Negative electrode for lithium secondary battery and lithium secondary battery comprising the same
Disclosed is a negative electrode for a lithium secondary battery having excellent electric conductivity and adhesion even though a high-loading negative electrode is used, and the negative electrode includes a negative electrode current collector; a first negative electrode mixture layer containing a first negative electrode active material, a first polymer binder and a first conductive material and formed on at least one surface of the negative electrode current collector; and a second negative electrode mixture layer containing a second negative electrode active material, a second polymer binder and a second conductive material and formed on an upper surface of the first negative electrode mixture layer, wherein the first negative electrode active material contains natural graphite and silicon oxide, and the second negative electrode active material contains artificial graphite.
1. A negative electrode for a lithium secondary battery, comprising:
a negative electrode current collector;
a first negative electrode mixture layer containing a first negative electrode active material, a first polymer binder and a first conductive material and formed on at least one surface of the negative electrode current collector; and
a second negative electrode mixture layer containing a second negative electrode active material, a second polymer binder and a second conductive material and formed on an upper surface of the first negative electrode mixture layer,
wherein the first negative electrode active material contains natural graphite and silicon oxide, and the second negative electrode active material consists of artificial graphite.
2. The negative electrode for a lithium secondary battery according to claim 1 , wherein the first negative electrode active material contains 80 to 100 wt % of natural graphite and silicon oxide, based on the total weight of the first negative electrode active material.
3. The negative electrode for a lithium secondary battery according to claim 1 , wherein the natural graphite and the silicon oxide have a weight ratio of 80:20 to 95:5.
4. The negative electrode for a lithium secondary battery according to claim 3 , wherein the natural graphite and the silicon oxide have a weight ratio of 90:10 to 95:5.
5. The negative electrode for a lithium secondary battery according to claim 1 , wherein the second negative electrode active material contains 90 to 100 wt % of artificial graphite, based on the total weight of the second negative electrode active material.
6. The negative electrode for a lithium secondary battery according to claim 1 , wherein the first negative electrode mixture layer and the second negative electrode mixture layer have a thickness ratio of 3:7 to 1:9.
7. The negative electrode for a lithium secondary battery according to claim 1 , wherein the first negative electrode mixture layer has a loading amount of 50 to 200 mg/25 cm 2 , and the second negative electrode mixture layer has a loading amount of 300 to 450 mg/25 cm 2 .
8. The negative electrode for a lithium secondary battery according to claim 1 , wherein the first polymer binder and the second polymer binder are independently at least one selected from the group consisting of polyvinylidene fluoride-hexafluoropropylene copolymer (PVDF-co-HFP), polyvinylidene fluoride, polyacrylonitrile, polymethyl methacrylate, polyvinyl pyrrolidone, tetrafluoroethylene, polyethylene, polypropylene, polyacrylic acid, ethylene-propylene-diene monomer (EPDM), sulfonated EPDM, styrene butadiene rubber (SBR), fluorine rubber, and polymers prepared by substituting hydrogen thereof with Li, Na or Ca.
9. The negative electrode for a lithium secondary battery according to claim 8 , wherein the first polymer binder and the second polymer binder are respectively styrene butadiene rubber (SBR).
10. The negative electrode for a lithium secondary battery according to claim 1 , wherein the negative electrode has a thickness of 50 μm to 250 μm.
11. A lithium secondary battery, comprising a positive electrode, a negative electrode and a separator interposed between the positive electrode and the negative electrode, wherein the negative electrode is a negative electrode defined in claim 1 .