Methods for the treatment of a flue gas stream using catalytically-enhanced sorbent compositions
View Patent ↗A sorbent composition that is useful for injection into a flue gas stream of a coal burning furnace to efficiently remove mercury from the flue gas stream. The sorbent composition may include a sorbent with an associated ancillary catalyst component that is a catalytic metal, a precursor to a catalytic metal, a catalytic metal compound or a precursor to a catalytic metal compound. Alternatively, a catalytic metal or metal compound, or their precursors, may be admixed with the coal feedstock prior to or during combustion in the furnace, or may be independently injected into a flue gas stream. A catalytic promoter may also be used to enhance the performance of the catalytic metal or metal compound.
1. A method for the removal of mercury from a flue gas stream, the method comprising the steps of:
combusting a fuel source, the combusting generating a flue gas stream comprising one or more contaminants;
contacting the flue gas stream with (i) a solid sorbent comprising powdered activated carbon and having a mean particle diameter of not greater than about 25 μm, and (ii) an ancillary catalyst component, wherein the ancillary catalyst component comprises a metal salt having a metal cation and an anion, where the metal is selected from the group consisting of Fe, Cu, Mn, Zn, and the anion is selected from the group consisting of a chloride, a sulfate, a carbonate, and a nitrate;
maintaining the ancillary catalyst component in contact with the flue gas stream for a period of time sufficient to catalytically oxidize at least a portion of the mercury and form an oxidized contaminant species; and
sequestering the oxidized contaminant species with the solid sorbent.
2. The method recited in claim 1 , wherein the solid sorbent has a mean particle diameter (D50) of not greater than about 20 μm.
3. The method recited in claim 1 , wherein the solid sorbent has a mean particle diameter (D50) of not greater than about 15 μm.
4. The method recited in claim 1 , wherein the catalytic metal compound is selected from the group consisting of copper (II) chloride (CuCl 2 ), copper (II) nitrate (Cu(NO 3 ) 2 ), copper (II) carbonate (CuCO 3 ), iron (III) chloride (FeCl 3 ), iron (III) nitrate (Fe(NO 3 ) 3 ), iron (III) sulfate Fe 2 (SO4) 3 and zinc sulfate (ZnSO 4 ).
5. The method recited in claim 1 , further comprising the step of contacting the flue gas stream with a catalytic promoter.
6. The method recited in claim 5 , wherein the catalytic promoter comprises a metal selected from the group consisting of alkali metals and alkaline earth metals.
7. The method recited in claim 5 , wherein the catalytic promoter comprises a metal selected from the group consisting of Al, Li, Na, K, Be, Ca, Sr, Ba, Sc, Y, Mg and combinations thereof.
8. The method recited in claim 1 , wherein the flue gas stream is contacted with the solid sorbent and with the ancillary catalyst component in the absence of any added halogen that is not a constituent of the ancillary catalyst component.
9. The method recited in claim 1 , wherein the ancillary catalyst component is dispersed on the solid sorbent to form a sorbent composition comprising catalytically active sorbent particles.
10. The method recited in claim 1 , wherein the ancillary catalyst component is physically separate from the solid sorbent when contacted with the flue gas stream.
11. The method recited in claim 10 , wherein the ancillary catalyst component is injected into the flue gas stream separate from the solid sorbent.
12. The method recited in 10 , wherein the ancillary catalyst component is added to the fuel source before or during combustion of the fuel source.
13. The method recited in claim 1 , wherein the fuel source comprises coal.
14. The method recited in claim 1 , wherein the cation is selected from the group consisting of a chloride, a sulfate and a nitrate.
15. The method recited in claim 1 , wherein the solid sorbent comprises activated carbon derived from lignite coal.
16. The method recited in claim 1 , wherein the solid sorbent comprises at least about 0.5 wt. % and not greater than about 5 wt. % of the ancillary catalyst component.
17. A method for the removal of one or more contaminants from a flue gas stream, the method comprising the steps of:
combusting a fuel source, the combusting generating a flue gas stream comprising one or more contaminants;
contacting the flue gas stream with a solid sorbent and with an ancillary catalyst component, wherein the ancillary catalyst component comprises a metal cation an anion, where the metal is selected from the group consisting of Fe, Cu, Mn, Zn, and the anion is selected from the group consisting of a chloride, a sulfate, a carbonate, and a nitrate;
maintaining the ancillary catalyst component in contact with the flue gas stream for a period of time sufficient to catalytically oxidize at least a portion of the one or more contaminants and form an oxidized contaminant species; and
sequestering the oxidized contaminant species with the solid sorbent;
wherein the ancillary catalyst component is physically separate from the solid sorbent when contacted with the flue gas stream.
18. The method recited in claim 17 , wherein the ancillary catalyst component is injected into the flue gas stream separate from the solid sorbent.
19. The method recited in claim 17 , wherein the ancillary catalyst component is added to the fuel source before or during combustion of the fuel source.