Conductive material dispersed liquid and lithium secondary battery manufactured using same
The present invention provides a conductive material dispersed liquid, including: a conductive material which includes bundle-type carbon nanotubes; a dispersant; a dispersion medium, where a phase angle is in a range of 3° to 18° when measured by a rheometer at a frequency of 1 Hz; and a lithium secondary battery manufactured using the conductive material dispersed liquid. The conductive material dispersed liquid has high solid-like properties, and thus allows the formation of an electrode active material layer having a uniform thickness with no concern for collapse or occurrence of cracks during manufacture of an electrode, and thereby can improve the performance characteristics, particularly capacity characteristics, of a battery.
1. A conductive material dispersed liquid, comprising:
a conductive material which includes bundle-type carbon nanotubes;
a dispersant; and
a dispersion medium,
wherein a phase angle of the conductive material dispersed liquid is in a range of 3° to 18° when measured by a rheometer at a frequency of 1 Hz, and
wherein the bundle-type carbon nanotubes have a ratio (TD/BD ratio) of a true density (TD) to a bulk density (BD) in a range of 70 to 100.
2. The conductive material dispersed liquid according to claim 1 , wherein the carbon nanotubes include a carbon nanotube unit having an average strand diameter of 10 to 30 nm.
3. The conductive material dispersed liquid according to claim 1 , wherein the carbon nanotubes are included at 1 to 33 wt % based on the total weight of the conductive material dispersed liquid.
4. The conductive material dispersed liquid according to claim 1 , wherein the dispersant includes a nitrile butadiene-based rubber.
5. The conductive material dispersed liquid according to claim 1 , wherein the dispersant includes a hydrogenated nitrile butadiene-based rubber comprising a structural unit derived from a hydrogenated conjugated diene at 20 to 80 wt % based on the total weight of the rubber.
6. The conductive material dispersed liquid according to claim 5 , wherein the hydrogenated nitrile butadiene-based rubber includes a structural unit derived from α, β-unsaturated nitrile at 10 to 70 wt % based on the total weight of the rubber.
7. The conductive material dispersed liquid according to claim 5 , wherein the hydrogenated nitrile butadiene-based rubber includes a partially hydrogenated nitrile butadiene-based rubber comprising a structural unit derived from a hydrogenated conjugated diene at 20 to 80 wt %; a structural unit derived from α, β-unsaturated nitrile at 10 to 70 wt %; and a structural unit derived from a conjugated diene at 1 to 15 wt % based on the total weight of the rubber.
8. The conductive material dispersed liquid according to claim 5 , wherein the hydrogenated nitrile butadiene-based rubber has a weight average molecular weight of 10,000 to 700,000 g/mol and a polydispersity index of 2.0 to 6.0.
9. The conductive material dispersed liquid according to claim 1 , wherein the dispersant is included at 1 to 50 parts by weight based on 100 parts by weight of the carbon nanotubes.
10. The conductive material dispersed liquid according to claim 1 , wherein the dispersant is introduced into a surface of the carbon nanotubes to form a carbon nanotubes-dispersant composite, and the carbon nanotubes-dispersant composite has a particle size distribution D 99 of 100 μm or less and is included in an amount of 1 to 5 wt % based on the total weight of the dispersed liquid.
11. The conductive material dispersed liquid according to claim 1 , wherein the dispersion medium is an amide-based organic solvent.
12. The conductive material dispersed liquid according to claim 1 , wherein the conductive material dispersed liquid is used as a conductive material for an electrode of a lithium secondary battery.
13. A method of preparing the conductive material dispersed liquid according to claim 1 , comprising mixing a conductive material which includes bundle-type carbon nanotubes, a dispersant, and a dispersion medium to form a mixture, and then milling the mixture such that a phase angle of the mixture is in a range of 3° to 18° when measured by a rheometer at a frequency of 1 Hz.
14. The method according to claim 13 , wherein the milling is performed by a bead mill.
15. The method according to claim 14 , wherein the milling is performed using a bead mill having an average diameter of 0.5 to 2 mm for 60 to 120 minutes.
16. A composition for forming an electrode of a lithium secondary battery, comprising:
an electrode active material;
a binder; and
the conductive material dispersed liquid according to claim 1 .
17. The composition according to claim 16 , wherein the conductive material dispersed liquid is included at 1 to 50 wt % based on the total weight of the composition for forming an electrode.
18. The composition according to claim 16 , wherein the composition for forming an electrode of a secondary battery has a phase angle of 15° to 35° when measured by a rheometer at a frequency of 1 Hz.
19. An electrode for a lithium secondary battery, manufactured using the composition for forming an electrode according to claim 16 .
20. A lithium secondary battery, comprising:
a positive electrode;
a negative electrode;
a separator; and
an electrolyte,
wherein at least one of the positive electrode and the negative electrode is the electrode for a lithium secondary battery according to claim 19 .