic container comprising:

forming a glass body from a parent glass composition comprising 47-63 mol % SiO 2 , 15-22 mol % Na 2 O, and 18-36 mol % CaO, the glass body being in the shape of a container; and

subjecting the glass body to a thermal treatment schedule to promote bulk in situ crystallization of the glass body such that the glass body is transformed into a glass-ceramic body having an amorphous matrix phase and a crystalline phase homogeneously dispersed throughout the amorphous matrix phase, wherein the glass body is not cooled to a temperature below a glass transition temperature of the parent glass composition prior to being subjected to the thermal treatment schedule.

5. The method set forth in claim 1 , wherein the thermal treatment schedule comprises:

a combined nucleation and crystal growth stage, wherein the glass body is brought to a temperature in a range of 600° C.-750° C. and maintained within said range for 10 minutes to 180 minutes.

6. The method set forth in claim 1 , wherein the thermal treatment schedule comprises:

an annealing stage, wherein the glass-ceramic body is gradually cooled to a temperature below a strain point of the amorphous matrix phase to reduce internal stresses within the glass-ceramic body.

7. A method of manufacturing a soda-lime-silica glass-ceramic container comprising:

forming a glass body from a parent glass composition comprising 47-63 mol % SiO 2 , 15-22 mol % Na 2 O, and 18-36 mol % CaO, the glass body being in the shape of a container;

maintaining the glass body at a temperature between 525° C. and 600° C. to form nuclei spontaneously and homogeneously throughout the glass body;

maintaining the glass body at a temperature between 600° C. and 750° C. to grow crystals on the nuclei throughout the glass body and thereby transform the glass body into a glass-ceramic body; and

annealing the glass-ceramic body at a temperature between 540° C. and 580° C. followed by cooling the glass-ceramic body to a temperature below a strain point of the amorphous glass matrix of the glass-ceramic body to reduce internal stresses within the glass-ceramic body.

8. The method set forth in claim 7 , wherein the glass body is not cooled to a temperature below the glass transition temperature of the parent glass composition prior to maintaining the glass body at a temperature between 525° C. and 600° C. to form nuclei spontaneously and homogeneously throughout the glass body.

9. The method set forth in claim 7 , wherein the glass-ceramic body comprises combeite crystalline particles homogeneously dispersed within an amorphous glass matrix, and wherein the glass-ceramic body does not include particles of devitrite (Na 2 O.3CaO.6SiO 2 ), wollastonite (CaO.SiO 2 ), or a SiO 2 polymorph.

10. The method set forth in claim 7 , wherein the glass body is maintained at a temperature between 580° C. and 610° C. to form nuclei, and wherein the glass body is further maintained at a temperature between 680° C. and 730° C. to grow crystals on the nuclei.

Assignments (2)
SECURITY INTEREST Recorded Mar 25, 2022
From: OWENS-BROCKWAY GLASS CONTAINER INC.
To: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 059503/0312 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 15, 2017
From: COOPER, SCOTT; CLICK, CAROL; SCHUVER, SAMUEL
To: OWENS-BROCKWAY GLASS CONTAINER INC
Reel/Frame 043605/0280 →
Continuity (1)
Related Publication 20190016629A1 · Jan 17, 2019
Cited By (1)
US 12,709,568