Closure for a product-retaining container
A closure for a product-retaining container is constructed for being inserted and securely retained in a portal-forming neck of said container. The closure comprises: a plastic material comprising at least one thermoplastic polymer; a plurality of particles comprising cork; and at least one processing aid. Optionally, one or more additives and/or blowing agents may be included. A method for manufacturing a closure comprises intimately combining multiple components, heating the resulting composition to form a melt, forming a closure precursor from the melt, and optionally cutting and/or finishing the closure precursor to form the closure.
1. A closure for a beverage-retaining container constructed for being inserted and securely retained in a portal-forming neck of said container, the closure comprising:
(a) a plastic material comprising at least one thermoplastic polymer, wherein the at least one thermoplastic polymer comprises at least one polymer that is biodegradable according to ASTM D6400, and the at least one thermoplastic polymer is selected from the group consisting of: polyhydroxyalkanoates;
copolymers of hydroxyalkanoates and monomers of biodegradable polymers;
polylactic acid; copolymers of lactic acid and monomers of biodegradable polymers; polycaprolactone; polyglycolide; poly(3-hydroxybutyrate); poly(3-hydroxybutyrate-co-3-hydroxyvalerate); poly(3-hydroxybutyrate-co-3-hydroxyhexanoate); poly(butylenesuccinate); poly(butylenesuccinate-co-adipate); poly(trimethyleneterephthalate); poly(butylenadipate-co-terephthalate); poly(butylenesuccinate-co-terephthalate); poly(butylenesebacate-co-terephthalate); lactic acid caprolactone lactic acid copolymers; lactic acid ethylene oxide lactic acid copolymers; and combinations of any two or more thereof;
(b) a plurality of particles comprising cork and having a particle size distribution D 50 measured by means of mechanical sieving according to ISO ICS 19.120 in a range of from 0.2 mm to 10 mm; and
(c) two or more processing aids, comprising at least one processing aid that reduces the melt viscosity of the plastic material, and at least one processing aid that reduces the friction of the plastic material relative to at least one extruder surface during extrusion,
wherein at atmospheric pressure at least one processing aid is solid at temperatures up to 160° C., and
wherein the plurality of particles is distributed homogeneously throughout the closure.
2. The closure according to claim 1 , wherein said closure comprises a plurality of cells.
3. The closure according to claim 2 , wherein said plastic material comprises a polymer matrix that comprises the plurality of cells.
4. The closure according to claim 3 , wherein at least one cell of the plurality of cells in the polymer matrix is defined by at least one cell wall facing an interior of the at least one cell, wherein at least a part of the at least one cell wall comprises a plastic material, and the plastic material of the at least a part of the at least one cell wall comprises a thermoplastic polymer of a composition that differs from a composition of a plastic material that forms a remainder of the polymer matrix.
5. The closure according to claim 2 , wherein the plurality of cells comprises a plurality of substantially closed cells or a plurality of closed cells.
6. The closure according to claim 2 , wherein the plurality of cells has an average cell size in a range of from about 0.025 mm to about 0.5 mm.
7. The closure according to claim 2 , wherein at least one of a size or a distribution of the plurality of cells in the closure is substantially uniform throughout at least one of a length or a diameter of the closure.
8. The closure according to claim 1 , wherein the closure has an overall density in a range of from 100 kg/m 3 to 500 kg/m 3 .
9. The closure according to claim 1 , wherein the plastic material has a foam density in a range of from 25 kg/m 3 to 800 kg/m 3 .
10. The closure according to claim 1 , wherein the plastic material is thermoplastically processable.
11. The closure according to claim 1 , wherein a portion of the closure in a range of from 50% by weight to 100% by weight of the closure is biodegradable according to ASTM D6400, based on a total weight of the closure.
12. The closure according to claim 1 , wherein the plurality of particles has a particle size distribution D 50 measured by means of mechanical sieving according to ISO ICS 19.120 in a range of from 0.5 mm to 5 mm.
13. The closure according to claim 1 , wherein the two or more processing aids are selected from the group consisting of: fatty acid derivatives derived from a saturated or unsaturated fatty acid having from 12 to 45 carbon atoms; modified fatty acid derivatives derived from a modified, saturated or unsaturated fatty acid having from 12 to 45 carbon atoms; natural waxes; synthetic waxes; fatty acids; fatty acid esters; fatty acid amides; wax esters; ester waxes; plasticisers; alcohols; glycerol esters; polyol esters; polyol partial esters; polyglycol esters; fatty acid polyglycol esters; fatty acid polyglycol ethers; fatty alcohol polyglycol ethers; metallic soaps; fluoropolymers; polyols; silicones; glycerol monostearate; fatty acid esters of polyols; high molecular weight poly esters; and combinations of any two or more thereof.
