Long-life rechargeable ion batteries having ion reservoirs
An aspect of the present disclosure is an electrochemical device that includes a first electrode, an ion reservoir electronically connected to the electrode by a first circuit, an electrolyte positioned between the first electrode and the ion reservoir and ionically connecting the first electrode and the ion reservoir, and a regulating element, where the regulating element is positioned between the first electrode and the ion reservoir, the regulating element electronically and/or ionically connects the ion reservoir and the first electrode, and the regulating element limits the transfer of at least one of electrons and/or ions between the ion reservoir and the first electrode.
1. An electrochemical device comprising:
a first electrode;
a second electrode;
a first electrolyte positioned between the first electrode and the second electrode;
a passively triggered ion reservoir comprising a solid active material;
a first circuit;
a second circuit; and
a conduit comprising a second electrolyte and an ionic regulating element, wherein:
the first electrolyte ionically connects the first electrode and the second electrode;
the first circuit electronically connects the first electrode and the second electrode,
the second circuit electronically connects the solid active material and the first electrode,
the second electrolyte ionically connects the solid active material and the first electrode,
the solid active material is not in direct contact with the first electrolyte or the second electrode,
the solid active material is indirectly connected ionically to the second electrode through the second electrolyte, the first electrode, and the first electrolyte,
the solid active material is indirectly connected electronically to the second electrode through the second circuit, the first electrode, and the first circuit, and
the ionic regulating element passively provides a release of an ion to the first electrode.
2. The electrochemical device of claim 1 , wherein
the solid active material is capable of being oxidized according to a first reaction comprising M↔M n+ +ne − having a first standard reduction potential E St 0 ,
M is an element,
M n+ is the ion, and
n is an integer value greater than zero.
3. The electrochemical device of claim 2 , wherein the solid active material comprises at least one of lithium, magnesium, aluminum, potassium, zinc, or vanadium.
4. The electrochemical device of claim 2 , wherein M n+ comprises at least one of Li + , Na + , K + , Fe 3+ , Cu 2+ , V 2+ , or Mg 2+ .
5. The electrochemical device of claim 2 , wherein:
the first electrode behaves as a cathode capable of being reduced according to a second reaction comprising X+M n+ +ne − ↔MX having a second standard reduction potential E cat 0 ,
X comprises an element, and
E St 0 <E cat 0 .
6. The electrochemical device of claim 5 , wherein X comprises at least one of FePO 4 , FeCl 3 , Mn 2 O 4 , CoO 2 , sulfur, a NiCoAlO 2 alloy, a NiMnCoO 2 alloy, or a vanadate.
7. The electrochemical device of claim 6 , wherein the first reaction is Li↔Li + +e − and V St 0 is about −3.04 V.
8. The electrochemical device of claim 7 , wherein the second reaction is FePO 4 +Li + +e − ↔LiFePO 4 and E cat 0 is about 0.36 V.
9. The electrochemical device of claim 2 , wherein:
the first electrode behaves as an anode capable of being oxidized according to a second reaction comprising Y↔Y n+ +ne − having a second standard reduction potential E ano 0 , Y comprises an element, and E St 0 <E ano 0 .
10. The electrochemical device of claim 9 , wherein Y comprises at least one of carbon, silicon, tin, sodium, zinc, magnesium, vanadium, or TiO 3 .
11. The electrochemical device of claim 10 , wherein the first reaction is Li↔Li + +e − and E St 0 is about −3.04 V.
12. The electrochemical device of claim 11 , wherein the second reaction is LiC 6 ↔Li + +e − +C and E ano 0 is about −2.99 V.
13. The electrochemical device of claim 1 , wherein
the solid active material is capable of being reduced according to a first reaction comprising M+ne − ↔M n− having a first standard reduction potential E St 0 ,
M is an element,
M n− is the ion, and
n is an integer value greater than zero.
14. The electrochemical device of claim 13 , wherein:
the first electrode behaves as a cathode capable of being reduced according to a second reaction comprising MX+ne − ↔X+M n− having a second standard reduction potential E cat 0 ,
X comprises an element, and E St 0 >E cat 0 .
15. The electrochemical device of claim 13 , wherein:
the first electrode behaves as an anode capable of being oxidized according to a second reaction comprising Y+M n− ↔MY+n e− having a second standard reduction potential E cat 0 ,
Y comprises an element, and E St 0 >E cat 0 .
16. The electrochemical device of claim 1 , wherein the ionic regulating element comprises at least one of a resistor or a diode.