Sealant having fireworthy properties for use with aircraft parts
Fireworthy sealants may be have a variety of compositions and be made by a variety of techniques. In certain implementations, a fireworthy sealant may include a body comprised of a cured, tacky, soft, deformable non-adhesive gel. The gel body may have an upper surface, a lower surface, and a perimeter, wherein the upper and lower surfaces of the gel body, in an uncompressed state, define a body thickness. The sealant may, in an uncompressed state, be dimensioned to fit in a first opening between a wall and an aircraft component surface and deformable when under compression to fit in a second opening, smaller than the first opening. The sealant may be flame retardant and produce low smoke density and low smoke toxicity.
1. A sealant comprising a body and a skeleton encapsulated by the body:
the body comprising a cured, tacky, soft, deformable, non-adhesive gel, the gel body having an upper surface, a lower surface, and a perimeter, wherein the upper and lower surfaces of the gel body, in an uncompressed state, define a body thickness; and
the skeleton comprising multiple openings for encapsulation by the gel body, the skeleton having an upper surface, a lower surface, and a perimeter;
the sealant in an uncompressed state dimensioned to fit in a first opening between a wall and an aircraft component surface and deformable when under compression to fit in a second opening, smaller than the first opening;
wherein the sealant has toxicity limits of less than about: 150 PPM HCN, 1000 PPM CO, 100 PPM NO/NO2, 100 PPM SO2, 100 PPM HF, and 150 PPM HCl under AITM 3-0005, Issue 2; and
wherein the sealant passes 12 second vertical burn test according to 14 CFR, Part 25—Subpart D, § 25.853(a) compartment interiors.
2. The sealant of claim 1 , wherein the gel is 100% solid (no VOCs).
3. The sealant of claim 1 , wherein the sealant has a smoke density of 200 maximum at about 4.0 minutes under AITM2-0007A, Issue 3.
4. The sealant of claim 1 , wherein the sealant comprises a two-part polymer, the first part comprising a polyol and the second part comprising an isocyanate, the two parts when combined curing to form the gel of the gel body, and wherein the skeleton is comprised of a nylon, polypropylene, or fiberglass having a thickness less than about 0.033″.
5. The sealant of claim 1 , wherein the body comprises a polyurethane gel with a molecular weight range is between about 200 to 20,000.
6. The sealant of claim 1 , wherein the tackiness of the sealant is between about 10 and 40 psi.
7. The sealant of claim 1 , wherein the sealant passes the 3000 hour salt fog test according to ASTMB 117.
8. The sealant of claim 1 , wherein the body contains no silicone or silicone oil.
9. The sealant of claim 1 , wherein the sealant substantially recovers its original dimensional configuration in less than one minute after 180 days under compression between about 150 and 350 psi.
10. The sealant of claim 1 , wherein the sealant has a smoke density of 200 maximum at 4.0 min. under AITM2-0007A, Issue 3.
11. The sealant of claim 10 , wherein the sealant comprises a two-part polymer, the first part comprising a polyol and the second part comprising isocyanate, the two parts when combined curing to form the gel of the gel body.
12. The sealant of claim 10 , wherein the gel body comprises a cured polyurethane gel of molecular weight between about 200 and 20,000.
13. The sealant of claim 10 , wherein the skeleton is either nylon or woven fiberglass and less than about 0.033″ thick.
14. The sealant of claim 10 , wherein the volume ratio of gel body to skeleton is in the range of about 3 to 1 and 7 to 1.
15. The sealant of claim 10 , wherein the cured hardness of the gel body is between about 40 and 150 measured by 35 gr. cone penetrometer.
16. The sealant of claim 10 , wherein the body further includes a corrosion inhibiting composition.
17. The sealant of claim 1 , wherein the body thickness is greater than a skeleton thickness.
18. The sealant of claim 1 , wherein the sealant is resistant to degradation upon exposure to common aviation fluids.
19. The sealant of claim 1 , wherein the sealant is a single sided sticky sealant, the sealant provided with a skin on one side of the body, the skin having a surface distal from the body that is non-sticky.
20. A device for providing an environmental seal to an aircraft assembly comprising a first part and a spaced apart second part, the two parts forming a gap, the device comprising:
a sealant comprising a skeleton and a body encapsulating the skeleton, wherein the body is comprised of a cured polyurethane gel, resulting from a mix of a polyol and isocyanate, the sealant having fireworthiness properties and passing the following tests:
wherein the sealant has toxicity limits of less than about: 150 PPM HCN, 1000 PPM CO, 100 PPM NO/NO2, 100 PPM SO2, 100 PPM HF, and 150 PPM HCl under AITM 3-0005, Issue 2;
wherein the sealant passes 12 second vertical burn test according to 14 CFR, Part 25—Subpart D, § 25.853(a) compartment interiors;
wherein the sealant has a smoke density of Ds maximum at about 4.0 min. of under 200 AITM2-0007A, Issue 3;
wherein the skeleton is comprised of a nylon or fiberglass mesh having a thickness less than about 0.033″; and
the body having a tackiness of between 5 and 50 psi; and
wherein the volume of gel/skeleton is in the range of about 3/1 to 7/1.
21. A method for releasably, environmentally sealing a pair of opposing, gap forming, fastener engaging surfaces of aircraft parts, the method comprising the steps of:
providing an adhesive-free elastomeric, tacky sealant having a layer of polyurethane gel encapsulating a skeleton, the sealant having fireworthiness properties;
placing the sealant in the gap between the surfaces; and
compressing the opposing surfaces by tightening the fasteners, and closing the gap contacting the sealant, thereby providing a substantially fluid and air tight seal between the opposed mating surfaces with the sealant substantially filling the gap;
wherein the sealant has a smoke density of 200 maximum at 4.0 min. under 200 AITM2-0007A, Issue 3;
wherein the sealant has toxicity limits of less than about: 150 PPM HCN, 1000 PPM CO, 100 PPM NO/NO2, 100 PPM SO2, 100 PPM HF, and 150 PPM HCl under AITM 3-0005, Issue 2; and
wherein the sealant passes 12 second vertical burn test according to 14 CFR, Part 25—Subpart D, § 25.853(a) compartment interiors.
22. The method of claim 21 , wherein the sealant of the providing step has a tackiness between about 5 and 50 psi.
23. The method of claim 21 , wherein the tightening of the compressing step continues until the sealant visibly deforms.
24. The method of claim 21 , wherein the body comprises a polyurethane gel and the molecular weight range is between about 200 to 20,000.
25. The method of claim 21 , wherein the sealant passes the 3000 hour salt fog test according to ASTMB 117.
26. The method of claim 21 , wherein the body of sealant is deformable under compression.
27. The method of claim 21 , wherein the sealant substantially recovers its original dimensional configuration after 180 days under compression between about 150 and 350 psi.
28. The method of claim 21 , wherein the skeleton is either nylon or woven fiberglass and less than about 0.033″ thick.
29. The method of claim 21 , wherein the sealant is resistant to degradation upon exposure to common aviation fluids.
30. The method of claim 21 , wherein the sealant is a single sided sticky sealant, the sealant provided with a skin on one side of the body, the skin having a surface distal from the body that is non-sticky.