Polyester blends with improved oxygen scavenging ability
Disclosed herein is an oxygen scavenging composition for containers. The oxygen scavenging composition may comprise at least one polyester component, which is a copolyester containing a metal sulfonate salt group, a transition metal catalyst, and a vegetable oil. The vegetable oil may comprise at least one molecule having a double allylic structure. The copolyester containing a metal sulfonate salt group may comprise at least one acid unit and at least one diol unit. The concentration of the double allylic structures of the vegetable oil in the composition may be greater than 5.0 meq/kg of all of the polyester components. The composition may also be void of or substantially void of a polyamide.
1. An oxygen scavenging composition for containers comprising:
at least one polyester component which is a copolyester containing a metal sulfonate salt group,
a transition metal catalyst, and
a vegetable oil comprising at least one molecule having a double allylic structure,
wherein the copolyester containing a metal sulfonate salt group comprises at least one acid unit and at least one diol unit, the concentration of the double allylic structures of the vegetable oil in the composition is greater than 5.0 meq/kg of all of the polyester components, and the composition is substantially void of a polyamide.
2. The composition of claim 1 , wherein the metal sulfonate salt group is a metal sulfoisophthalate derived from a metal salt of 5-sulfoisophthalic acid, its dimethyl ester or its glycol ester.
3. The composition of claim 2 , wherein the metal salt of 5-sulfoisophthalic acid, its dimethyl ester or its glycol ester comprises a metal ion selected from the group consisting of Na + , Li + , K + , Zn 2+ , Mn 2+ , Co 2+ and Ca 2+ .
4. The composition of claim 1 , wherein the metal sulfonate salt group is in a range selected from the group consisting of 0.01 to 10.0 mole percent, 0.01 to 2.0 mole percent, 0.05 to 1.1 mole percent, 0.10 to 0.74 mole percent and 0.10 to 0.6 mole percent based upon the total moles of acid units in all of the polyester components.
5. The composition of claim 1 , wherein the transition metal catalyst is a compound containing at least one cobalt atom in a positive oxidation state.
6. The composition of claim 1 , wherein the transition metal catalyst is a salt containing at least one cobalt atom in a positive oxidation state.
7. The composition of claim 1 , wherein the transition metal catalyst is added to the composition at a level in a range selected from the group of between 10 and 600 ppm, between 20 and 400 ppm and between 40 and 200 ppm of metal relative to the total amount of the polyester components and vegetable oil present in the composition.
8. The composition of claim 1 , wherein the composition is void of a polyamide.
9. The composition of claim 1 , wherein the composition further comprises TiO 2 .
10. The composition of claim 9 , wherein the TiO 2 is present in the composition at a level in a range selected from the group consisting of between 0.1 and 15% by weight of the composition, between 0.1 and 10% by weight of the composition, between 0.1 and 5% by weight of the composition and between 0.1 and 2% by weight of the composition.
11. A preform manufactured from the composition of claim 1 .
12. A biaxially oriented container manufactured from the preform of claim 11 .
13. An oxygen scavenging composition for containers comprising:
at least one polyester component,
a transition metal catalyst,
a vegetable oil comprising at least one molecule having a double allylic structure, and
TiO 2 ,
wherein the concentration of the double allylic structures of the vegetable oil in the composition is greater than 5.0 meq/kg of all of the polyester components, and the composition is substantially void of a polyamide.
14. The composition of claim 13 , wherein the transition metal catalyst is a compound containing at least one cobalt atom in a positive oxidation state.
15. The composition of claim 13 , wherein the transition metal catalyst is a salt containing at least one cobalt atom in a positive oxidation state.
16. The composition of claim 13 , wherein the transition metal catalyst is added to the composition at a level in a range selected from the group of between 10 and 600 ppm, between 20 and 400 ppm and between 40 and 200 ppm of metal relative to the total amount of the polyester components and vegetable oil present in the composition.
17. The composition of claim 13 , wherein the composition is void of a polyamide.
18. The composition of claim 13 , wherein the TiO 2 is present in the composition at a level in a range selected from the group consisting of between 0.1 and 15% by weight of the composition, between 0.1 and 10% by weight of the composition, between 0.1 and 5% by weight of the composition and between 0.1 and 2% by weight of the composition.
19. A preform manufactured from the composition of claim 13 .
20. A biaxially oriented container manufactured from the preform of claim 19 .