Generation of wrinkle-free silicon monoxide electrodes using combined preformation and formation
A solid electrolyte interface is formed on a silicon monoxide electrode in a battery cell. While the solid electrolyte interface is being formed on the silicon monoxide electrode, the battery cell is charged for one or more initial cycles.
1. A method, comprising:
assembling a sealed battery cell, including by:
forming a solid electrolyte interface on a silicon monoxide electrode in the sealed battery cell; and
while the solid electrolyte interface is being formed on the silicon monoxide electrode, charging and discharging the sealed battery cell for a plurality of cycles at substantially the same rate as charging and discharging the sealed battery cell after the solid electrolyte interface is fully formed, including by:
charging and discharging the sealed battery cell for a first cycle during which the solid electrolyte interface on the silicon monoxide electrode is at a first thickness; and
charging and discharging the sealed battery cell for a second cycle that occurs after the first cycle during which the solid electrolyte interface on the silicon monoxide electrode is at a second thickness that is thicker than the first thickness, wherein A) the sealed battery cell is charged for the plurality of cycles while the sealed battery cell is compressed, and the sealed battery cell is discharged for the plurality of cycles while the sealed battery cell is uncompressed, or B) the sealed battery cell is charged for the plurality of cycles while the sealed battery cell is uncompressed, and the sealed battery cell is discharged for the plurality of cycles while the sealed battery cell is compressed.
2. The method recited in claim 1 , wherein the sealed battery cell is charged and discharged for the plurality of cycles while the sealed battery cell is compressed to a pressure within 25 psi and 75 psi.
3. The method recited in claim 1 , wherein forming the solid electrolyte interface and charging and discharging the sealed battery cell include applying a same charging current to the sealed battery cell multiple times over a same amount of time and up to a same voltage while the sealed battery cell is compressed.
4. The method recited in claim 1 , wherein forming the solid electrolyte interface and charging and discharging the sealed battery cell include applying a same charging current to the sealed battery cell multiple times over a same amount of time within 3 hours and 7 hours and up to a same voltage while the sealed battery cell is compressed.
5. The method recited in claim 1 , wherein forming the solid electrolyte interface and charging and discharging the sealed battery cell include applying a same charging current to the sealed battery cell multiple times over a same amount of time and up to a same voltage within 2.0V and 4.4V while the sealed battery cell is compressed.
6. The method recited in claim 1 further comprising:
before forming the solid electrolyte interface on the silicon monoxide electrode and before charging and discharging the sealed battery cell for the plurality of cycles, compressing the sealed battery cell at room temperature; and
after forming the solid electrolyte interface on the silicon monoxide electrode and after charging and discharging the sealed battery cell for the plurality of cycles, compressing the sealed battery cell while the sealed battery cell is heated.
7. The method recited in claim 1 , wherein:
forming the solid electrolyte interface and charging and discharging the sealed battery cell include applying a same charging current to the sealed battery cell multiple times over a same amount of time and up to a same voltage while the sealed battery cell is compressed; and
the method further includes:
before forming the solid electrolyte interface on the silicon monoxide electrode and before charging and discharging the sealed battery cell for the plurality of cycles, compressing the sealed battery cell at room temperature; and
after forming the solid electrolyte interface on the silicon monoxide electrode and after charging and discharging the sealed battery cell for the plurality of cycles, compressing the sealed battery cell while the sealed battery cell is heated.
8. A computer program product, the computer program product being embodied in a non-transitory computer readable storage medium and comprising computer instructions for:
assembling a sealed battery cell, including by:
forming a solid electrolyte interface on a silicon monoxide electrode in the sealed battery cell; and
while the solid electrolyte interface is being formed on the silicon monoxide electrode, charging and discharging the sealed battery cell for a plurality of cycles at substantially the same rate as charging and discharging the sealed battery cell after the solid electrolyte interface is fully formed, including by:
charging and discharging the sealed battery cell for a first cycle during which the solid electrolyte interface on the silicon monoxide electrode is at a first thickness; and
charging and discharging the sealed battery cell for a second cycle that occurs after the first cycle during which the solid electrolyte interface on the silicon monoxide electrode is at a second thickness that is thicker than the first thickness, wherein A) the sealed battery cell is charged for the plurality of cycles while the sealed battery cell is compressed, and wherein the sealed battery cell is discharged for the plurality of cycles while the sealed battery cell is uncompressed, or B) the sealed battery cell is charged for the plurality of cycles while the sealed battery cell is uncompressed, and wherein the sealed battery cell is discharged for the plurality of cycles while the sealed battery cell is compressed.
9. The method recited in claim 1 , wherein assembling the sealed battery cell further includes:
filling a unsealed battery cell, which includes the silicon monoxide electrode, with a liquid electrolyte; and
sealing the unsealed battery cell filled with the liquid electrolyte in order to obtain the sealed battery cell.
10. The method recited in claim 1 , wherein forming the solid electrolyte interface and charging and discharging the sealed battery cell include applying a same charging current to the sealed battery cell multiple times over a same amount of time within 3 hours and 7 hours and up to a same voltage within 2.0 V and 4.4V while the sealed battery cell is compressed.
11. The method recited in claim 1 , wherein the sealed battery cell is charged for the plurality of cycles while the sealed battery cell is compressed, and the sealed battery cell is discharged for the plurality of cycles while the sealed battery cell is uncompressed.
12. The method recited in claim 1 , wherein the sealed battery cell is charged for the plurality of cycles while the sealed battery cell is uncompressed, and the sealed battery cell is discharged for the plurality of cycles while the sealed battery cell is compressed.