Rubber compositions containing tackifiers
View Patent ↗A composition comprising, a rubber component selected from the group consisting of a rubber polymer, a synthetic rubber polymer, and combinations thereof; and an alkylphenol resin which is a reaction product of: at least one phenolic monomer selected from the group consisting of phenol, cresol, resorcinol, xylenol, ethyl phenol, alkylresorcinols, and combinations thereof; and at least one alkyl aldehyde having from 5 to 12 carbon atom alkyl groups, is disclosed. The composition can be used to prepare articles of manufacture such as tires, tire treads, tire shoulders, tire sidewalls, rubber belts, and rubber hoses.
1. A composition comprising
a rubber component selected from the group consisting of a rubber polymer, a synthetic rubber polymer, and combinations thereof; and
an alkylphenol resin condensation product which is a reaction product comprising:
at least one phenolic monomer selected from the group consisting of phenol, cresol, resorcinol, xylenol, ethyl phenol, alkylresorcinols, and combinations thereof;
formaldehyde;
an organic solvent selected from the group of an aliphatic hydrocarbon solvent, an aromatic hydrocarbon solvent or combination therein, wherein the organic solvent forms an azeotrope with water;
an acid catalyst;
a base catalyst;
water; and
at least one alkyl aldehyde having from 5 to 12 carbon atom alkyl groups, wherein the alkylphenol resin condensation product comprises a resole alkylphenol resin condensation product.
2. The composition of claim 1 , wherein the alkylphenol resin condensation product does not contain octylphenol or nonylphenol.
3. The composition of claim 1 , wherein the alkyl aldehyde is selected from the group consisting of 3,5,5-trimethyl hexanal, nonanal, 2-ethyl hexanal, and combinations thereof.
4. A composition in accordance with claim 1 , wherein the alkylphenol resin condensation product is present in the composition in a range of from 1 phr to 10 phr.
5. A composition in accordance with claim 1 , wherein the synthetic rubber polymer is selected from the group consisting of styrene butadiene rubber, polybutadiene rubber, halogenated butyl rubber, butyl rubber, polyisoprene rubber, styrene/isoprene/butadiene rubber, and combinations thereof.
6. A composition in accordance with claim 1 , having a tan δ at 0° C. as measured by Dynamic Mechanical Analysis in the range of from 0.12 to 0.17.
7. A composition in accordance with claim 1 , having a tan δ at 60° C. as measured by Dynamic Mechanical Analysis in the range of from 0.10 to 0.16.
8. A composition in accordance with claim 1 , having an ultimate elongation as measured by ASTM D412 in the range of from 550% to 800%.
9. A composition in accordance with claim 1 , having an elastic modulus at 60° C. in the range of from 3.60×106 Pa to 5.00×106 Pa.
10. An article of manufacture prepared using the composition of claim 1 , wherein the article is selected from the group consisting of a tire, a tire tread, a tire shoulder, a tire sidewall, a rubber belt, and a rubber hose.