Production of graphene materials directly from carbon/graphite precursor
Provided is a method of producing isolated graphene sheets directly from a carbon/graphite precursor. The method comprises: (a) providing a mass of aromatic molecules wherein the aromatic molecules are selected from petroleum heavy oil or pitch, coal tar pitch, a polynuclear hydrocarbon, or a combination thereof; (b) heat treating this mass and using chemical or mechanical means to form graphene domains dispersed in a disordered matrix of carbon or hydrocarbon molecules, wherein the graphene domains are each composed of from 1 to 30 planes of hexagonal carbon atoms or fused aromatic rings having a length or width from 5 nm to 20 μm and an inter-graphene space between two planes of hexagonal carbon atoms or fused aromatic rings no less than 0.4 nm; and (c) separating and isolating the planes of hexagonal carbon atoms or fused aromatic rings to recover graphene sheets from the disordered matrix.
1. A method of producing isolated graphene sheets, said method comprising:
a) providing a mass of aromatic molecules in a liquid, solid, or semi-solid state wherein said aromatic molecules are selected from petroleum heavy oil or pitch, coal tar pitch, a polynuclear hydrocarbon, or a combination thereof;
b) heat treating said mass of aromatic molecules and using chemical or mechanical means to directly form graphene domains dispersed in a disordered matrix of carbon or hydrocarbon molecules without the formation of meso-carbon microbeads, wherein said graphene domains are each composed of from 1 to 30 planes of hexagonal carbon atoms or fused aromatic rings having a length or width from 5 nm to 20 μm and, in the situations wherein there are 2-30 planes in a graphene domain, having an inter-graphene space between two planes of hexagonal carbon atoms or fused aromatic rings no less than 0.4 nm; and
c) separating and isolating said planes of hexagonal carbon atoms or fused aromatic rings to recover graphene sheets from said disordered matrix without intercalation.
2. The method of claim 1 , wherein said polynuclear hydrocarbon is selected from naphthalene, anthracene, phenanthrene, tetracene, chrysene, triphenylene, pyrene, pentacene, benzo-pyrene, corannulene, benzo-perylene, coronene, ovalene, benzo-fluorene, a derivative thereof having a substituent on a ring structure thereof, a chemical derivative thereof, or a combination thereof.
3. The method of claim 1 , wherein said graphene domains have a length or width from 10 nm to 5 μm or an inter-graphene space no less than 0.5 nm.
4. The method of claim 1 , wherein said graphene domains have an inter-graphene space from 0.5 nm to 2.0 nm.
5. The method of claim 1 , wherein said graphene domains have a length or width from 15 nm to 2 μm.
6. The method of claim 1 , wherein said chemical means includes functionalizing or derivatizing at least one of said planes of hexagonal carbon atoms or fused aromatic rings.
7. The method of claim 1 , wherein said graphene sheets comprise single-layer graphene, double-layer graphene, or triple-layer graphene sheets.
8. The method of claim 1 , wherein said heat treating is conducted at a temperature selected from a range of 150° C. to 3,200° C.
9. The method of claim 1 , wherein said heat treating is conducted at a temperature selected from a range of 200° C. to 2,500° C.
10. The method of claim 1 , wherein said heat treating is conducted at a temperature selected from a range of 300° C. to 1,500° C.
11. The method of claim 1 , wherein said heat treating is conducted at a temperature selected from a range of 400° C. to 1,200° C.
12. The method of claim 1 , wherein said mechanical means include exposing said mass of aromatic molecules to a gaseous environment, flowing fluid, sonic waves, mechanical shearing, or a combination thereof.
13. The method of claim 1 , wherein said step of separating and isolating includes solvent extraction or supercritical fluid extraction of said planes of hexagonal carbon atoms or fused aromatic rings from said disordered matrix to form said graphene sheets.
14. The method of claim 13 , wherein said supercritical fluid includes carbon dioxide.
15. The method of claim 1 , wherein said step (c) includes a step of dissolving, melting, etching, vaporizing, subliming, burning off, or ultrasonicating said disordered matrix material for separating said graphene sheets.
