Carbon capture in fermentation
The invention relates to a method for producing products by microbial fermentation. The method comprises first converting a feed stream containing methane to a gaseous substrate comprising CO, of the invention include converting CO H 2 , and CO 2 using a steam reforming zone and a water gas shift zone. The gaseous substrate is then converted to products such as alcohols and/or acids by to one or more products including alcohols and/or acids by fermentation using a carboxydotrophic microorganism.
1. A method for the production of a product, comprising:
a. providing a feed stream comprising methane to a steam reforming zone to reform at least a portion of the methane to produce a reformed gas stream comprising CO and H 2 by the reaction: CH 4 +H 2 O→CO+3H 2 ;
b. passing the reformed gas stream to a water gas shift zone to produce a first gas stream comprising CO, H 2 , and CO 2 by the reaction: CO+H 2 O→CO 2 +H 2 ;
c. passing the first gas stream to a first gas separator and removing at least a portion of one or more of CO, CO 2 , H 2 , N 2 , and O 2 from the first gas stream to produce a second gas stream,
d. passing the second gas stream to a bioreactor containing one or more carboxydotrophic microorganisms, and
e. culturing the microorganisms to produce a product comprising at least one of alcohols, and acids.
2. The method of claim 1 , comprising removing at least a portion of H 2 from the first gas stream.
3. The method of claim 2 , wherein H 2 is separated by a pressure swing adsorption unit.
4. The method of claim 2 , wherein the H 2 is used as a fuel.
5. The method of claim 1 , wherein the second gas stream comprises one or more of CO, CO 2 , and H 2 .
6. The method of claim 1 , wherein the second gas stream comprises at least CO and CO 2 .
7. The method of claim 6 further comprising removing at least a portion of CO 2 from the second gas stream prior to passing the second gas stream to the bioreactor.
8. The method of claim 1 , further comprising recovering the product.
9. The method of claim 1 further comprising separating at least a portion of a CO 2 component from an exhaust stream exiting the bioreactor.
10. The method of claim 1 , wherein the carboxydotrophic microorganism is selected from the group consisting of Clostridium, Moorella and Carboxydothermus.
11. The method of claim 10 where the Clostridium bacterium is selected from the group consisting of Clostridium autoethanogenum, Clostridium ljungdahlii, Clostridium ragsdalei, Clostridium drakei, Clostridium carboxydivorans, Clostridium scatologenes and mixtures thereof.
12. The method of claim 1 , wherein the product is selected from the group consisting of ethanol, acetate and mixtures thereof.
13. The method of claim 1 where the reforming zone and water shift zone are present in the same reactor.
14. The method of claim 1 where the reforming zone and water shift zone are present in separate reactors.