Negative electrode active material and lithium secondary battery comprising the same
The present invention relates to a negative electrode active material comprising a mixture of a first negative electrode active material and a second negative electrode active material, wherein the first negative electrode active material has a hardness of 1 kg/mm 2 to 10 kg/mm 2 on the basis of the Vickers hardness standard, and the second negative electrode active material has a higher hardness than the first negative electrode active material. The negative electrode active material according to the present invention comprises a mixture of negative electrode active materials having different hardness so that pores of an active material layer are maintained in spite of a rolling process at the time of producing an negative electrode, and the pores acting as an electrolyte flow passage of an electrode can effectively be secured, thereby producing a lithium secondary battery having excellent battery performance by lowering resistance when a battery is charged or discharged.
1. A negative electrode active material comprising a mixture of a first negative electrode active material and a second negative electrode active material,
wherein the first negative electrode active material has a hardness of 1 to 10 kg/mm 2 based on Vickers hardness, and
the second negative electrode active material has a higher hardness than that of the first negative electrode active material,
wherein the second negative electrode active material is one or more selected from the group consisting of a metal carbide coated with a metal oxide, an alloy coated with a metal oxide, and a metal coated with a metal oxide, and
wherein the first negative electrode active material is one or more selected from the group consisting of soft carbon, hard carbon, natural graphite, kish graphite, pyrolytic carbon, mesophase pitch-based carbon fiber, meso-carbon microbeads, mesophase pitches, petroleum or coal tar pitch-derived cokes, Al, Zn, Sb, Si, Ge and Sn.
2. The negative electrode active material of claim 1 , wherein the second negative electrode active material has a hardness of 11 to 10,000 kg/mm 2 based on Vickers hardness.
3. The negative electrode active material of claim 1 , wherein the first negative electrode active material and the second negative electrode active material are included in a weight ratio of 99:1 to 50:50.
4. The negative electrode active material of claim 1 , wherein the second negative electrode comprises the metal oxide and/or the metal coated with the metal oxide, wherein the metal oxide is one or more selected from the group consisting of titanium oxide, aluminum oxide, chromium trioxide, zinc oxide, copper oxide, magnesium oxide, zirconium dioxide, molybdenum trioxide, vanadium pentoxide, niobium pentoxide, iron oxide, manganese oxide, vanadium oxide, cobalt oxide, nickel oxide and tantalum pentoxide.
5. The negative electrode active material of claim 1 , wherein the second negative electrode active material has a particle size in a direction in which the pressure is applied of 60% or more based on an original particle size when a pressure of 2,000 kgf/cm 2 is applied.
6. The negative electrode active material of claim 1 , wherein the second negative electrode active material has a particle size in a direction in which the pressure is applied of 80 to 90% based on an original particle size when a pressure of 2,000 kgf/cm 2 is applied.
7. The negative electrode active material of claim 1 , wherein the first negative electrode active material has an average particle size (D 50 ) of 10 nm to 100 μm.
8. The negative electrode active material of claim 1 , wherein the second negative electrode active material has an average particle size (D 50 ) of 10 nm to 100 μm.
9. A negative electrode comprising a negative electrode active material layer including the negative electrode active material according to claim 1 .
10. The negative electrode of claim 9 , wherein the negative electrode active material layer has a porosity of 10 to 60%.
11. A lithium secondary battery comprising the negative electrode according to claim 9 .
12. The negative electrode active material of claim 1 , wherein the metal in the metal oxide is one or more selected from the group consisting of Si, Ge, Sn, Al, Zn, and Sb.