Processes, products, and compositions having tetraalkylguanidine salt of aromatic carboxylic acid
Disclosed are processes, products, and compositions having tetraalkylguanidine salt of aromatic acid. The processes include providing a pre-mix comprising an aromatic carboxylic acid component and contacting a tetraalkylguanidine with the aromatic carboxylic acid component in the pre-mix to form the tetraalkylguanidine salt of aromatic carboxylic acid or producing a catalyst composition by contacting the tetraalkylguanidine with the aromatic carboxylic acid component to form the tetraalkylguanidine salt of aromatic carboxylic acid. The compositions include the tetraalkylguanidine salt of aromatic carboxylic acid. The product is formed by the tetraalkylguanidine salt of aromatic carboxylic acid.
1. A polyurethane composition, comprising:
at least one polyol component,
a catalyst composition, and
at least one isocyanate component;
wherein the catalyst composition comprises at least one tetraalkylguanidine salt of aromatic carboxylic acid and at least one amine salt of aromatic carboxylic acid; and
wherein the at least one amine salt of aromatic carboxylic acid comprises an aromatic carboxylic acid salt of 1,8-diazabicyclo[5.4.0]undec-7-ene.
2. The composition of claim 1 wherein the composition is substantially free of Hg, Sn, Pb, Bi, Sb, Mn, Fe, Ti, La, Zr, Zn and compounds containing Hg, Sn, Pb, Bi, Sb, Mn, Fe, Ti, La, Zr, Zn.
3. The polyurethane composition of claim 1 , wherein the at least one tetraalkylguanidine salt of aromatic carboxylic acid comprises a tetraalkylguanidine salt of phthalic acid, a tetraalkylguanidine salt of benzoic acid, a tetraalkylguanidine salt of phenyl-propionic acid, a tetraalkylguanidine salt of salicylic acid, or a combination thereof.
4. The polyurethane composition of claim 1 , wherein the at least one amine salt of aromatic carboxylic acid further comprises an amine salt of phthalic acid, an amine salt of benzoic acid, an amine salt of phenyl-propionic acid, an amine salt of salicylic acid, or a combination thereof.
5. The polyurethane composition of claim 1 further comprising at least one member selected from the group consisting of surfactant component, and a crosslinking component.
6. The polyurethane composition of claim 1 , wherein the at least one polyol component comprises a polyether polyol and a grafted polyether polyol containing copolymerized styrene and acrylonitrile.
7. The polyurethane composition of claim 1 , wherein the at least one polyol component comprises a natural oil or fat polyol.
8. The polyurethane composition of claim 1 , wherein the at least one polyol component comprises a polyester polyol.
9. The polyurethane composition of claim 1 , wherein the at least one amine salt comprises a tertiary amine salt.
10. The polyurethane composition of claim 9 , wherein the tertiary amine salt comprises an isocyanate reactive group.
11. The polyurethane composition of claim 9 , wherein the tertiary amine salt is not reactive to an isocyanate.
12. The polyurethane composition of claim 1 , wherein the at least one amine salt is a salt of the aromatic carboxylic acid and at least one member selected from the group consisting of urethane gelling catalyst and urethane blowing catalyst.
13. The polyurethane composition of claim 1 , wherein the at least one amine salt is a salt of at least one tertiary amine and the aromatic carboxylic acid.
14. The polyurethane composition of claim 1 , wherein the at least one polyol component is comprises a polyether triol polyol and the at least one isocyanate component comprises 4, 4′-diphenylmethane diisocyanate.