IP Library Granted Patent US 10,221,378
Granted Patent B2
US 10,221,378 · App. 15/679,361 · Granted Mar 5, 2019

Compositions containing one or more poly alpha-1,3-glucan ether compounds

Inventors: Kevin D Nagy (Wilmington, DE); Perry G Caimi (Kennett Square, PA); T Joseph Dennes (Parkesburg, PA); Susan Marie Hennessey (Avondale, PA); Ayrookaran J. Poulose (Belmont, CA); Jayme L Paullin (Claymont, DE)
Assignee: E I DU PONT DE NEMOURS AND COMPANY
C11D3/38645A61K8/66A61K8/73A61Q19/00C11D3/225D06M16/00A61K2800/10
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Quick Facts
Patent No.
US 10,221,378
App. No.
15/679,361
Granted
Mar 5, 2019
Kind
B2
Abstract

Compositions comprising cellulase and at least one poly alpha-1,3-glucan ether compound having a degree of substitution with an organic group of about 0.05-3.0 are disclosed. Such compositions can be dry or aqueous, the latter of which can have a viscosity of at least about 10 cPs. The disclosed composition can be in the form of a personal care product, household product, or industrial product, for example. Also disclosed are a method for preparing an aqueous composition comprising cellulase and a poly alpha-1,3-glucan ether compound, and a method of treating a material such as fabric by contacting it with this aqueous composition.

Claims (39)

1. A composition comprising a cellulase and a poly alpha-1,3-glucan compound comprising the structure:

wherein

(i) n is at least 6,

(ii) each R is independently H or an organic group, wherein at least one R is an organic group,

(iii) the poly alpha-1,3-glucan compound has a degree of substitution of about 0.05 to about 3.0 with the organic group, and

(iv) at least 90% of the glycosidic linkages of the poly alpha-1,3-glucan compound are alpha-1,3 glycosidic linkages.

2. The composition of claim 1 , wherein the organic group is selected from the group consisting of carboxy alkyl, hydroxy alkyl, and alkyl.

3. The composition of claim 2 , wherein the organic group is selected from the group consisting of carboxymethyl, hydroxypropyl, dihydroxypropyl, hydroxyethyl, methyl, and ethyl.

4. The composition of claim 2 , wherein the organic group is a carboxymethyl group.

5. The composition of claim 1 , wherein the composition is in the form of a personal care product, household product, or industrial product.

6. The composition of claim 5 , wherein the composition is a fabric care product.

7. The composition of claim 1 , wherein the composition is an aqueous composition.

8. The composition of claim 7 , wherein the composition has a viscosity of at least about 10 centipoise.

9. The composition of claim 1 , wherein at least 95% of the glycosidic linkages of the poly alpha-1,3-glucan compound are alpha-1,3 glycosidic linkages.

10. The composition of claim 1 , wherein the poly alpha-1,3-glucan compound has one or more of the same organic group.

11. The composition of claim 1 , wherein the poly alpha-1,3-glucan compound has two or more different organic groups.

12. The composition of claim 1 , wherein the composition comprises a surfactant.

13. The composition of claim 1 , wherein the composition comprises less than 1 part-per-million of the cellulase.

14. A method for preparing an aqueous composition, the method comprising:

contacting an aqueous composition with a poly alpha-1,3-glucan compound comprising the structure:

wherein

(i) n is at least 6,

(ii) each R is independently H or an organic group, wherein at least one R is an organic group,

(iii) the poly alpha-1,3-glucan compound has a degree of substitution of about 0.05 to about 3.0 with the organic group, and

(iv) at least 90% of the glycosidic linkages of the poly alpha-1,3-glucan compound are alpha-1,3 glycosidic linkages;

and wherein the aqueous composition prepared in said method comprises a cellulase.

15. The method of claim 14 , wherein said cellulase is:

(i) comprised in the aqueous composition prior to said contacting step, or

(ii) added to the aqueous composition during or after said contacting step.

16. The method of claim 14 , wherein:

(i) the viscosity of the aqueous composition is increased by said poly alpha-1,3-glucan compound, and/or

(ii) the shear thinning behavior or the shear thickening behavior of the aqueous composition is increased by said poly alpha-1,3-glucan compound.

17. The method of claim 14 , wherein at least 95% of the glycosidic linkages of the poly alpha-1,3-glucan compound are alpha-1,3 glycosidic linkages.

18. A method of treating a material, said method comprising:

contacting the material with a composition according to claim 7 .

19. The method of claim 18 , wherein the material comprises fabric.

20. The method of claim 19 , wherein the fabric comprises a (i) natural fiber, (ii) synthetic fiber, or a combination of both (i) and (ii).

21. The method of claim 19 , wherein the poly alpha-1,3-glucan compound adsorbs to the fabric.

22. The method of claim 18 , wherein at least 95% of the glycosidic linkages of the poly alpha-1,3-glucan compound are alpha-1,3 glycosidic linkages.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 28, 2020
From: DUPONT INDUSTRIAL BIOSCIENCES USA, LLC
To: NUTRITION & BIOSCIENCES USA 4, INC.
Reel/Frame 055028/0496 →
CORRECTIVE ASSIGNMENT TO CORRECT THE ENTITY TYPE PREVIOUSLY RECORDED AT REEL: 049879 FRAME: 0043. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Sep 6, 2019
From: E. I. DU PONT DE NEMOURS AND COMPANY
To: DUPONT INDUSTRIAL BIOSCIENCES USA, LLC
Reel/Frame 050300/0408 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 26, 2019
From: E. I. DU PONT DE NEMOURS AND COMPANY
To: DUPONT INDUSTRIAL BIOSCIENCES USA, LLC
Reel/Frame 049879/0043 →
Continuity (3)
Continuation 14741769 · Jun 17, 2015
Provisional Application 62014318 · Jun 19, 2014
Related Publication 20180066214A1 · Mar 8, 2018