16. The method of claim 1 , wherein said graphene sheets contain at least 80% single-layer graphene or at least 80% few-layer graphene having no greater than 10 graphene planes.
17. The method of claim 1 , wherein said graphene sheets contain pristine graphene, oxidized graphene with less than 5% oxygen content by weight, graphene fluoride, graphene fluoride with less than 5% fluorine by weight, graphene with a carbon content no less than 95% by weight, or chemically modified graphene.
18. The method of claim 1 wherein said chemical means contains adding a functionalizing agent into said mass of organic molecules and said organic molecules are chemically functionalized by said agent.
19. The method of claim 18 , wherein said functionalizing agent contains a chemical functional group selected from alkyl or aryl silane, alkyl or aralkyl group, hydroxyl group, carboxyl group, amine group, sulfonate group (—SO 3 H), aldehydic group, quinoidal, fluorocarbon, or a combination thereof.
20. The method of claim 18 , wherein said functionalizing agent contains an azide compound selected from the group consisting of 2-Azidoethanol, 3-Azidopropan-1-amine, 4-(2-Azidoethoxy)-4-oxobutanoic acid, 2-Azidoethyl-2-bromo-2-methylpropanoate, chlorocarbonate, azidocarbonate, dichlorocarbene, carbene, aryne, nitrene, (R-)-oxycarbonyl nitrenes, where R=any one of the following groups,
and combinations thereof.
21. The method of claim 18 , wherein said functionalizing agent contains an oxygenated group selected from the group consisting of hydroxyl, peroxide, ether, keto, and aldehyde.
22. The method of claim 18 , wherein said functionalizing agent contains a functional group selected from the group consisting of SO 3 H, COOH, NH 2 , OH, R′CHOH, CHO, CN, COCl, halide, COSH, SH, COOR′, SW, SiR′ 3 , Si(—OR′—) y R′ 3 -y, Si(—O—SiR′ 2 —)OR′, R″, Li, AlR′ 2 , Hg—X, TlZ 2 and Mg—X; wherein y is an integer equal to or less than 3, R′ is hydrogen, alkyl, aryl, cycloalkyl, or aralkyl, cycloaryl, or poly(alkylether), R″ is fluoroalkyl, fluoroaryl, fluorocycloalkyl, fluoroaralkyl or cycloaryl, X is halide, and Z is carboxylate or trifluoroacetate, and combinations thereof.
23. The method of claim 18 , wherein said functionalizing agent contains a functional group selected from the group consisting of amidoamines, polyamides, aliphatic amines, modified aliphatic amines, cycloaliphatic amines, aromatic amines, anhydrides, ketimines, diethylenetriamine (DETA), triethylene-tetramine (TETA), tetraethylene-pentamine (TEPA), polyethylene polyamine, polyamine epoxy adduct, phenolic hardener, non-brominated curing agent, non-amine curatives, and combinations thereof.
24. The method of claim 18 , wherein said functionalizing agent contains a functional group selected from OY, NHY, O═C—OY, P═C—NR′Y, O═C—SY, O═C—Y, —CR′1-OY, N′Y or C′Y, and Y is a functional group of a protein, a peptide, an amino acid, an enzyme, an antibody, a nucleotide, an oligonucleotide, an antigen, or an enzyme substrate, enzyme inhibitor or the transition state analog of an enzyme substrate or is selected from R′—OH, R′—NR′ 2 , R′SH, R′CHO, R′CN, R′X, R′N + (R′) 3 X − , R′SiR′ 3 , R′Si(—OR′—) y R′ 3-y , R′Si(—O—SiR′ 2 —)OR′, R′—R″, R′—N—CO, (C 2 H 4 O—) w H, (—C 3 H 6 O—) w H, (—C 2 H 4 O) w —R′, (C 3 H 6 O) w —R′, R′, and w is an integer greater than one and less than 200.
25. The method of claim 18 , wherein said functionalizing agent contains an acrylonitrile chain, polyfurfuryl alcohol, phenolic resin, or a combination thereof.