Nano imprinting with reusable polymer template with metallic or oxide coating
Methods and systems are provided for fabricating polymer-based imprint lithography templates having thin metallic or oxide coated patterning surfaces. Such templates show enhanced fluid spreading and filling (even in absence of purging gases), good release properties, and longevity of use. Methods and systems for fabricating oxide coated versions, in particular, can be performed under atmospheric pressure conditions, allowing for lower cost processing and enhanced throughput.
1. A method of forming an imprint lithography template, the method comprising:
forming a polymer layer on a surface of a base layer;
forming a pattern in the polymer layer to create a patterned polymer layer;
selecting a metal from a group consisting of Gold Palladium (AuPd), Silver Palladium (AgPd), Gold (Au), Silver (Ag), Platinum (Pt) and alloys thereof;
determining a desired layer thickness as a function of both the selected metal and an attribute of the pattern; and
depositing the selected metal on the patterned polymer layer to form a metal layer of the determined desired layer thickness.
2. The method of claim 1 , wherein the desired layer thickness is between 2 and 50 nanometers.
3. The method of claim 1 , wherein forming the pattern in the polymer layer to define the patterned polymer layer comprises contacting the polymer layer with an additional imprint lithography template.
4. The method of claim 3 , wherein forming the pattern in the polymer layer to define the patterned polymer layer comprises, after contacting the polymer layer with the additional imprint lithography template, solidifying the polymer layer to define the patterned polymer layer.
5. The method of claim 1 , wherein the base layer comprises silicon, glass, or a flexible film.
6. The method of claim 1 , wherein depositing the selected metal includes depositing the selected metal on the patterned polymer layer by sputtering.
7. The method of claim 1 , wherein depositing the selected metal includes depositing the selected metal on the patterned polymer layer by evaporation.
8. The method of claim 1 , wherein depositing the selected metal includes depositing the selected metal on the patterned polymer layer by atomic layer deposition (ALD).
9. A method of forming an imprint lithography template, comprising:
forming a polymer layer on a surface of a base layer;
forming a pattern in the polymer layer to create a patterned polymer layer;
selecting a type of metal of a metal layer to be formed on the patterned polymer layer;
determining a desired layer thickness of the metal layer as a function of both i) the selected type of metal of the metal layer and ii) an attribute of the pattern of the patterned polymer layer; and
depositing the selected metal on the patterned polymer layer to form the metal layer of the determined desired layer thickness by one of sputtering, evaporation, or atomic layer deposition.
10. The method of claim 9 , wherein the metal is selected from a group consisting of Gold (Au), Gold Palladium (AuPd), and alloys thereof.
11. The method of claim 9 , wherein the metal is selected from a group consisting of Silver (Ag), Platinum (Pt), Silver Palladium (AgPd), and alloys thereof.
12. The method of claim 9 , wherein the desired layer thickness is between 2 and 50 nanometers.
13. The method of claim 9 , wherein forming the pattern in the polymer layer to define the patterned polymer layer comprises contacting the polymer layer with an additional imprint lithography template.
14. The method of claim 13 , wherein forming the pattern in the polymer layer to define the patterned polymer layer comprises, after contacting the polymer layer with the additional imprint lithography template, solidifying the polymer layer to define the patterned polymer layer.
15. The method of claim 9 , wherein the base layer comprises silicon, glass, or a flexible film.