Polyolefin micro porous film, separator film for power-storage device, and power-storage device
A polyolefin micro porous film includes at least one of polyethylene and polypropylene, in which the compressive elastic modulus is 95 MPa or more and 150 MPa or less, the surface roughness (Ra) of a film surface is measured for a front surface and a rear surface, and the average value (Ra(ave)) thereof is 0.01 μm to 0.30 μm.
1. A polyolefin micro porous film having:
a compressive elastic modulus of 105 MPa to 145 MPa,
an average value (Ra(ave)) of a surface roughness (Ra) of a film surface measured at a front surface and a rear surface of 0.05-0.23 μm,
a maximal micropore diameter obtained by using a mercury porosimeter is in a range of 0.08 to 0.18 μm, and
a porosity of 35% to 60%,
wherein the polyolefin micro porous film comprises a layer of polyethylene having two surfaces, and a polypropylene layer laminated to each of the two surfaces of the polyethylene layer,
an amount of strain in a compression direction is in a range of 0.010 to 0.037 when a strain pressure of 2.7 MPa is applied,
after a pressure of 17.3 MPa is applied thereto, a Gurley value obtained when the pressure is released is higher than a Gurley value obtained before the pressure is applied thereto, and its increase rate of the Gurley value is 0.5% or more and 29.0% or less,
after a pressure of 11.5 MPa is applied thereto, a Gurley value obtained when the pressure is released is higher than a Gurley value obtained before the pressure is applied thereto, and its increase rate of the Gurley value is 0.05% or more and 6.0% or less,
a thermal shrinkage ratio in a TD direction is in a range of −1.0% to 1.0%, and a thermal shrinkage ratio in an MD direction is in a range of 0.5% to 8.0%,
a Gurley value is in a range of 100 to 600 sec/100 cc, a film thickness is in a range of 10 to 40 μm, a puncture strength is in a range of 200 to 700 gf.
2. The polyolefin micro porous film according to claim 1 , wherein a shutdown temperature in a range of 130° C. to 140° C., and a meltdown temperature is 175° C. or higher and 190° C. or lower.
3. The polyolefin micro porous film according to claim 1 , wherein a heat-resistant porous layer primarily containing heat-resistant fine particles and containing a resin binder is provided on the polyolefin micro porous film.
4. A separator film for a power-storage device using the polyolefin micro porous film according to claim 1 .
5. A power-storage device comprising:
a positive electrode;
a negative electrode;
the polyolefin micro porous film according to claim 1 interposed between the positive electrode and the negative electrode; and
a nonaqueous electrolyte with which the polyolefin micro porous film is impregnated,
wherein a resistance value obtained by DC-R measurement upon application of a pressure of 2.7 MPa is in a range of 100.1% to 105.0%, wherein 100% is a resistance value when no pressure is applied.
6. The polyolefin micro porous film according to claim 1 , wherein an interlaminar peel strength is in a range of 3 g to 80 g/15 mm.
7. The polyolefin micro porous film according to claim 1 , wherein the porosity is 42% to 50%.