Method of manufacturing negative electrode and negative electrode
The present invention relates to a method of manufacturing a negative electrode and a negative electrode manufactured using the method. According to the present invention, negative electrode samples are fabricated to have different electrode densities, and then, in a negative electrode expansion curve of each negative electrode sample according to the 1 st charging, when a change in slopes of tangents to the negative electrode expansion curve at an initial state of charge (SOC) of less than 50%, at which the expansion curve increases, satisfies a particular value, a secondary battery manufactured including a negative electrode having the electrode density may exhibit excellent lifespan characteristics and excellent initial efficiency for the corresponding active material.
1. A method of manufacturing a negative electrode, the method comprising:
fabricating a plurality of negative electrode samples, each negative electrode sample having an active layer of the same composition and a different electrode density, wherein each active material layer includes graphite as an active material;
measuring expansion of each negative electrode sample as a function of a state of charge (SOC) during a 1 st charging cycle to generate an expansion curve for each negative electrode sample;
determining an SOC value, x, at which a slope of a tangent line to the expansion curve is 1, wherein x<50% for each negative electrode sample;
determining a slope of a tangent line to the expansion curve at an SOC value of x−5, and a slope of a tangent line to the expansion curve at an SOC value of x+5 for each negative electrode sample;
determining a difference between the slopes of the tangent lines at x−5 and x+5 for each negative electrode sample;
selecting the negative electrode samples having a difference between the slopes of the tangent lines at x−5 and x+5 in a range of 0 to 0.5; and
manufacturing a negative electrode under the same conditions as one of the selected negative electrode samples.
2. The method of claim 1 , wherein the graphite having a powder compact density ranging from 1.75 g/cc to 1.95 g/cc and consisting of secondary particles as an active material.
3. The method of claim 1 , wherein the active material layer comprises the graphite, a conductive material, and a binder in a weight ratio of 95-95.5:0.5-1.5:3.5-4.
4. The method of claim 1 , wherein, each negative electrode sample has an electrode density ranging from 1.3 g/cc to 1.8 g/cc.
5. The method of claim 1 , wherein the manufactured negative electrode is performed by applying a slurry on a current collector, wherein the slurry is a mixture of graphite, a conductive material, a binder, and an organic solvent; and
then drying and pressing the resulting negative active material layer against the current collector,
wherein the pressing is performed to achieve an electrode density that is the same as the electrode density of the selected negative electrode sample.
6. A negative electrode manufactured using the method of claim 1 ,
wherein the manufactured negative electrode comprises graphite consisting of secondary particles as an active material and has an electrode density of 1.3 g/cc to 1.5 g/cc.
7. A negative electrode manufactured using the method of claim 1 ,
wherein the manufactured negative electrode comprises graphite consisting of secondary particles as an active material and has an electrode density of 1.4 g/cc to 1.7 g/cc.
8. The negative electrode according to claim 6 , wherein a weight ratio of the graphite, a conductive material, and a binder in the manufactured negative electrode is 95-95.5:0.5-1.5:3.5-4.
9. A secondary battery comprising the manufactured negative electrode of claim 6 , a positive electrode, a separator between the negative electrode and the positive electrode, and an electrolyte.
10. The negative electrode according to claim 7 , wherein a weight ratio of the graphite, a conductive material, and a binder in the manufactured negative electrode is 95-95.5:0.5-1.5:3.5-4.
11. A secondary battery comprising the manufactured negative electrode of claim 7 , a positive electrode, a separator between the negative electrode and the positive electrode, and an electrolyte.