Phosphor, method for manufacturing same, and light-emitting device
A phosphor-containing member includes a transparent member, and a plurality of granular single crystal phosphors dispersed in the transparent member. Each of the plurality of granular single crystal phosphors includes a YAG crystal as a mother crystal. The plurality of granular single crystal phosphors are prepared by crushing the YAG crystal. The YAG crystal has a composition represented by a formula of Y 3-x-y Gd x Ce y Al 5 O 12-w (0.03≤x≤0.2, 0.003≤y≤0.2, −0.2≤w≤0.2). Reduction of fluorescence intensity of the phosphors is less than 3% when an excitation light wavelength is 460 nm and a temperature is increased from 25° C. to 100° C.
1. A phosphor-containing member, comprising:
a transparent member; and
a plurality of granular single crystal phosphors dispersed in the transparent member,
wherein each of the plurality of granular single crystal phosphors comprises a YAG crystal as a mother crystal,
wherein the plurality of granular single crystal phosphors are prepared by crushing the YAG crystal,
wherein the YAG crystal has a composition represented by a formula of Y 3-x-y Gd x Ce y Al 5 O 12-w (0.03≤x≤0.2, 0.003≤y≤0.2, −0.2≤w≤0.2), and
wherein reduction of fluorescence intensity of the phosphors is less than 3% when an excitation light wavelength is 460 nm and a temperature is increased from 25° C. to 100° C.
2. The phosphor-containing member according to claim 1 , wherein a quantum efficiency of the phosphors at 25° C. is not less than 92% when the excitation light wavelength is 460 nm.
3. The phosphor-containing member according to claim 1 , wherein variation of a full width at half maximum (FWHM) of fluorescence spectrum of the phosphors is not more than 1.5 nm when the excitation light wavelength is varied from 460 nm to 480 nm.
4. The phosphor-containing member according to claim 1 , wherein the transparent member comprises one of a silicone resin, an epoxy resin, and a transparent inorganic material.
5. The phosphor-containing member according to claim 1 , wherein the transparent member comprises a transparent inorganic material comprising a glass.
6. The phosphor-containing member according to claim 1 , wherein the granular single crystal phosphors absorb a part of a blueish light to emit a yellowish fluorescent light.
7. The phosphor-containing member according to claim 1 , wherein the granular single crystal phosphors emit a yellowish fluorescent light having a wavelength in a range from 500 nm to 630 nm.
8. A light emitting device, comprising:
a light emitting element for emitting bluish light; and
the phosphor-containing member as defined in claim 2 .
9. The light emitting device according to claim 8 , wherein the light-emitting element and the phosphor-containing member are separately arranged from each other.
10. A light emitting device, comprising:
a light emitting element for emitting bluish light; and
the phosphor-containing member as defined in claim 3 .
11. The light emitting device according to claim 10 , wherein the light-emitting element and the phosphor-containing member are separately arranged from each other.
12. A light emitting device, comprising:
a light emitting element for emitting bluish light; and
the phosphor-containing member as defined in claim 1 .
13. The light emitting device according to claim 12 , wherein the light-emitting element and the phosphor-containing member are separately arranged from each other.