14. The closure according to claim 1 , wherein one or more of the two or more processing aids comprises at least one of the following properties:
(i) a dropping point measured according to ASTM D2265 in a range of from 50° C. to 160° C.; or
(ii) a specific gravity in a range of from 0.900 to 1.300, measured according to ASTM D1298-12b.
15. The closure according to claim 1 , wherein components (a), (b) and (c) are present in the following weight percent amounts, based on a total weight of the closure:
(a) 10 wt. % to 59.9 wt. % of the plastic material;
(b) 40 wt. % to 85 wt. % of the plurality of particles; and
(c) 0.1 wt. % to 10 wt. % of the two or more processing aids.
16. The closure according to claim 1 , comprising at least one of the following conditions (i) to (iv): (i) the closure is devoid of a binder; (ii) the closure is devoid of a crosslinking agent; (iii) the closure is devoid of a binder and is devoid of a crosslinking agent; or (iv) the plastic material is not crosslinked by means of a crosslinking agent.
17. The closure according to claim 1 , wherein the closure is formed by a process comprising extrusion.
18. The closure according to claim 1 , wherein the closure is formed by a process comprising monoextrusion.
19. The closure according to claim 1 , wherein the closure has an oxygen ingress rate measured according to ASTM F1307 of less than about 3 mg oxygen per container in a first 100 days after the container is closed with the closure.
20. The closure according to claim 1 , wherein the closure has an oxygen ingress rate measured according to ASTM F1307 selected from the group consisting of less than about 1 mg oxygen, less than about 0.5 mg oxygen, less than about 0.25 mg oxygen, less than about 0.2 mg oxygen, and less than about 0.1 mg oxygen, per container in a first 100 days after the container is closed with the closure.
21. The closure according to claim 1 , wherein the closure has an oxygen transfer rate measured according to ASTM F1307 in 100% oxygen of less than 0.05 cc/day.
22. The closure according to claim 1 , wherein the closure has a content of releasable trichloroanisole of less than 6 ng/L.
23. The closure according to claim 1 , being constructed for being inserted and securely retained in a portal-forming neck of a beverage-containing container embodying a wine bottle.
24. The closure according to claim 1 , wherein the at least one thermoplastic polymer comprises poly (trimethyleneterephthalate).
25. A closure system comprising the closure according to claim 1 and a beverage-retaining container.
26. A composition for use in manufacturing a closure for a product-retaining container, the composition comprising:
(a) a plastic material comprising at least one thermoplastic polymer, wherein the at least one thermoplastic polymer comprises at least one polymer that is biodegradable according to ASTM D6400, and the at least one thermoplastic polymer is selected from the group consisting of: polyhydroxyalkanoates; copolymers of hydroxyalkanoates and monomers of biodegradable polymers; polylactic acid; copolymers of lactic acid and monomers of biodegradable polymers; polycaprolactone; polyglycolide; poly (3-hydroxybutyrate); poly (3-hydroxybutyrate-co-3-hydroxyvalerate); poly (3-hydroxybutyrate-co-3-hydroxyhexanoate); poly (butylenesuccinate); poly (butylenesuccinate-co-adipate); poly (trimethyleneterephthalate); poly (butylenadipate-co-terephthalate); poly (butylenesuccinate-co-terephthalate); poly (butylenesebacate-co-terephthalate); lactic acid caprolactone lactic acid copolymers; lactic acid ethylene oxide lactic acid copolymers; and combinations of any two or more thereof;
(b) a plurality of particles comprising cork and having a particle size distribution D 50 measured by mechanical sieving according to ISO ICS 19.120 in a range of from 0.2 mm to 10 mm;
(c) two or more processing aids, comprising at least one processing aid that reduces the melt viscosity of the plastic material, and at least one processing aid that reduces the friction of the plastic material relative to at least one extruder surface during extrusion;
(d) optionally, at least one additive; and
(e) at least one blowing agent wherein at atmospheric pressure at least one processing aid is solid at temperatures up to 160° C., and wherein the plurality of particles is distributed homogeneously throughout the closure.
27. The composition according to claim 26 , wherein components (a), (b), (c), (d) and (e) are present in the following weight percent amounts, based on a total weight of the composition:
(a) 10 wt. % to 59.8 wt. % of the plastic material;
(b) 40 wt. % to 85 wt. % of the plurality of particles;
(c) 0.1 wt. % to 10 wt. % of the two or more processing aids;
(d) 0 wt. % to 10 wt. % of the at least one additive; and
(e) 0.1 wt. % to 10 wt. % of the at least one blowing agent.
28. The composition according to claim 26 , wherein the at least one blowing agent is selected from the group consisting of expandable microspheres, chemical blowing agents, physical blowing agents, and combinations of two or more thereof.
