Carbon Dioxide Capture from Flu Gas

1 . A method for separating carbon dioxide from a gas stream comprising:

cooling a compressed flue gas stream, comprising carbon dioxide, by passing the compressed flue gas stream across a cooling side of a first indirect-contact heat exchanger to produce a cooled flue gas stream;

passing the cooled flue gas stream through a direct-contact desublimating exchanger, the direct-contact desublimating exchanger using a contact liquid stream, wherein:

a first portion of the carbon dioxide desublimates, absorbs, condenses, freezes, or a combination thereof into the contact liquid stream, forming a first solid product stream entrained in the contact liquid stream as a slurry; and

removal of the first portion of the carbon dioxide from the cooled flue gas stream results in a partially-stripped flue gas stream;

separating the slurry and the partially-stripped flue gas stream in a slurry-gas separator;

passing the partially-stripped flue gas stream through an expansion device, such that a temperature of the partially-stripped flue gas drops and a second portion of the carbon dioxide desublimates, condenses, freezes, or a combination thereof, to produce a second solid product stream and a stripped flue gas stream;

separating the second solid product stream and the stripped flue gas stream in a solid-gas separator;

heating the stripped flue gas stream by passing the stripped flue gas stream across a heating side of a second indirect-contact heat exchanger that cools the contact liquid stream or through the heating side of the first indirect-contact heat exchanger, or a combination thereof, to produce a warmed stripped flue gas product and providing a portion of cooling needed for cooling the compressed flue gas stream;

pressurizing the slurry and the second solid product stream above carbon dioxide's triple-point pressure either together in a first separator or separately in a first separator and a second separator such that the contact liquid and any entrained gases are substantially driven from the solid product stream, forming a substantially pure contact liquid stream, a substantially pure product gas stream, and a pressurized solid stream;

heating the pressurized solid stream to its melting point such that the pressurized solid stream melts to form a product liquid stream.

2 . The method of claim 1 , wherein the pressurized solid stream is melted by exchanging heat across a third indirect-contact heat exchanger, wherein the exchanged heat is provided by a warm exchange fluid stream.

3 . The method of claim 2 , wherein the exchanged heat comprises latent heat provided by the warm exchange fluid stream condensing from a gas to a liquid, the warm exchange fluid stream condensing into a liquid exchange fluid stream.

4 . The method of claim 3 , wherein the liquid exchange fluid stream is further cooled and is used to cool the substantially pure contact liquid stream.

5 . The method of claim 1 , wherein a portion of the heating required to melt the pressurized solid stream is drawn from the substantially pure contact liquid or the compressed flue gas stream.

6 . The method of claim 1 , wherein the compressed flue gas stream further comprises water, sulfur dioxide, nitrogen dioxide, nitrogen oxide, hydrogen chloride, mercury, or combinations thereof.

7 . The method of claim 6 , further comprising separating at least a portion of the sulfur dioxide, the nitrogen dioxide, the hydrogen chloride, the mercury, or a combination thereof from the compressed flue gas stream with the first portion of the carbon dioxide.

8 . The method of claim 1 , further comprising removing sulfur dioxide, nitrogen dioxide, hydrogen chloride, mercury, or a combination thereof from the compressed flue gas stream before cooling the compressed flue gas stream.

9 . The method of claim 1 , wherein the flue gas is produced from a hydrocarbon processing plant comprising coal, black liquor, natural gas, oil, biomass, waste, pet coke, oil shale, tar sands, or a combination thereof.

10 . The method of claim 1 , wherein the compressed flue gas stream contains substantially no water.

11 . The method of claim 1 , wherein the second solid product stream deposits on the expansion device, blocking the expansion device.

12 . The method of claim 9 , wherein the second solid product stream is removed by a mechanical scraper.

13 . The method of claim 1 , wherein pressurizing the slurry and the second solid product stream comprises a pump, hydraulic ram, screw press, progressive cavity pump, or combinations thereof.

14 . The method of claim 11 , wherein the expansion device comprises a turbine, an expansion valve, or a combination thereof.

15 . The method of claim 12 , wherein the expansion device provides power, work, or a combination thereof.

16 . The method of claim 12 , wherein the turbine and the compressor share a drive shaft.

17 . The method of claim 1 , wherein the warmed stripped flue gas product is stored in high-pressure storage vessels.

18 . The method of claim 17 , wherein the warmed stripped flue gas product is used for power grid levelization.

19 . The method of claim 1 , wherein the warmed stripped flue gas product is passed through turbines to produce electricity.

20 . The method of claim 1 , further comprising cooling the partially-stripped flue gas stream as it enters or exits the expansion device.