Combined Direct Contact Exchanger and Indirect-Contact Heat Exchanger

1 . A device for separating a vapor component from a gas comprising:

a vessel comprising a top portion and a bottom portion, the top portion comprising a gas outlet, a fluid inlet, and a direct-contact heat exchanger, and the bottom portion comprising an indirect-contact heat exchanger, a gas inlet manifold, and a fluid outlet manifold;

the indirect-contact heat exchanger aligned vertically within the vessel and comprising parallel heat exchange surfaces, wherein plenums between the heat exchange surfaces comprise alternating, adjacent ascending gas channels and descending fluid channels; and,

the gas inlet manifold comprising one or more inlets adjacent to a bottom portion of each of the ascending gas channels, and the fluid outlet manifold comprising one or more outlets adjacent to a bottom portion of each of the descending fluid channels.

2 . The device of claim 1 , wherein:

a fluid passes through the fluid inlet and descends through the direct-contact exchanger, exchanging heat, material, or heat and material with bubbles of a carrier gas;

the carrier gas passes through the gas inlet and upward through the ascending gas channels, exchanging heat with the fluid;

the carrier gas bubbles into the direct-contact exchanger as the bubbles of the carrier gas with sufficient momentum to prevent the fluid from passing into the ascending gas channels;

the fluid passes through the descending fluid channels and passes out of the fluid outlet.

3 . The device of claim 2 , wherein the carrier gas comprises flue gas, syngas, producer gas, natural gas, steam reforming gas, hydrocarbons, light gases, refinery off-gases, organic solvents, steam, ammonia, or combinations thereof.

4 . The device of claim 3 , wherein the carrier gas comprises a vapor component comprising carbon dioxide, nitrogen oxide, sulfur dioxide, nitrogen dioxide, sulfur trioxide, hydrogen sulfide, hydrogen cyanide, water, mercury, hydrocarbons, pharmaceuticals, or combinations thereof.

5 . The device of claim 4 , wherein the fluid comprises water, hydrocarbons, liquid ammonia, liquid carbon dioxide, cryogenic liquids, or combinations thereof.

6 . The device of claim 5 , wherein the fluid extracts the vapor component by desublimation, condensation, freezing, entrainment, absorption, or combinations thereof.

7 . The device of claim 6 , wherein the vapor component extracted into the fluid evaporates, sublimates, or combinations thereof, in the descending fluid channels, producing a product gas comprising the vapor component.

8 . The device of claim 2 , wherein flow of the fluid through a top portion of the ascending gas channels is further prevented by use of orifices, sieves, bubble caps, or combinations thereof.

9 . The device of claim 2 , wherein the top portion further comprises a second indirect-contact heat exchanger, the indirect-contact heat exchanger providing cooling to the fluid.

10 . The device of claim 2 , wherein the fluid inlet comprises spray nozzles, droplet generators, misters, or combinations thereof.

11 . The device of claim 2 , wherein the indirect-contact heat exchanger comprises plates, tubes, pipes, or combinations thereof.

12 . A method for separating a vapor component from a gas comprising:

providing a vessel comprising a top portion and a bottom portion, the top portion comprising a gas outlet, a fluid inlet, and a direct-contact heat exchanger, and the bottom portion comprising an indirect-contact heat exchanger, a gas inlet manifold, and a fluid outlet manifold;

providing the indirect-contact heat exchanger aligned vertically and comprising parallel exchange surfaces, wherein plenums between the exchange surfaces comprise alternating, adjacent ascending gas channels and descending fluid channels;

providing the gas inlet manifold comprising one or more inlets adjacent to a bottom portion of each of the ascending gas channels, and the fluid outlet manifold comprising one or more outlets adjacent to a bottom portion of each of the descending fluid channels;

passing a fluid through the fluid inlet, the fluid descending through the direct-contact exchanger, exchanging heat, material, or heat and material with bubbles of a carrier gas;

passing the carrier gas through the gas inlet, the carrier gas ascending upward through the ascending gas channels, exchanging heat with the fluid;

bubbling the carrier gas into the direct-contact exchanger as the bubbles of the carrier gas with sufficient momentum to prevent the fluid from passing into the ascending gas channels;

passing the fluid through the descending fluid channels and out of the fluid outlet.

13 . The method of claim 12 , providing the carrier gas comprising flue gas, syngas, producer gas, natural gas, steam reforming gas, hydrocarbons, light gases, refinery off-gases, organic solvents, steam, ammonia, or combinations thereof, the carrier gas further comprising a vapor component, the vapor component comprising carbon dioxide, nitrogen oxide, sulfur dioxide, nitrogen dioxide, sulfur trioxide, hydrogen sulfide, hydrogen cyanide, water, mercury, hydrocarbons, pharmaceuticals, or combinations thereof.

14 . The method of claim 13 , providing the fluid comprising water, hydrocarbons, liquid ammonia, liquid carbon dioxide, cryogenic liquids, or combinations thereof.

15 . The method of claim 14 , wherein the fluid extracts the vapor component by desublimation, condensation, freezing, entrainment, absorption, or combinations thereof.

16 . The method of claim 15 , wherein the vapor component extracted into the fluid evaporates, sublimates, or combinations thereof, in the descending fluid channels, producing a product gas comprising the vapor component.

17 . The method of claim 12 , wherein flow of the fluid through a top portion of the ascending gas channels is further prevented by use of orifices, sieves, bubble caps, or combinations thereof.

18 . The method of claim 12 , wherein the top portion further comprises a second indirect-contact heat exchanger, the indirect-contact heat exchanger providing cooling to the fluid.

19 . The method of claim 12 , providing the fluid inlet comprising spray nozzles, droplet generators, misters, or combinations thereof.

20 . The method of claim 12 , providing the indirect-contact heat exchanger comprising plates, tubes, pipes, or combinations thereof.