IP Library Granted Patent US 9,834,569
Granted Patent B2
US 9,834,569 · App. 15/651,410 · Granted Dec 5, 2017

Process for producing tetrakis(

Inventors: Rajeev S. Mathur (Baton Rouge, LA); Jamie R. Strickler (Baton Rouge, LA)
Assignee: ALBEMARLE CORPORATION
C07F5/02C07F5/027
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Quick Facts
Patent No.
US 9,834,569
App. No.
15/651,410
Granted
Dec 5, 2017
Kind
B2
Abstract

This invention provides processes for forming halomagnesium tetrakis( F aryl)borates, which processes comprise bringing together, in an anhydrous liquid organic medium, at least one boron trihalide; at least one F aryl Grignard reagent; and at least one copper compound. Also provided are processes for forming halomagnesium tetrakis( F aryl)borates, which processes comprise bringing together, in an anhydrous liquid organic medium, at least one boron trihalide; at least one copper compound; magnesium metal; and at least one polyhaloaromatic compound.

Claims (3)

1. A product mixture comprising a liquid organic medium, magnesium salts, copper compounds, and at least one halomagnesium tetrakis( F aryl)borate.

2. A product mixture as in claim 1 wherein the halomagnesium tetrakis( F aryl)borate is chloromagnesium tetrakis(pentafluorophenyl)borate, bromomagnesium tetrakis(pentafluorophenyl)borate, chloromagnesium tetrakis(heptafluoronaphthyl)borate, or bromomagnesium tetrakis(heptafluoronaphthyl)borate.

3. A product mixture as in claim 1 which further comprises an F aryl Grignard reagent, and wherein the F aryl Grignard reagent is pentafluorophenyl chloromagnesium, pentafluorophenyl bromomagnesium, heptafluoronaphthyl chloromagnesium, or heptafluoronaphthyl bromomagnesium.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 31, 2018
From: ALBEMARLE CORPORATION
To: W. R. GRACE & CO-CONN.
Reel/Frame 045946/0786 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 29, 2017
From: MATHUR, RAJEEV S; STRICKLER, JAMIE R
To: ALBEMARLE CORPORATION
Reel/Frame 044252/0789 →
Continuity (4)
Division 14434132
Provisional Application 61730203 · Nov 27, 2012
Provisional Application 61774877 · Mar 8, 2013
Related Publication 20170313725A1 · Nov 2, 2017