Lithium-sulfur battery separation film having composite coating layer including polydopamine, manufacturing method therefor, and lithium-sulfur battery comprising same
The present invention relates to a separator for a lithium-sulfur battery having a composite coating layer including polydopamine, and a method for preparing the same, and in particular, to a lithium-sulfur battery suppressing lithium polysulfide elution by using a composite coating layer including polydopamine and a conductive material on one surface of a separator. In the lithium-sulfur battery according to the present invention, a porous structure of polydopamine adsorbs lithium polysulfide eluted from a positive electrode preventing elution and diffusion, and by providing additional electric conductivity, a reaction site of a positive electrode active material is provided, and therefore, battery capacity and life time properties are enhanced.
1. A separator for a lithium-sulfur battery comprising:
a separator body; and
a composite coating layer formed on at least one surface of the separator body,
wherein the composite coating layer comprises a mixture of polydopamine and a conductive material in a weight ratio of 3:1 to 7:1.
2. The separator for a lithium-sulfur battery of claim 1 , wherein the composite coating layer has a thickness of 0.1 μm to 10 μm.
3. The separator for a lithium-sulfur battery of claim 1 , wherein the conductive material includes one type selected from the group consisting of carbon-based conductors, conductive polymers and combinations thereof.
4. The separator for a lithium-sulfur battery of claim 3 , wherein the carbon-based conductor includes one type selected from the group consisting of graphite-based, active carbon-based, carbon black-based, carbon fiber-based, carbon nanostructures and combinations thereof.
5. The separator for a lithium-sulfur battery of claim 3 , wherein the conductive polymer includes one type selected from the group consisting of polyaniline, polypyrrole, polythiopene, polyazulene, polypyridine, polyindole, polycarbazole, polyazine, polyquinone, polyacetylene, polyselenophene, polytellurophene, poly-para-phenylene, polyphenylene vinylene, polyphenylene sulfide, polyethylenedioxythiophene and combinations thereof.
6. A separator for a lithium-sulfur battery comprising:
a separator body;
a composite coating layer formed on at least one surface of the separator body; and
a polydopamine coating layer between the separator body and the composite coating layer,
wherein the composite coating layer comprises polydopamine and a conductive material.
7. The separator for a lithium-sulfur battery of claim 6 , wherein the polydopamine coating layer has a thickness of 0.1 μm to 10 μm.
8. A method for preparing a separator for a lithium-sulfur battery comprising:
i) preparing a separator body;
ii) preparing a mixture slurry by mixing polydopamine, a conductive material and a solvent,
wherein mixture of the polydopamine and the conductive material is in a weight ratio of 3:1 to 7:1;
iii) coating the mixture slurry on at least one surface of the separator body; and
iv) forming a composite coating layer by drying the coated separator.
9. A method for preparing a separator for a lithium-sulfur battery, comprising:
i) preparing a separator body;
ii) preparing a polydopamine slurry;
iii) coating the polydopamine slurry on the separator body;
iv) drying the coated separator body;
v) preparing a mixture slurry by mixing polydopamine, a conductive material and a solvent;
vi) coating the mixture slurry on at least one surface of the separator body; and
vii) forming a composite coating layer by drying the coated separator body.
10. A lithium-sulfur battery comprising:
a positive electrode;
a negative electrode;
a separator provided between the positive electrode and the negative electrode; and
an electrolyte,
wherein the separator is the separator of claim 1 .