Positive electrode material for Li-ion battery, method for preparing the same, and Li-ion power battery containing the same
The present application relates to the technical field of Li-ion battery and, more particularly, to a positive electrode material for a Li-ion battery, a method for preparing the same, and a Li-ion battery containing the same. The positive electrode material for a Li-ion battery includes a substrate material and a coating layer coated on a surface of the substrate material, wherein the coating layer includes boron, a chemical formula of the substrate material is Li x Ni a Co b Mn c O 2 , wherein 0.99<x≤1.1, 0.3<a<0.9, 0.1<b<0.4, 0.1<c<0.4, and a+b+c=1; and the substrate material consists of a large particle substrate material and a small particle substrate material. In the present application, by gradation of large particles and small particles, the pellet density, the capacity density, the room-temperature cycle performance, the high-temperature cycle performance and low temperature discharging performance of the Li-ion battery are improved.
1. A positive electrode material for a Li-ion battery, comprising a substrate material and a coating layer coated on a surface of the substrate material, wherein the coating layer comprises boron, a chemical formula of the substrate material is Li x Ni a Co b Mn c O 2 , wherein 0.99<x≤1.1, 0.3<a<0.9, 0.1<b<0.4, 0.1<c<0.4, and a+b+c=1; the substrate material consists of a large particle substrate material and a small particle substrate material.
2. The positive electrode material for a Li-ion battery according to claim 1 , wherein a particle size of the large particle substrate material is in a range of 10 μm-14 μm, and a particle size of the small particle substrate material is in a range of 3 μm-6 μm.
3. The positive electrode material for a Li-ion battery according to claim 1 , wherein a weight ratio of the large particle substrate material with respect to the small particle substrate material is 5-9:1-5.
4. The positive electrode material for a Li-ion battery according to claim 1 , wherein a content of Ni in the large particle substrate material is greater than or equal to a content of Ni in the small particle substrate material; preferably, when the content of Ni in the large particle substrate material is greater than the content of Ni in the small particle substrate material, the content of Ni in the large particle substrate material is in a range of 30%-100%.
5. The positive electrode material for a Li-ion battery according to claim 1 , wherein the coating layer consists of B 2 O 3 .
6. The positive electrode material for a Li-ion battery according to claim 1 , wherein the coating layer accounts for 0.01%-0.2% by weight of the positive electrode material, preferably 0.02%-0.1%.
7. A Li-ion power battery, comprising the positive electrode material according to claim 1 .
8. A method for preparing the positive electrode material for a Li-ion battery according to claim 1 , comprising at least steps as follows:
(1) preparing a precursor of the large particle substrate material according to a molar ratio of all the elements in the large particle substrate material, and preparing a precursor of the small particle substrate material according to a molar ratio of all the elements in the small particle substrate material;
(2) mixing the precursor of the large particle substrate material and a lithium source and then sintering a thus obtained mixture of the precursor of the large particle substrate material and the lithium source to obtain the large particle substrate material;
and mixing the precursor of the small particle substrate material and a lithium source and then sintering a thus obtained mixture of the precursor of the small particle substrate material and the lithium source to obtain the small particle substrate material;
(3) mixing the small particle substrate material obtained in step(2) and the large particle substrate material obtained in step (2) according to a weight ratio, and then mixing a thus obtained mixture of the small particle substrate material and the large particle substrate material with a boron source, and sintering a thus obtained mixture of the small particle substrate material, the large particle substrate material and the boron source to obtain the positive electrode material.
9. The method for preparing the positive electrode material for a Li-ion battery according to claim 8 , wherein in step (2), a sintering temperature is 800° C.-960° C., and a sintering time is 10 h-20 h, after sintering, the mixture is cooled to a room temperature with a cooling rate of 0.5° C./min-2° C./min.
10. The method for preparing the positive electrode material for a Li-ion battery according to claim 8 , wherein in step (3), a sintering temperature is 500° C.-800° C., and a sintering time is 4 h-6 h.