IP Library Granted Patent US 10,793,770
Granted Patent B2
US 10,793,770 · App. 15/735,178 · Granted Oct 6, 2020

Enhanced proppant transport for hydraulic fracturing

Inventors: Abdelaziz Rahy (Waxahachie, TX); DeWitt Knox (Mansfield, TX); Mohand Melbouci (Wilmington, DE); Christopher Alameddin (Denver, CO); Joel F. Siegel (Denver, CO); Benjamin J. Poppel (Westminster, CO); Leendert Weijers (Greenwood Village, CO); Ronald Gusek (Denver, CO)
C09K8/90C08B37/14C08L5/00C08L33/26C09K8/80C09K8/882C09K8/887E21B43/00C09K8/92C09K2208/28E21B43/267
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Quick Facts
Patent No.
US 10,793,770
App. No.
15/735,178
Granted
Oct 6, 2020
Kind
B2
Abstract

A dry composition of dry polyacrylamide and dry guar; or a liquid suspension made from the dry composition for treating subterranean formations and methods for enhancing proppant transport in fracturing fluids using the composition.

Claims (27)

1. A method for enhancing proppant transport in fracturing fluids for hydraulic fracturing comprising the steps of:

a) combining from 10-90% by weight of a dry naturally-derived polymer having a particle size below 500 μm and from 10-90% by weight of dry synthetic friction reducer having a particle size below 500 μm to form a dry friction reducing composition;

b) forming a liquid suspension from said dry friction reducing composition by adding said at least 20 percent by weight of said composition to a liquid carrier, the liquid carrier comprising mineral oil;

c) introducing said liquid suspension into a hydraulic fracturing fluid to form a treated hydraulic fracturing fluid;

d) adding said treated hydraulic fracturing fluid to a wellbore having a hole in a subterranean formation and

e) pumping said treated hydraulic fracturing fluid down said hole to frac said wellbore;

wherein said treated hydraulic fracturing fluid carries a minimum of 3 ppa proppant, is more crosslinkable and has a higher breakability.

2. The method of claim 1 wherein said liquid carrier further comprises glycol.

3. The method of claim 1 wherein said synthetic friction reducer is a water-soluble polymer.

4. The method of claim 3 wherein said water-soluble polymer is selected from the group consisting of polyacrylamide, polyethylene oxide and combinations thereof.

5. The method of claim 1 wherein said naturally-derived polymer is selected from the group consisting of guar, guar derivatives, cellulose derivatives and combinations thereof.

6. The method of claim 1 wherein said naturally-derived polymer is guar and said synthetic friction reducer is polyacrylamide fine powder having a particle size below 200 μm.

7. The method of claim 1 wherein said liquid suspension further comprises a cross-linking agent.

8. The method of claim 1 wherein said liquid suspension has a minimum linear gel viscosity of 15 cP at 4 pptg polymer loading.

9. The method of claim 1 wherein the fracturing fluid is slickwater formed from additives selected from the group consisting of polyacrylamide, polyethylene oxide, guar, cellulosics and combinations thereof.

10. The method of claim 6 wherein the range of guar to polyacrylamide of said dry friction reducing composition is in the range of 10% to 90% by weight to 90% to 10% by weight.

11. The composition of claim 1 , wherein the liquid suspension further comprises an organophilic clay.

12. The composition of claim 1 , wherein the liquid suspension further comprises surfactant.

13. A method for increasing the efficiency of a polyacrylamide additive in slickwater fracturing comprising the steps of:

a) combining dry polyacrylamide fine powder having a particle size below 500 μm with dry guar having a particle size below 500 μm to form an additive composition to form a dry friction reducing composition;

b) forming a liquid suspension from said dry friction reducing composition by adding said at least 20 percent by weight of said composition to a liquid carrier, the liquid carrier comprising mineral oil;

c) introducing said liquid suspension into a hydraulic fracturing fluid to form a treated hydraulic fracturing fluid;

d) adding said treated hydraulic fracturing fluid to a wellbore having a hole in a subterranean formation and

e) pumping said treated hydraulic fracturing fluid down said hole to frac said wellbore;

wherein said treated hydraulic fracturing fluid carries a minimum of 3 ppa proppant, is more crosslinkable and has a higher breakability.

14. The method of claim 13 , wherein the liquid suspension further comprises an organophilic clay.

15. The method of claim 13 , wherein the liquid suspension further comprises surfactant.

Assignments (7)
RELEASE OF SECURITY INTEREST IN PATENTS FILED MARCH 4,2019 AT REEL/FRAME 048491/0404 Recorded Aug 2, 2023
From: BANK OF AMERICA, N.A., AS COLLATERAL AGENT
To: UNIVAR SOLUTIONS USA INC.; NEXEO SOLUTIONS, LLC
Reel/Frame 064473/0801 →
NOTICE OF GRANT OF SECURITY INTEREST IN PATENTS (ABL) Recorded Aug 2, 2023
From: UNIVAR SOLUTIONS USA INC.; NEXEO SOLUTIONS, LLC
To: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 064465/0186 →
RELEASE OF SECURITY INTEREST IN PATENTS FILED MARCH 1, 2019 AT REEL/FRAME 048480/0280 Recorded Aug 2, 2023
From: BANK OF AMERICA, N.A., AS COLLATERAL AGENT
To: UNIVAR SOLUTIONS USA INC.; NEXEO SOLUTIONS, LLC
Reel/Frame 064474/0619 →
NOTICE OF GRANT OF SECURITY INTEREST IN PATENTS (FIRST LIEN) Recorded Aug 1, 2023
From: UNIVAR SOLUTIONS USA INC.; NEXEO SOLUTIONS, LLC
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 064460/0825 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 24, 2023
From: RAHY, ABDELAZIZ; KNOX, DEWITT; MELBOUCI, MOHAND; ALAMEDDIN, CHRISTOPHER; SIEGEL, JOEL F.; POPPEL, BENJAMIN J.; WEIJERS, LEENDERT; GUSEK, RONALD
To: UNIVAR USA INC.
Reel/Frame 062470/0156 →
ABL SECURITY AGREEMENT Recorded Mar 4, 2019
From: UNIVAR USA INC.; NEXEO SOLUTIONS, LLC
To: BANK OF AMERICA, N.A.
Reel/Frame 048491/0404 →
TERM LOAN SECURITY AGREEMENT Recorded Mar 1, 2019
From: UNIVAR USA INC.; NEXEO SOLUTIONS, LLC
To: BANK OF AMERICA, N.A.
Reel/Frame 048480/0280 →
Continuity (2)
Provisional Application 62174883 · Jun 12, 2015
Related Publication 20180155615A1 · Jun 7, 2018