Catalyst component
The present invention relates to a solid, particulate catalyst component having an mean particle size range of 5 to 200 μm and comprising a compound of a Group 2 metal, a compound of a transition metal of Group 4 to 6, and at least two internal electron donors being different to each other and being non-phthalic organic compounds selected from (di)esters of non-phthalic carboxylic (di)acids, 1,3-diethers and di-esters of 1,3-diol compounds and derivatives thereof, and wherein the solid particulate catalyst component is free of any external support material. The invention relates also to the preparation of the catalyst component and a polymerization process for producing propylene polymers.
1. A solid, particulate catalyst component having a mean particle size range of 5 to 200 μm and comprising
i) a compound of Group 2 metal, IUPAC, Nomenclature of Inorganic Chemistry, 1989,
ii) a compound of a transition metal of Group 4 to 6, IUPAC, Nomenclature of Inorganic Chemistry, 1989,
iii) a first internal electron donor and a second internal electron donor, which are different from each other,
wherein the first internal electron donor is a non-phthalic organic compound selected from esters of non-phthalic carboxylic acids, or di-esters of 1,3-diol compounds, and
iv) an additional internal electron donor, which is a third internal electron donor,
wherein the second internal electron donor and the third internal electron donor are selected from esters of non-phthalic carboxylic acids, or diesters of 1,3-diol compounds,
wherein the solid particulate catalyst component is free of any phthalic compound and external support material.
2. The solid, particulate catalyst component according to claim 1 , wherein the Group 2 metal is magnesium.
3. The solid, particulate catalyst component according to claim 1 , wherein the transition metal of Group 4 to 6 is a Group 4 metal.
4. The solid, particulate catalyst component according to claim 1 , wherein the amount of the first internal electron donor is in the range of 1 to 25 wt-%, and the sum of the amounts of the second and the third internal electron donors is in the range of 1 to 50 wt-% in the catalyst component.
5. The solid, particulate catalyst component according to claim 1 , wherein the total amount of the first, the second, and the third internal electron donors in the catalyst component is in the range of 5 to 50 wt-%.
6. A Ziegler-Natta catalyst comprising the solid catalyst component of claim 1 , a co-catalyst of an organoaluminium compound, and an external electron donor.
7. A process for producing propylene polymers by polymerising propylene and a comonomer selected from C 2 - C 12 monomers in a process comprising at least one polymerisation step in the presence of the catalyst of claim 6 .
8. The solid, particulate catalyst component according to claim 1 , wherein the first internal electron donor is a non-phthalic organic compound selected from esters of non-phthalic carboxylic acids, or di-esters of 1,3-diol compounds, and the second internal electron donor and the third internal electron donor are selected from diesters of 1,3-diol compounds.