29. A method for obtaining a composition for use in manufacturing a closure for a product-retaining container, the method comprising intimately combining the following components:
(a) a plastic material comprising at least one thermoplastic polymer, wherein the at least one thermoplastic polymer comprises at least one polymer that is biodegradable according to ASTM D6400, and the at least one thermoplastic polymer is selected from the group consisting of: polyhydroxyalkanoates; copolymers of hydroxyalkanoates and monomers of biodegradable polymers; polylactic acid; copolymers of lactic acid and monomers of biodegradable polymers; polycaprolactone; polyglycolide; poly(3-hydroxybutyrate); poly(3-hydroxybutyrate-co-3-hydroxyvalerate); poly(3-hydroxybutyrate-co-3-hydroxyhexanoate); poly(butylenesuccinate); poly(butylenesuccinate-co-adipate); poly(trimethyleneterephthalate); poly(butylenadipate-co-terephthalate); poly(butylenesuccinate-co-terephthalate); poly(butylenesebacate-co-terephthalate); lactic acid caprolactone lactic acid copolymers; lactic acid ethylene oxide lactic acid copolymers; and combinations of any two or more thereof;
(b) a plurality of particles comprising cork and having a particle size distribution D 50 measured by means of mechanical sieving according to ISO ICS 19.120 in a range of from 0.2 mm to 10 mm;
c) two or more processing aids;
(d) optionally, at least one additive; and
(e) at least one blowing agent wherein at atmospheric pressure at least one processing aid is solid at temperatures up to 160° C., and wherein the plurality of particles is distributed homogeneously throughout the closure.
30. The method according to claim 29 , wherein the components (a), (b), (c), (d) and (e) are present in the following weight percent amounts, based on a total weight of the composition:
(a) 10 wt. % to 59.8 wt. % of the plastic material;
(b) 40 wt. % to 85 wt. % of the plurality of particles;
(c) 0.1 wt. % to 10 wt. % of the two or more processing aids;
(d) 0 wt. % to 10 wt. % of the at least one additive; and
(e) 0.1 wt. % to 10 wt. % of the at least one blowing agent.
31. A composition obtainable by the method according to claim 29 .
32. A method for manufacturing a closure for a product-retaining container constructed for being inserted and securely retained in a portal-forming neck of said container, said method comprising as method steps:
i. intimately combining the following components, to form a composition:
(a) a plastic material comprising at least one thermoplastic polymer, wherein the at least one thermoplastic polymer comprises at least one polymer that is biodegradable according to ASTM D6400, and the at least one thermoplastic polymer is selected from the group consisting of: polyhydroxyalkanoates; copolymers of hydroxyalkanoates and monomers of biodegradable polymers; polylactic acid; copolymers of lactic acid and monomers of biodegradable polymers; polycaprolactone; polyglycolide; poly(3-hydroxybutyrate); poly(3-hydroxybutyrate-co-3-hydroxyvalerate); poly(3-hydroxybutyrate-co-3-hydroxyhexanoate); poly(butylenesuccinate); poly(butylenesuccinate-co-adipate); poly(trimethyleneterephthalate); poly (butylenadipate-co-terephthalate); poly(butylenesuccinate-co-terephthalate); poly (butylenesebacate-co-terephthalate); lactic acid caprolactone lactic acid copolymers; lactic acid ethylene oxide lactic acid copolymers; and combinations of any two or more thereof;
(b) a plurality of particles comprising cork and having a particle size distribution D 50 measured by means of mechanical sieving according to ISO ICS 19.120 in a range of from 0.2 mm to 10 mm;
(c) two or more processing aids, comprising at least one processing aid that reduces the melt viscosity of the plastic material, and at least one processing aid that reduces the friction of the plastic material relative to at least one extruder surface during extrusion;
(d) optionally, at least one additive; and
(e) at least one blowing agent wherein at atmospheric pressure at least one processing aid is solid at temperatures up to 160° C., and wherein the plurality of particles is distributed homogeneously throughout the closure;
ii. heating the composition obtained in step i. to form a melt;
iii. forming, by means of extrusion or molding, a closure precursor from the melt obtained in step ii.; and
iv. optionally cutting and/or finishing the closure precursor to form the closure.
33. The method according to claim 32 , wherein the at least one blowing agent is selected from the group consisting of expandable microspheres, chemical blowing agents, physical blowing agents, and combinations of two or more thereof.
34. The method according to claim 32 , wherein during step ii. the plastic material is foamed.
35. The method according to claim 32 , wherein the components (a), (b), (c), (d) and (e) are present in the following weight percent amounts, based on a total weight of the composition:
(a) 10 wt. % to 59.8 wt. % of the plastic material;
(b) 40 wt. % to 85 wt. % of the plurality of particles;
(c) 0.1 wt. % to 10 wt. % of the two or more processing aids;
(d) 0 wt. % to 10 wt. % of the at least one additive; and
(e) 0.1 wt. % to 10 wt. % of the at least one blowing agent.
36. A closure obtained by the method according to claim 32 .