IP Library Granted Patent US 10,799,853
Granted Patent B2
US 10,799,853 · App. 15/718,006 · Granted Oct 13, 2020

Synthesis of AEI and Cu-AEI zeolites

Inventors: Hai-Ying Chen (Wayne, PA); Joseph Fedeyko (Wayne, PA); Raul Lobo (Newark, DE); Trong Pham (Wayne, PA)
Assignee: Johnson Matthey Public Limited Company
B01J29/76B01D53/9418B01J29/70B01J35/0006B01J35/04B01J37/0018B01J37/04B01J37/10C01B39/026C01B39/48B01D2255/20738B01D2255/20761B01D2255/50C01P2006/37F01N3/2066F01N2330/30F01N2370/04F01N2570/14F01N2570/18
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Quick Facts
Patent No.
US 10,799,853
App. No.
15/718,006
Granted
Oct 13, 2020
Kind
B2
Abstract

A method of synthesizing a zeolite comprising the steps of: a. preparing an admixture containing (i) at least one source of alumina, (ii) at least one source of silica, and (iii) at least one structure directing agent (SDA) in hydroxide form, wherein the admixture is essentially free of alkali metals, wherein the at least one structure directing agent (SDA) in hydroxide form is N,N-diethyl-2,6-dimethylpiperidinium; and b. heating the admixture under autogenous pressure at a temperature and with stirring or mixing for a sufficient time to crystalize hydrogen-form zeolite crystals having an AEI framework.

Claims (34)

1. A method of synthesizing a zeolite comprising the steps of:

a. preparing an admixture containing (i) at least one source of alumina, (ii) at least one source of silica, and (iii) at least one structure directing agent (SDA) in hydroxide form, wherein the admixture is essentially free of alkali metals, wherein the admixture has the following composition:

Ratios

SiO 2 /OH

1-4

SiO 2 /SDA(s)

1-4

H 2 O/SiO 2

10-40

alkali metal/SiO 2

0

Al 2 O 3 /SiO 2

0.02-0.05

and wherein the at least one structure directing agent (SDA) in hydroxide form is N,N-diethyl-2,6-dimethylpiperidinium; and

b. heating the admixture under autogenous pressure at a temperature and with stirring or mixing for a sufficient time to crystalize hydrogen-form zeolite crystals having an AEI framework.

2. The method of claim 1 , wherein the admixture is essentially free of metal ions, other than aluminum.

3. The method of claim 1 , wherein the molar ratio of SDA to silica is greater than 0.4:1.

4. The method of claim 1 , wherein the yield on silica is at least about 50%.

5. The method of claim 1 , wherein the sources of silica and alumina are faujasite zeolites.

6. The method of claim 1 , wherein the admixture has the following composition:

Ratios

SiO 2 /OH

1.5-2.5

SiO 2 /SDA(s)

1.5-2.5

H 2 O/SiO 2

15-30

alkali metal/SiO 2

0

Al 2 O 3 /SiO 2

 0.025-0.04.

7. The method of claim 1 , further comprising a second SDA.

8. The method of claim 7 , wherein the second SDA is selected from 3,5-DMP, trimethyl cyclohexylammonium (TMCHA), tetraethylammonium (TEA), Dimethyldipropylammonium (DMDPA), tetrapropylammonium (TPA), tetraethylphosphonium (TEP).

9. The method of claim 7 , wherein the second SDA is N,N-Dimethyl-3,5-dimethylpiperidinium.

Assignments (2)
CHANGE OF ADDRESS Recorded Jan 14, 2026
From: JOHNSON MATTHEY PUBLIC LIMITED COMPANY
To: JOHNSON MATTHEY PUBLIC LIMITED COMPANY
Reel/Frame 074703/0733 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 7, 2019
From: CHEN, HAI-YING; LOBO, RAUL FRANCISCO; FEDEYKO, JOSEPH; PHAM, TRONG
To: JOHNSON MATTHEY PUBLIC LIMITED COMPANY
Reel/Frame 050636/0303 →
Continuity (2)
Provisional Application 62402687 · Sep 30, 2016
Related Publication 20180093256A1 · Apr 5, 2018
Cited By (1)
US 12,415,178