Fiber reinforced polypropylene composition with high strain at break
The invention is related to a fiber reinforced composition with superior balance of the strength/stiffness and the strain at break. It is further related to articles comprising the fiber reinforced composition.
1. A fiber reinforced composition comprising
(a) 5.0 to 89.5 wt. % of a heterophasic polypropylene copolymer (HECO),
(b) 5.0 to 89.5 wt. % of a propylene polymer (PP) having a melt flow rate MFR2 at 230° C. measured according to ISO 1133 of 1-150 g/10 min,
(c) 5.0 to 65.0 wt. % of Glass fibers (GF) and
(d) 0.5 to 5.0 wt. % of a polar modified polypropylene as adhesion promoter (AP),
based on the total weight of the fiber reinforced composition, wherein
(i) the heterophasic polypropylene copolymer (HECO) having a xylene cold soluble (XCS) content in the range of 10.0 to lower than 25.0 wt. % based on the heterophasic polypropylene copolymer (HECO);
(ii) the xylene cold soluble (XCS) fraction of the heterophasic polypropylene copolymer (HECO) having a comonomer content in the range of 15.0 to 35.0 wt. %, and an intrinsic viscosity (IV) of lower than 2.0 dl/g,
wherein the weight ratio between the heterophasic polypropylene copolymer (HECO) and the propylene polymer (PP) is in the range of 1:5 to 1:1.
2. The fiber reinforced composition according to claim 1 , wherein said heterophasic polypropylene copolymer (HECO) has a melt flow rate MFR2 at 230° C. measured according to ISO 1133 in the range of higher than 2.0 to 50.0 g/10 min.
3. The fiber reinforced composition according to claim 1 , wherein said heterophasic polypropylene copolymer (HECO) has a comonomer content in the range of 5.0 to 30.0 wt. % based on the said heterophasic polypropylene copolymer (HECO).
4. The fiber reinforced composition according to claim 1 , wherein said heterophasic polypropylene copolymer (HECO) comprises a matrix (M) being a propylene random copolymer (M-RPP) and an elastomeric propylene copolymer (E) dispersed in said matrix (M), wherein
a) said propylene random copolymer (M-RPP) has a melt flow rate MFR2 at 230° C. of below 30 g/10 min;
or
b) the comonomer content of the said propylene random copolymer (M-RPP) is in the range of 1 to 8 wt. %.
5. The fiber reinforced composition according to claim 1 , wherein said propylene polymer (PP) is selected from the group consisting of a propylene homopolymer (H-PP) and a random polypropylene copolymer (R-PP) with a comonomer content in the range of 1.0 to 5.0 wt. % based on the random polypropylene copolymer (R-PP).
6. The fiber reinforced composition according to claim 1 , wherein said propylene polymer (PP) has a xylene cold soluble (XCS) content of not more than 20 wt. % based on the propylene polymer (PP).
7. The fiber reinforced composition according to claim 1 , wherein the tensile strain at break of the fiber reinforced composition measured according to ISO 527-2 is not lower than 4.0%.
8. The fiber reinforced composition according to claim 1 , wherein the tensile strength of the fiber reinforced composition measured according to ISO 527-2 is not lower than 80.0 MPa.
9. The fiber reinforced composition according to claim 1 , wherein the Notched impact strength at 23° C. of the fiber reinforced composition measured according to ISO 179 2C is not lower than 12.0 kJ/m2.
10. An automotive article comprising the fiber reinforced composition according to claim 1 .
11. A foamed article, comprising the fiber reinforced composition according to claim 1 .
12. A method comprising producing automotive articles with a fiber reinforced composition, the fiber reinforced composition comprising
(a) 5.0 to 89.5 wt. % of a heterophasic polypropylene copolymer (HECO),
(b) 5.0 to 89.5 wt. % of a propylene polymer (PP) having a melt flow rate MFR2 at 230° C. measured according to ISO 1133 of 1-150 g/10 min,
(c) 5.0 to 65.0 wt. % of Glass fibers (GF) and
(d) 0.5 to 5.0 wt. % of a polar modified polypropylene as adhesion promoter (AP),
based on the total weight of the fiber reinforced composition, wherein
(i) the heterophasic polypropylene copolymer (HECO) having a xylene cold soluble (XCS) content in the range of 10.0 to lower than 25.0 wt. % based on the heterophasic polypropylene copolymer (HECO);
(ii) the xylene cold soluble (XCS) fraction of the heterophasic polypropylene copolymer (HECO) having a comonomer content in the range of 15.0 to 35.0 wt. %, and an intrinsic viscosity (IV) of lower than 2.0 dl/g,
wherein the weight ratio between the heterophasic polypropylene copolymer (HECO) and the propylene polymer (PP) is in the range of 1:5 to 1:1, the automotive article is a foamed article and the method comprises the step of chemical or physical foaming.
13. A method comprising producing parts of washing machines or dishwashers with a fiber reinforced composition, the fiber reinforced composition comprising
(a) 5.0 to 89.5 wt. % of a heterophasic polypropylene copolymer (HECO),
(b) 5.0 to 89.5 wt. % of a propylene polymer (PP) having a melt flow rate MFR2 at 230° C. measured according to ISO 1133 of 1-150 g/10 min,
(c) 5.0 to 65.0 wt. % of Glass fibers (GF) and
(d) 0.5 to 5.0 wt. % of a polar modified polypropylene as adhesion promoter (AP),
based on the total weight of the fiber reinforced composition, wherein
(i) the heterophasic polypropylene copolymer (HECO) having a xylene cold soluble (XCS) content in the range of 10.0 to lower than 25.0 wt. % based on the heterophasic polypropylene copolymer (HECO);
(ii) the xylene cold soluble (XCS) fraction of the heterophasic polypropylene copolymer (HECO) having a comonomer content in the range of 15.0 to 35.0 wt. %, and an intrinsic viscosity (IV) of lower than 2.0 dl/g,
wherein the weight ratio between the heterophasic polypropylene copolymer (HECO) and the propylene polymer (PP) is in the range of 1:5 to 1:1, the automotive article is a foamed article and the method comprises the step of chemical or physical foaming.
14. The fiber reinforced composition according to claim 1 , wherein said heterophasic polypropylene copolymer (HECO) comprises a matrix (M) being a propylene random copolymer (M-RPP) and an elastomeric propylene copolymer (E) dispersed in said matrix (M), wherein
a) said propylene random copolymer (M-RPP) has a melt flow rate MFR2 at 230° C. of below 30 g/10 min;
and
b) the comonomer content of the said propylene random copolymer (M-RPP) is in the range of 1 to 8 wt. %.