Combined condensing direct-contact exchange and separations
Devices, systems, and methods for separating a vapor from a gas are disclosed. A gas is passed through a direct-contact exchanger. The exchanger using a contact liquid to cool the gas. The gas comprises a vapor. A portion of the vapor is condensed as the gas passes through the direct-contact exchanger, producing a product liquid and a vapor-depleted gas. The product liquid is immiscible in the contact liquid. The product liquid is gravity settled from the contact liquid such that the contact liquid and the product liquid separate in the direct-contact exchanger.
1. A method for separating a vapor from a gas comprising:
passing a gas through a direct-contact exchanger, the direct-contact exchanger using a contact liquid to cool the gas, wherein the gas comprises a vapor;
condensing a portion of the vapor as the gas passes through the direct-contact exchanger to produce a product liquid and a vapor-depleted gas, wherein the product liquid is immiscible in the contact liquid; and,
gravity settling the product liquid from the contact liquid such that the contact liquid and the product liquid separate in the direct-contact exchanger.
2. The method of claim 1 , further comprising decanting the product liquid and the contact liquid out of the direct-contact exchanger into separate vessels.
3. The method of claim 2 , wherein the direct-contact exchanger further comprises a bubble contactor, a spray tower, a distillation column, a packed tower, a liquid-liquid extractor, or a combination thereof.
4. The method of claim 3 , wherein the direct-contact exchanger further comprises a gas inlet, a gas outlet, a contact liquid inlet, a product liquid outlet, and a contact liquid outlet.
5. The method of claim 4 , wherein the gas enters the exchanger through the gas inlet, the vapor-depleted gas exits the exchanger through the gas outlet, the contact liquid enters the exchanger through the contact liquid inlet, the product liquid exits the exchanger through the product liquid outlet, and the contact liquid exits the exchanger through the contact liquid outlet.
6. The method of claim 5 , wherein the direct-contact exchanger further comprises an overflow weir spilling into a stilling well, the contact liquid and the product liquid separating in the stilling well.
7. The method of claim 6 , wherein the product liquid outlet is situated at a bottom portion of the stilling well and the contact liquid outlet is situated above an interface of the contact liquid and the product liquid in the stilling well.
8. The method of claim 6 , wherein the contact liquid outlet is situated at a bottom portion of the stilling well and the product liquid outlet is situated above an interface of the contact liquid and the product liquid in the stilling well.
9. The method of claim 1 , wherein the contact liquid and the product liquid comprise:
a polar compound and a non-polar compound;
a non-polar compound and a polar compound;
a first material and a second material, wherein the first material has a strong affinity for itself and a weak affinity for the second material;
a first material and a second material, wherein the second material has a strong affinity for itself and a weak affinity for the first material;
a first material of a first pure-component density and a second material of a second pure-component density, wherein the first pure-component density and the second pure-component density are substantially different; or,
a combination thereof.
10. The method of claim 1 , wherein the contact liquid comprises a mixture comprising a mixture of a solvent and a compound from a group consisting of:
ionic compounds comprising potassium carbonate, potassium formate, potassium acetate, calcium magnesium acetate, magnesium chloride, sodium chloride, lithium chloride, and calcium chloride; and,
soluble organic compounds comprising glycerol, ammonia, propylene glycol, ethylene glycol, ethanol, and methanol.
11. The method of claim 10 , wherein the solvent comprises water, hydrocarbons, liquid ammonia, liquid carbon dioxide, cryogenic liquids, or combinations thereof.
12. The method of claim 1 , wherein the gas comprises flue gas, syngas, producer gas, natural gas, steam reforming gas, hydrocarbons, light gases, refinery off-gases, organic solvents, water, ammonia, liquid ammonia, or combinations thereof.
13. The method of claim 12 , wherein the vapor comprises carbon dioxide, nitrogen oxide, sulfur dioxide, nitrogen dioxide, sulfur trioxide, hydrogen sulfide, hydrogen cyanide, water, mercury, hydrocarbons, pharmaceuticals, salts, biomass, or combinations thereof.