HYDROLYSABLE BINDER
The invention relates to ahydrolysable binder based on an ABAB type polysiloxane copolymer suitable for the preparation of coating compositions with an improved anti-adhesive and/or dirt-repellent surface.
1 : A hydrolysable binder for a coating composition, the hydrolysable binder comprising:
the reaction product of: i) at least one polysiloxane of monomer A′ of formula (A″):
wherein each R 1 is methyl,
X and Y are the same and represent (CH 2 ) x′ —OH or —(CH 2 ) x′ —COOH or —(CH 2 ) x′ —COOR;
x′ is 1 to 5;
R is C1-6 alkyl; and
n is 10-300,
and
ii) at least one second monomer B′ of formula
RcOOC-Q-COORc (formula B″)
or
Rc′O-Q-ORc′ (formula B′″)
where Q is an aliphatic, cycloalkyl, cycloalkenyl, polyoxyalkylene or aromatic group having up to 20 carbon atoms or a covalent bond or a linear polysiloxane and each Rc and Rc′ are the same or different and represent H, C 1-20 alkyl, C 2-20 alkenyl, C 6-20 aryl, C 3-20 cycloalkyl group or C 7-20 arylalkyl group,
with the proviso that the Rc or Rc′ groups in (formula B″) or (formula B′″) are selected to react with the X and Y groups in monomer A′ to form an ester group,
wherein the hydrolysable binder is suitable for a coating composition that is not a marine coating composition.
2 : The hydrolysable binder as claimed in claim 1 , wherein monomer A′ is at least one monomer selected from the group consisting of:
wherein
X′ is 1 to 10; and
R 11 and R 12 are each independently C2-6 alkylene.
3 : The hydrolysable binder as claimed in claim 1 , wherein monomer B′ is
wherein Rd is a saturated, unsaturated or aromatic C 3 -C 8 ring.
4 : The hydrolysable binder as claimed in claim 1 , wherein monomer B′ is
wherein
Rd is a saturated, unsaturated, or aromatic C 3 -C 8 ring; and
R 3 and R 4 are each independently a straight or branched chain C 1-20 alkyl group, a straight or branched chain C 2-10 alkenyl group, a C 6-20 aryl group, a C 7-20 arylalkyl group, or a C 3-20 cycloalkyl group.
5 : The hydrolysable binder as claimed in claim 1 , wherein
monomer B′ is HO-Q-OH diol where Q is an aliphatic, polyoxyalkylene, cycloalkyl, cycloalkenyl or aromatic group having up to 20 carbon atoms or a covalent bond.
6 : The hydrolysable binder as claimed in claim 1 , wherein
monomers A′ and B′ undergo a polymerisation reaction to form a copolymer of structure -[ABAB]-.
7 : The hydrolysable binder as claimed in claim 6 , wherein
the copolymer backbone contains a polyoxyalkylene moiety.
8 : A non-marine coating composition, comprising:
at least one hydrolysable binder as claimed in claim 1 , and
at least one of filler, pigment, solvent, additive, curing agent, and catalyst.
9 . (canceled)
10 : A method of making a coating composition, the method comprising:
adding the hydrolysable binder as claimed in claim 1 to a coating composition, wherein the coating composition exhibits an anti-adhesive-property, an anti-dirt-property, an easy-to-clean property, an anti-graffiti-property or an anti-fouling property in a non-marine application.
11 : The hydrolysable binder as claimed in claim 1 , wherein
x′ is 2 to 5 or is 3 to 5;
R is C1-6 alkyl; and
n is 15-100.
12 : The hydrolysable binder as claimed in claim 2 , wherein
X′ is 1 to 5 or 2 to 5 or 3 to 5.
13 : The hydrolysable binder as claimed in claim 3 , wherein
Rd is a saturated, unsaturated or aromatic C 5 -C 6 ring.
14 : The hydrolysable binder as claimed in claim 1 , wherein monomer B′ is
wherein
Rd is a saturated, unsaturated, or aromatic C 5 -C 6 ring; and
R 3 and R 4 are each independently a straight or branched chain alkyl group, a straight or branched chain alkenyl group, an arylalkyl group, or a cycloalkyl group,
wherein the straight or branched chain alkyl group is a C 1-10 alkyl group or a C 1-6 alkyl group or a C 1-4 alkyl group,
wherein the straight or branched chain alkenyl group is a C 2-6 alkenyl group,
wherein the arylalkyl group is a C 7-12 arylalkyl group, and
wherein the cycloalkyl group is a C 4-15 cycloalkyl group or a C 5-10 cycloalkyl group.
15 : The hydrolysable binder as claimed in claim 5 , wherein
Q represents an alkylene chain having up to 10 carbon atoms.
16 : The hydrolysable binder as claimed in claim 6 , wherein
the copolymer backbone contains a moiety of PEG, PPG, a PEG copolymer, or a PPG copolymer.