Method of preparing secondary battery
The present invention relates to a method of preparing a secondary battery which includes providing a film layer, which includes a first solvent having a melting temperature of 25° C. or more and a viscosity of 1.5 cP or more, between a separator and an electrode (step 1), preparing an electrode assembly by using the electrode, the film layer, and the separator (step 2), and accommodating the electrode assembly in a case, injecting an injection solution including a second solvent, and sealing the case (step 3), and a secondary battery prepared by the method. According to the method of preparing a secondary battery of the preset invention, since electrolyte solution impregnability may be improved, performance and safety of the secondary battery may be further improved.
1. A method of preparing a secondary battery, the method comprising:
preparing a film layer by compressing a first solvent in a solid state at a temperature of less than 25° C. to prepare the film layer by applying a pressure of 50 to 300 Kgf/cm 2 , wherein the film layer consists of the first solvent having a melting temperature of 25° C. or more and a viscosity at 40° C. of 1.5 cP or more, and a first lithium salt included at a concentration of 0.3M to 2.0M with respect to the first solvent, wherein the first solvent comprises ethylene carbonate and 1,3-propylene carbonate mixed in a weight ratio of 1:1, OR the first solvent consists of ethylene carbonate and wherein the film layer has a thickness of 10 μm to 500 μm;
preparing an electrode assembly including an electrode, a separator, and the film layer disposed between the separator and the electrode;
inserting the electrode assembly in a case;
injecting an electrolyte solution including a second solvent into the case, wherein a weight ratio of the first solvent to the second solvent is in a range of 1:0.2 to 1:2; and
sealing the case.
2. The method of claim 1 , wherein the first solvent comprises at least one compound selected from the group consisting of ethylene carbonate, cis-4,5-dimethyl-1,3-dioxolan-2-one, trans-4,5-dimethyl-1,3-dioxolan-2-one, 1,2-cyclopentylene carbonate, cyclohexene carbonate, pinacolone cyclic carbonate, 1,3-propylene carbonate, 5,5-dimethyl-1,3-dioxan-2-one, sulfolane, ethyl methyl sulfone, diethyl sulfone, ethyl dimethylcarbamate, and phenyl dimethylcarbamate.
3. The method of claim 1 , wherein the second solvent comprises at least one selected from a group consisting of a low-viscosity solvent, which is a liquid at room temperature and has a viscosity at 25° C. of less than 1.5 cP, and a high-viscosity solvent which is a solid at room temperature and has a viscosity at 40° C. of 1.5 cP or more.
4. The method of claim 3 , wherein, in a case in which the second solvent is the low-viscosity solvent, the second solvent comprises a single material selected from a group consisting of carbonates; esters; and lactones, or a mixture of two or more thereof.
5. The method of claim 4 , wherein the second solvent comprises a single material selected from a group consisting of dim ethyl carbonate, ethyl methyl carbonate, butylene carbonate, diethyl carbonate, dipropyl carbonate, fluoroethylene carbonate, methyl propionate, ethyl propionate, propyl propionate, butyl propionate, 7-butyrolactone, and mixtures thereof.
6. The method of claim 3 , wherein, in a case in which the second solvent is a high-viscosity solvent, the second solvent comprises a single material selected from a group consisting of ethylene carbonate, cis-4,5-dimethyl-1,3-dioxolan-2-one, trans-4,5-dimethyl-1,3-dioxolan-2-one, 1,2-cyclopentylene carbonate, cyclohexene carbonate, pinacolone cyclic carbonate, 1,3-propylene carbonate, 5,5-dimethyl-1,3-dioxan-2-one, sulfolane, ethyl methyl sulfone, diethyl sulfone, ethyl dimethylcarbamate, phenyl dimethylcarbamate, and mixtures thereof.
7. The method of claim 1 , wherein the injection solution further comprises a second lithium salt.
8. The method of claim 7 , wherein the second lithium salt is included in a concentration of 0.7 M to 3.0 M with respect to the second solvent.
9. A secondary battery prepared by the method of claim 1 , the secondary battery comprising:
a positive electrode;
a negative electrode;
a separator;
an electrolyte solution wherein the electrolyte solution comprises a second solvent and a second lithium salt, wherein the second lithium salt is included in a concentration of 0.7 M-3 M with respect to the second solvent; and
a film layer disposed in at least one position between the separator and the negative electrode or between the separator and the positive electrode,
wherein the film layer has a thickness of 10 μm to 500 μm,
wherein the film layer consists of a first solvent having a melting temperature of 25 C or more and a viscosity at 40° C. of 1.5 cP or more, and a first lithium salt included at a concentration of 0.3M to 2.0M with respect to the first solvent,
wherein the first solvent comprises ethylene carbonate and 1, 3-propylene carbonate mixed in a weight ratio of 1:1, or the first solvent consists of ethylene carbonate and
wherein a weight ratio of the first solvent to the second solvent is in a range of 1:0.2 to 1:2.