Metal oxide film formation method
In a metal oxide film formation method of the present invention, the following steps are performed. In a solution vessel, a raw-material solution including aluminum as a metallic element is turned into a mist so that a raw-material solution mist is obtained. In a solution vessel provided independently of the solution vessel, a reaction aiding solution including a reaction aiding agent for formation of aluminum oxide is turned into a mist so that an aiding-agent mist is obtained. Then, the raw-material solution mist and the aiding-agent mist are fed to a nozzle provided in a reactor vessel via paths. Thereafter, the raw-material solution mist and the aiding-agent mist are mixed in the nozzle so that a mixed mist is obtained. Then, the mixed mist is fed onto a back surface of a heated P-type silicon substrate.
1. A metal oxide film formation method, comprising:
(a) turning a raw-material solution including a metallic element into a mist, to obtain a raw-material solution mist, in a first vessel;
(b) turning a reaction aiding solution including a reaction aiding agent into a mist, to obtain an aiding-agent mist, in a second vessel provided independently of said first vessel, the reaction aiding agent aiding in an oxidation of said metallic element; and
(c) feeding said raw-material solution mist and said aiding-agent mist via first and second paths provided independently of each other, into a reactor vessel while heating a substrate placed in said reactor vessel, to form a metal oxide film including said metallic element on one main surface of said substrate, wherein
said reaction aiding solution is a solution including one of ammonia and a hydrochloric acid, and
said raw-material solution mist and said aiding-agent mist are not mixed before reaching said reaction vessel,
wherein
said reactor vessel includes a nozzle, and
said feeding (c) includes:
(c-1) feeding said raw-material solution mist and said aiding-agent mist to said nozzle via said first and second paths;
(c-2) mixing said raw-material solution mist and said aiding-agent mist in said nozzle, to obtain a mixed mist; and
(c-3) feeding said mixed mist onto said one main surface of said substrate.
2. The method according to claim 1 , wherein said metallic element is aluminum.
3. The method according to claim 2 , wherein the metal oxide film is an aluminum oxide film.